A catalytically active, permanently microporous MOF with metalloporphyrin struts

Journal of the American Chemical Society

Volumn 131, Issue 12, 2009, Pages 4204-4205

  Shultz, Abraham M ^a   Farha, Omar K ^a   Hupp, Joseph T ^a   Nguyen, Sonbinh T ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BUILDING BLOCK; HIGH YIELD; LEWIS ACIDIC; METAL ORGANIC FRAMEWORK; METALLOPORPHYRIN; MICROPOROUS; SUPRAMOLECULAR SYSTEMS; TETRAKIS; TRANSFER REACTION;

BENZENE; MICROPOROSITY; STRUTS; ZINC;

PORPHYRINS;

DICARBOXYLIC ACID DERIVATIVE; METAL ORGANIC FRAMEWORK; METALLOPORPHYRIN; NICOTINYL ALCOHOL; ZINC PHOSPHATE;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CRYSTAL STRUCTURE; POROSITY; SYNTHESIS; X RAY DIFFRACTION;

EID: 67749145470     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja900203f     Document Type: Article

References (33)

1. For recent reviews, see: Collins, D. J.; Zhou, H.-C. J. Mater. Chem. 2007. 17, 3154-3160.
2. (b) Ferey, G. Chem. Soc. Rev. 2008, 37, 191-214.
3. See, for example: (a) Farha, O. K.; Mulfort, K. L.; Thorsness, A. M.; Hupp, J. T. J. Am. Chem. Soc. 2008, 130, 8598-8599.
4. (b) Gadzikwa, T.; Lu, G.; Stern, C. L.; Wilson, S. R.; Hupp, J. T.; Nguyen, S. T. Chem. Commun. 2008, 5493-5495.
5. (a) Nouar, F.; Eubank, J. F.; Bosquet, T.; Wojitas, L.; Zaworotko, M. J.; Eddaoudi, M. J. Am. Chem. Soc. 2008, 130, 1833-1835.
6. (b) Chen, B.; Ockwig, N. W.; Millard, A. R.; Contreras, D. S.; Yaghi, O. M. Angew. Chem., Int. Ed. 2005, 44, 4745-4749.
7. (c) Dinca, M.; Dailly, A.; Liu, Y.; Brown, C. M.; Neumann, D. A.; Long, J. R. J. Am. Chem. Soc. 2006, 128, 16876-16883.
8. (d) Latroche, M.; Surble, S.; Serre, C.; Mellot-Draznieks, C.; Llewellyn, P. L.; Lee, H.; Chang, J.; Jhung, S. H.; Ferey, G. Angew. Chem., Int. Ed. 2006, 45, 8227-8231.
9. (e) Mulfort, K. L.; Hupp, J. T. J. Am. Chem. Soc. 2007, 129, 9604-9605.
10. (f) Farha, O. K.; Spokoyny, A. M.; Mulfort, K. L.; Hawthorne, M. F.; Mirkin, C. A.; Hupp, J. T. J. Am. Chem. Soc. 2007, 129, 12680-12681.
11. (a) Lee, E. Y.; Jang, S. Y.; Suh, M. P. J. Am. Chem. Soc. 2005, 127, 6374-6381.
12. (b) Dinca, M.; Long, J. R. J. Am. Chem. Soc. 2005, 127, 9376-9377.
13. (c) Snurr, R. Q.; Hupp, J. T.; Nguyen, S. T. AIChE J. 2004, 50, 1090-1095.
14. (d) Bae, Y. S.; Mulfort, K. L.; Frost, H.; Ryan, P.; Punnathanam, S.; Broadbelt, L. J.; Hupp, J. T.; Snurr, R. Q. Langmuir 2008, 24, 8592-8598.
15. (e) Bae, Y. S.; Farha, O. K.; Spokoyny, A. M.; Mirkin, C. A.; Hupp, J. T.; Snurr, R. Q. Chem. Commun. 2008, 4135-4137.
16. (f) Chen, B.; Liang, C.; Yang, J.; Contreras, D. S.; Clancy, Y. L.; Lobkovsky, E. B.; Yaghi, O. M.; Dai, S. Angew. Chem., Int. Ed. 2006, 45, 1390-1393.
17. See, for example: (a) Cho, S.-H.; Ma, B.; Nguyen, S. T.; Hupp, J. T.; Albrecht-Schmitt, T. E. Chem. Commun. 2006, 2563-2565.
18. (b) Hu, A.; Ngo, H. L.; Lin, W. J. Am. Chem. Soc. 2003, 125, 11490-11491.
19. (c) Wu, C.-D.; Hu, A.; Zhang, L.; Lin, W. J. Am. Chem. Soc. 2005, 127, 8940-8941.
20. (d) Alkordi, M. H.; Liu, Y.; Larsen, R. W.; Eubank, J. F.; Eddaoudi, M. J. Am. Chem. Soc. 2008, 130, 12639-12641.
21. (e) Horike, S.; Dincǎ, M.; Tamaki, K.; Long, J. R. J. Am. Chem. Soc. 2008, 130, 5854-5855.
22. Metalloporphyrins in Catalytic Oxidations; Sheldon, R. A., Ed.; Marcel Dekker: New York, 1994.
23. See, for example: (a) Choi, E.-Y.; Barron, P. M.; Novotny, R. W.; Son, H.-T.; Hu, C.; Choe, W. Inorg. Chem. 2009, 48, 426-428.
24. (b) Lin, K.-J. Angew. Chem., Int. Ed. 1999, 38, 2730-2732.
25. (c) Pan, L.; Kelly, S.; Huang, X.; Li, J. Chem. Commun. 2002, 2334-2335.
26. (d) Abrahams, B. F.; Hoskins, B. F.; Michail, D. M.; Robson, R. Nature 1994, 369, 727-729.
27. Suslick, K. S.; Bhyrappa, P.; Chou, J.-H.; Kosal, M. E.; Nakagaki, S.; Smithenry, D. W.; Wilson, S. R. Acc. Chem. Res. 2005, 38, 263-291.
28. Farha, O. K.; Mulfort, K. L.; Hupp, J. T. Inorg. Chem. 2008, 47, 10223-10225.
29. See, for example: Ma, B.-Q.; Mulfort, K. L.; Hupp, J. T. Inorg. Chem. 2005, 44, 4912-4914.
30. 2/g) should be observable. The reasons for the discrepancy are not clear. We note, however, that the more important property here is substrate accessibility of catalytic sites.
31. (a) Mackay, L. G.; Wylie, R. S.; Sanders, J. K. M. J. Am. Chem. Soc. 1994, 116, 3141-3142.
32. (b) Oliveri, C. G.; Gianneschi, N. C.; Nguyen, S. T.; Mirkin, C. A.; Stern, C. L.; Wawrzak, Z.; Pink, M. J. Am. Chem. Soc. 2006, 128, 16286-16296.
33. However, when aggressive stirring was used (but not when controlled rocking was used), catalysis was observed after a lengthy induction period (see the SI). The catalysis can be ascribed to fragmentation of the MOF and exposure of zinc sites that otherwise play only a structural role.