On the importance of the reaction between OH and RO2 radicals

Atmospheric Science Letters

Volumn 10, Issue 2, 2009, Pages 102-108

  Archibald, Alexander T ^a   Petit, A S ^a   Percival, C J ^b   Harvey, J N ^a   Shallcross, D E ^a  

^a UNIVERSITY OF BRISTOL   (United Kingdom)

^b UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

Marine boundary layer; OVOCs; Peroxy radicals; Reaction with OH

Indexed keywords

ATMOSPHERIC MODELING; BOUNDARY LAYER; HYDROXYL RADICAL; PEROXY RADICAL; TRACE GAS; VOLATILE ORGANIC COMPOUND;

EID: 67849101379     PISSN: None     EISSN: 1530261X     Source Type: Journal    
DOI: 10.1002/asl.216     Document Type: Article

References (39)

1. Andrés Hernández MD, Burkert J, Reichert L, Stöbener D, Meyer-Arnek J, Burrows JP, Dickerson RR, Doddridge BG. 2001. Marine boundary layer peroxy radical chemistry during the AEROSOLS99 campaign: Measurements and analysis. Journal of Geophysical Research 106(D18): 20833-20846.
2. Archibald AT, McGillen MR, Taatjes CA, Percival CJ, Shallcross DE. 2007. Atmospheric transformation of enols: A potential secondary source of carboxylic acids in the urban troposphere. Geophysical Research Letters 34: L21801. DOI:10.1029/2007GL031032.
3. Baboukas ED, Kanakidou M, Mihalopoulos N. 2000. Carboxylic acids in gas and particulate phase above the Atlantic Ocean. Journal of Geophysical Research 105(D11): 14459-14471.
4. 3O with ClO. Geophysical Research Letters 22: 1221-1224.
5. 2 and H. Journal of the Chemical Society, Faraday Transactions 93(16): 2701-2705.
6. Bonsang B, Lambert G. 1985. Nonmethane hydrocarbons in an ocean atmosphere. Journal of Atmospheric Chemistry 2: 257-271.
7. Bonsang B, Polle C, Lambert G. 1992. Evidence for marine production of isoprene. Geophysical Research Letters 19: 1129-1132.
8. Burkert J, Andrés-Hernández MD, Stöbener D, Burrows JP. 2001. Peroxy radical and related trace gas measurements in the boundary layer above the Atlantic Ocean. Journal of Geophysical Research 106: 5457-5477.
9. Cantrell CA, Edwards GD, Stephens S, Mauldin L, Kosciuch E, Zondlo M, Eisele F. 2003. Peroxy radical observations using chemical ionization mass spectrometry during TOPSE. Journal of Geophysical Research 108(D6): 8371. DOI: 10.1029/2002JD002715.
10. Chameides WL, Walker JCG. 1973. A photochemical theory of tropospheric ozone. Journal of Geophysical Research 78: 8751-8760.
11. Criegee R, Wenner G. 1949. Die ozonisierung des 9,10-oktalins. Annalen der Chemie 564: 9-15.
12. Crutzen P. 1973. A discussion of the chemistry of some minor constituents in the stratosphere and troposphere. Pure and Applied Geophysics 106: 1385-1399.
13. 2 with Cl and ClO. Journal de Chimie Physique et de Physico-Chimie Biologique 93: 1081-1099.
14. Donahue NM, Prinn RG. 1990. Nonmethane hydrocarbon chemistry in the remote marine boundary layer. Journal of Geophysical Research 95: 18387-18411.
15. Donahue NM, Prinn RG. 1993. In situ nonmethane hydrocarbon measurements on SAGA 3. Journal of Geophysical Research 98: 16915-16932.
16. 2 with OH. Chemical Physics 327: 10-14.
17. Flemming ZL, Monks PS, Rickard AR, Heard DE, Bloss WJ, Seakins PW, Still TJ, Sommariva R, Pilling MJ, Morgan R, Brough N, Mills GP, Penkett SA, Lewis AC, Lee JD, Saiz-Lopez A, Plane JMC. 2006. Peroxy radical chemistry and the control of ozone photochemistry at Mace Head, Ireland during the summer of 2002. Atmospheric Chemistry and Physics 6: 2193-2214.
18. Guenther A, Hewitt CN, Erickson D, Fall R, Geron C, Graedel T, Harley P, Klinger L, Lerdau M, McKay WA, Pierce T, Scholes B, Steinbrecher R, Tallamraju R, Taylor J, Zimmerman P. 1995. A global model of natural volatile organic compound emissions. Journal of Geophysical Research 100: 8873-8892.
