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Volumn 131, Issue 6, 2009, Pages 2268-2273

Enhanced intersystem crossing in three-spin systems: A perturbation theory treatment

Author keywords

[No Author keywords available]

Indexed keywords

COUPLING PARAMETERS; FERMI'S GOLDEN RULE; INTERSYSTEM CROSSING; PERTURBATION THEORY; RATE EXPRESSION; SIMPLE MODEL; SPIN EXCHANGES; STABLE RADICALS; THREE-SPIN SYSTEM;

EID: 67849127164     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja807590q     Document Type: Article
Times cited : (24)

References (25)
  • 6
    • 4243542678 scopus 로고    scopus 로고
    • Rajca, A. Chem. ReV. 1994, 94, 871-893.
    • Chem. Re , vol.1994 , Issue.94 , pp. 871-893
    • Rajca, A.1
  • 16
    • 84891737533 scopus 로고    scopus 로고
    • It should be noted that only the triplet ground state, T1, is included. T2 and higher triplet excited states might be relevant in some systems; however, they will interact with the radical spin in the same fashion as T1, and once populated, they will nonradiatively decay to the triplet ground state
    • 1, and once populated, they will nonradiatively decay to the triplet ground state.
  • 17
    • 0004043298 scopus 로고    scopus 로고
    • For example, see:, 2nd ed, Dover Publications: Mineola, NY, Chapter 4
    • For example, see: Schatz, G. C.; Ratner, M. A. Quantum Mechanics in Chemistry, 2nd ed.; Dover Publications: Mineola, NY, 2002; Chapter 4.
    • (2002) Quantum Mechanics in Chemistry
    • Schatz, G.C.1    Ratner, M.A.2
  • 18
    • 84891744035 scopus 로고    scopus 로고
    • We remark that our nine states contain mixed-spin states, and while this is irrelevant in the quantum dynamics with all states included, it does introduce additional error in the FGR derivation, in which some states are dropped
    • We remark that our nine states contain mixed-spin states, and while this is irrelevant in the quantum dynamics with all states included, it does introduce additional error in the FGR derivation, in which some states are dropped.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.