Nucleobase-templated polymerization: Copying the chain length and polydispersity of living polymers into conjugated polymers

Journal of the American Chemical Society

Volumn 131, Issue 12, 2009, Pages 4182-4183

  Lo, Pik Kwan ^a   Sleiman, Hanadi F ^a  

^a MCGILL UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

BROAD MOLECULAR WEIGHT DISTRIBUTION; CONJUGATED OLIGOMER; CONTROLLED RADICAL POLYMERIZATION; DAUGHTER STRANDS; HYDROGEN BONDING INTERACTIONS; LIVING POLYMERS; NARROW MOLECULAR WEIGHT DISTRIBUTIONS; NUCLEOBASE; POLYMER SYNTHESIS; POLYMER TEMPLATES; POLYMERIZATION MECHANISMS; POLYMERIZATION METHOD; TEMPLATED POLYMERIZATION; TEMPLATED SYNTHESIS;

ATOM TRANSFER RADICAL POLYMERIZATION; CHAIN LENGTH; CONJUGATED POLYMERS; FREE RADICAL POLYMERIZATION; HYDROGEN; HYDROGEN BONDS; MOLECULAR WEIGHT DISTRIBUTION; NORMAL DISTRIBUTION; POLYDISPERSITY; POLYMERS; SYNTHESIS (CHEMICAL); WEIGHING; WEIGHT CONTROL;

ANIONIC POLYMERIZATION;

NUCLEIC ACID; POLYMER; ACRYLAMIDE DERIVATIVE; ADENINE; BIOMATERIAL; BIOMIMETIC MATERIAL; DNA; MACROMOLECULE;

ARTICLE; CHEMICAL STRUCTURE; HYDROGEN BOND; MOLECULAR WEIGHT; POLYMERIZATION; RING OPENING METATHESIS POLYMERIZATION; CHEMICAL MODEL; CHEMISTRY; MACROMOLECULE; MATERIALS TESTING; SYNTHESIS; TRANSMISSION ELECTRON MICROSCOPY;

ACRYLAMIDES; ADENINE; BIOCOMPATIBLE MATERIALS; BIOMIMETIC MATERIALS; DNA; HYDROGEN BONDING; MACROMOLECULAR SUBSTANCES; MATERIALS TESTING; MICROSCOPY, ELECTRON, TRANSMISSION; MODELS, CHEMICAL; MOLECULAR STRUCTURE; MOLECULAR WEIGHT; NUCLEIC ACIDS; POLYMERS;

EID: 67849090886     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja809613n     Document Type: Article

References (21)

1. Steitz, T. A. Harvey Lect. 1997-1998, 93, 75-93.
2. Li, X.; Zhan, Z.-Y. J.; Knipe, R.; Lynn, D. G. J. Am. Chem. Soc. 2002, 124, 746-747.
3. Kleiner, R. E.; Brudno, Y.; Bimabaum, M. E.; Liu, D. R. J. Am. Chem. Soc. 2008, 130, 4646-4659.
4. Böhler, C.; Nielsen, P. E.; Orgel, L. E. Nature 1995, 376, 578-581.
5. Bag, B. G.; von Keidrowski, G. Pure Appl. Chem. 1996, 68, 2145-2152.
6. Gat, Y.; Lynn, D. G. Templated Organic Synthesis; Wiley: New York, 2000; pp 133-157.
7. South, C. R.; Weck, M. Macromolecules 2007, 40, 1386-1394.
8. Lin, N. T.; Lin, S. Y.; Lee, S. L.; Chen, C. H.; Hsu, C. H.; Hwang, L. P.; Xie, Z. Y.; Chen, C. H.; Huang, S. L.; Luh, T. Y. Angew. Chem., Int. Ed. 2007, 46, 4481-4485.
9. Khan, A.; Haddleton, D. M.; Hannon, M. J.; Kukulj, D.; Marsh, A. Macromolecules 1999, 32, 6560-6564.
10. Wise, D. L.; Wnek, G. E.; Trantolo, D. J.; Cooper, T. M.; Gresser, J. D. Electrical and Optical Polymer Systems: Fundamentals, Methods and Application; CSC Press: New York, 1998; p 763.
11. Xue, C.; Luo, F. T.; Chen, J.; Liu, H. Anal. Chim. Acta 2006, 569, 27-34.
12. 20
13. Samori, P.; Francke, V.; Müllen, K.; Rabe, P. Chem.-Eur. J. 1999, 5, 2312-2317.
14. Dai, C. A.; Yen, W. C.; Lee, Y. H.; Ho, C. C.; Su, W. F. J. Am. Chem. Soc. 2007, 129, 11036-11038.
15. Miyakoshi, R.; Yokoyama, A.; Yokozawa, T. J. Am. Chem. Soc. 2005, 127, 17542-17547.
16. Zhang, Y.; Tajima, K.; Hirota, K.; Hashimoto, K. J. Am. Chem. Soc. 2008, 130, 7812-7813.
17. Ishihara, Y.; Bazzi, H. S.; Toader, H. S.; Godin, F.; Sleiman, H. F. Chem.-Eur. J. 2007, 16, 4560-4571.
18. Lo, P. K.; Sleiman, H. F. Macromolecules 2008, 41, 5590-5603.
19. Molecular models for the H-bond alignment of template 2 with daughter strand 4t are described in the Supporting Information.
20. See Supporting Information.
21. 9 DAP units self-associate only weakly.