19. Heard DE, Read KA, Methven J, Al-Haider S, Bloss WJ, Johnson GP, Pilling MJ, Seakins PW, Smith SC, Sommariva R, Stanton JC, Still TJ, Ingham TJ, Brooks B, De Leeuw G, Jackson AV, McQuaid JB, Morgan R, Smith MH, Carpenter LJ, Carslaw N, Hamilton J, Hopkins JR, Lee JD, Lewis AC, Purvis RM, Wevill DJ, Brough N, Green T, Mills G, Penkett SA, Plane JMC, Saiz-Lopez A, Worton D, Monks PS, Fleming Z, Rickard AR, Alfarra MR, Allan JD, Bower K, Coe H, Cubison M, Flynn M, McFiggans G, Gallagher M, Norton EG, O'Dowd CD, Shillito J, Topping D, Vaughan G, Williams P, Bitter M, Ball SM, Jones RL, Povey IM, O'Doherty S, Simmonds PG, Allen A, Kinnersley RP, Beddows DCS, Dall'Osto M, Harrison RM, Donovan RJ, Heal MR, Jennings SG, Noone C, Spain G. 2006. The North Atlantic Marine Boundary Layer Experiment (NAMBLEX). Overview of the campaign held at Mace Head, Ireland, in summer 2002. Atmospheric Chemistry and Physics 6: 2241-2272.
20. Heikes B, Lee M, Jacob D, Talbot R, Bradshaw J, Singh H, Blake D, Anderson B, Fuelberg H, Thompson AM. 1996. Ozone, hydroperoxides, oxides of nitrogen, and hydrocarbon budgets in the marine boundary layer over the South Atlantic. Journal of Geophysical Research 30: 24211-24234.
21. Jacob DJ, Field BD, Li QB, Blake BR, de Gouw J, Warneke C, Hansel A,Wistheler A, Singh HB, Guenther A. 2005. Global budget of methanol: constraints from atmospheric observations. Journal of Geophysical Research 110: D08303. DOI:10.1029/2004JD005172.
22. Jenkin ME, Saunders SM, Pilling MJ. 1997. The tropospheric degradation of volatile organic compounds: a protocol for mechanism development. Atmospheric Environment 31: 81-104.
23. 3O with Cl atoms at room temperature. Berichte der Bunsen-Gesellschaft für Physikalische Chemie 99: 1057-1066.
24. 2 and positive nighttime correlations with monoterpenes. Journal of Geophysical Research 112: D11308. DOI:10.1029/2006JD007987.
25. Keene WC, Galloway JN. 1984. Organic acidity in precipitation of North America. Atmospheric Environment 18: 2491-2497.
26. Keene WC, Galloway JN. 1988. The biogeochemical cycling of formic and acetic acids through the troposphere: an overview of current understanding. Tellus B 40: 322-334.
27. 4 hydrocarbons in the North and South Pacific. Tellus 26: 71-77.
28. Maricq MM, Szente JJ, Kaiser EW, Shi J. 1994. Reaction of chlorine atoms with methylperoxy and ethylperoxy radicals. Journal of Physical Chemistry 98: 2083-2089.
29. Millet DP, Jacob DJ, Custer TG, DeGouw JA, Goldstein AH, Karl T, Singh HB, Sive BC, Talbot RW, Warneke C, Williams J. 2008. New constraints on terrestrial and ocean sources of atmospheric methanol. Atmospheric Chemistry and Physics 8: 7609-7655.
30. Palmer PI, Shaw SL. 2005. Quantifying global marine isoprene fluxes using MODIS chlorophyll observations. Geophysical Research Letters 32: L09805. DOI:10.1029/2005GL022592.
31. Riemer DD, Milne PJ, Zika RG, Pos WH. 2000. Photoproduction of nonmethane hydrocarbons (NMHCs) in seawater. Marine Chemistry 71: 177-198.
32. Saunders SM, Jenkin ME, Derwent RG, Pilling MJ. 2003. Protocol for the development of the master chemical mechanism MCMv3 (Part A): tropospheric degradation of non-aromatic volatile organic compounds. Atmospheric Chemistry and Physics 3: 161-180.
33. Singh HB, Chen Y, Tabazadeh A, Fukui Y, Bey I, Yantosca R, Jacob D, et al. 2000. Distribution and fate of selected oxygenated organic species in the troposphere and lower stratosphere over the Atlantic. Journal of Geophysical Research 105: 3795-3805.
34. 2 chemistry during NAMBLEX: roles of oxygenates, halogen oxides and heterogeneous uptake. Atmospheric Chemistry and Physics 6: 1135-1153.
35. 2OO) in dimethyl sulphoxide oxidation. Journal of the American Chemical Society 130: 11883-11885.
36. Tsang W, Hampson RF. 1986. Chemical kinetic data base for combustion chemistry. Part I. Methane and related compounds. Journal of Physical and Chemical Reference Data 15: 1238.
37. Tyndall GS, Cox RA, Granier C, Lesclaux R, Moortgat GK, Pilling MJ, Ravishankara AR, Wallington TJ. 2001. Atmospheric chemistry of small organic peroxy radicals. Journal of Geophysical Research 106: 12157-12182.
38. von Kuhlmann R, Lawrence MG, Crutzen PJ, Rasch PJ. 2003a. A model for studies of tropospheric ozone and nonmethane hydrocarbons: Model description and ozone results. Journal of Geophysical Research 108(D9): 4294. DOI:10.1029/2002JD002893.
39. von Kuhlmann R, Lawrence MG, Crutzen PJ, Rasch PJ. 2003b. A model for studies of tropospheric ozone and nonmethane hydrocarbons: model evaluation of ozone-related species. Journal of Geophysical Research 108(D23): 4729. DOI:10.1029/2002JD003348.