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It should be noted that only the triplet ground state, T1, is included. T2 and higher triplet excited states might be relevant in some systems; however, they will interact with the radical spin in the same fashion as T1, and once populated, they will nonradiatively decay to the triplet ground state
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1, and once populated, they will nonradiatively decay to the triplet ground state.
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We remark that our nine states contain mixed-spin states, and while this is irrelevant in the quantum dynamics with all states included, it does introduce additional error in the FGR derivation, in which some states are dropped
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We remark that our nine states contain mixed-spin states, and while this is irrelevant in the quantum dynamics with all states included, it does introduce additional error in the FGR derivation, in which some states are dropped.
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24
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Giacobbe, E. M.; Mi, Q.; Colvin, M. T.; Cohen, B.; Ramanan, C.; Scott, A. M.; Marks, T. J.; Ratner, M. A.; Wasielewski, M. R. J. Am. Chem. Soc., submitted for publication.
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Wasielewski, M.R.9
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