Direct observation of acyl azide excited states and their decay processes by ultrafast time resolved infrared spectroscopy

Journal of the American Chemical Society

Volumn 131, Issue 12, 2009, Pages 4212-4213

  Kubicki, Jacek ^a   Zhang, Yunlong ^b   Wang, Jin ^b   Luk, Hoi Ling ^b   Peng, Huo Lei ^a   Vyas, Shubham ^b   Platz, Matthew S ^b  

^a ADAM MICKIEWICZ UNIVERSITY   (Poland)

^b OHIO STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

[CARBONYL; DECAY PROCESS; DIRECT OBSERVATION; TIME RESOLVED INFRARED SPECTROSCOPY; TIME-RESOLVED IR SPECTROSCOPY; ULTRA-FAST;

CARBONYLATION; CHLORINE COMPOUNDS; EXCITED STATES; NITROGEN COMPOUNDS; SPECTROSCOPIC ANALYSIS;

INFRARED SPECTROSCOPY;

AZIDE; ISOCYANATE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; COOLING; ENERGY; EXCITATION; FLUORESCENCE SPECTROSCOPY; INFRARED SPECTROMETRY; PHOTOCHEMISTRY; PHOTOLYSIS;

EID: 67849111794     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9002102     Document Type: Article

References (17)

1. Moss, R. A.; Platz, M. S.; Jons, M. J. Nitrenes in Reactive Intermediate Chemistry; John Willey & Sons, Inc.: 2004; pp 501-559.
2. Gritsan, N. P. Russ. Chem. Rev. 2007, 76, 1139.
3. Linke, S.; Tisue, G. T.; Lwowski, W. J. Am. Chem. Soc. 1967, 89, 6308-6310.
4. Tisue, G. T.; Linke, S.; Lwowski, W. J. Am. Chem. Soc. 1967, 89, 6303-6307.
5. Poppinger, D.; Radom, L.; Pople, J. A. J. Am. Chem. Soc. 1977, 99, 7806-7816.
6. Carpenter, B. K. Angew. Chem., Int. Ed. 1998, 37, 3340-3350.
7. Burdzinski, G. T.; Wang, J.; Gustafson, T. L.; Platz, M. S. J. Am. Chem. Soc. 2008, 130, 3746-3747.
8. Pritchina, E. A.; Gritsan, N. P.; Maltsev, A.; Bally, T.; Autrey, T.; Liu, Y.; Wang, Y.; Toscano, J. P. Phys. Chem. Chem. Phys. 2003, 5, 1010-1018.
9. Autrey, T.; Schuster, G. B. J. Am. Chem. Soc. 1987, 109, 5814-5820.
10. Gritsan, N. P.; Pritchina, E. A. Mendeleev Commun. 2001, 11, 94.
11. Desikan, V.; Liu, Y.; Toscano, J. P.; Jenks, W. S. J. Org. Chem. 2007, 72, 6848-6859.
12. Sigman, M. E.; Autrey, T.; Schuster, G. B. J. Am. Chem. Soc. 1988, 110, 4297-4305.
13. Desikan, V.; Liu, Y.; Toscano, J. P.; Jenks, W. S. J. Org. Chem. 2008, 73, 4398-44 1 4.
14. Hamm, P.; Ohline, S. M.; Zinth, W. J. Chem. Phys. 1997, 106, 519.
15. Rabinovitch, B. S.; Rynbrandt, J. D. J. Phys. Chem. 1971, 75, 2164-2171.
16. Klessinger, M., Michl, J, Excited States and Photochemistry of Organic Molecules; VCH Publishers, Inc.: 1995; Chapter 6. Photochemical Reaction Models, pp 309-359.
17. 3 is longer than 3 ns and would not be detected in these experiments.