Thermodynamics of supersaturated solutions: From ternary electrolyte+solute+H2O to binary solute+H2O systems

Chemical Engineering Science

Volumn 64, Issue 18, 2009, Pages 3983-3995

  Han, Guangjun ^a   Tan, R B H ^a,b  

^a INSTITUTE OF CHEMICAL AND ENGINEERING SCIENCES   (Singapore)

^b NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

Author keywords

Activity; Cell potential; Electrolyte; Solubility; Supersaturated solution; Thermodynamics

Indexed keywords

ACTIVITY; ACTIVITY RATIOS; CELL POTENTIAL; EXPERIMENTAL INVESTIGATIONS; EXPERIMENTAL TECHNIQUES; MEASURED DATA; POTENTIOMETRIC METHODS; SOLUBILITY DATA; SUPERSATURATED SOLUTION; SUPERSATURATED SOLUTIONS; THERMODYNAMIC ACTIVITY; THERMODYNAMIC BEHAVIORS; THERMODYNAMIC CONSISTENCY;

CELL MEMBRANES; CRYSTALLIZATION; ELECTROLYSIS; ELECTROLYTES; RELIABILITY ANALYSIS; SOLUBILITY; TERNARY SYSTEMS;

THERMODYNAMICS;

EID: 67749143580     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2009.05.040     Document Type: Article

References (40)

1. Bates R.G., Dickson A.G., Gratzl M., Hrabeczy-Pall A., Lindner E., and Pungor E. Determination of mean activity coefficients with ion-selective electrodes. Anal. Chem. 55 (1983) 1275-1280
2. Breil M.P., Mollerup J.M., Rudolph E.S., Ottens M., and van der Wielen L.A.M. Determination of the activity coefficients of glycylglycine and glycyl-L-alanine in sodium chloride solutions by an electrochemical cell with ion-selective electrodes: experimental measurements and thermodynamic theory. Fluid Phase Equilib. 191 (2001) 127-140
3. Chan M.N., Choi M.Y., Ng N.L., and Chan C.K. Hygroscopicity of water-soluble organic compounds in atmospheric aerosols: amino acids and biomass burning derived organic species. Environ. Sci. Technol. 39 (2005) 1555-1562
4. Chan M.N., Kreidenweis S.M., and Chan C.K. Measurements of the hygroscopic and deliquescence properties of organic compounds of different solubilities in water and their relationship with cloud condensation nuclei activities. Environ. Sci. Technol. 42 (2008) 3602-3608
5. Chang Y.C., and Myerson A.S. Diffusivity of glycine in concentrated saturated and supersaturated aqueous solutions. A.I.Ch.E. J. 32 (1986) 1567-1569
6. Cohen M.D., Flagan R.C., and Seinfeld J.H. Studies of concentrated electrolyte solutions using the electrodynamic balance. 1. Water activities for single-electrolyte solutions. J. Phys. Chem. 91 (1987) 4563-4574
7. Cohn E.J., and Edsall T.J. Proteins, Amino Acids and Peptides as Ions and Dipolar Ions (1943), Hafner, New York
8. Doki N., Yokota M., Kido K., Sasaki S., and Kubota N. Reliable and selective crystallization of the metastable α-form glycine by seeding. Cryst. Growth Des. 4 (2004) 103-107
9. Ellerton H.D., Reinfelds G., Mulcahy D.E., and Dunlop P.J. Activity, density, and relative viscosity data for several amino acids, lactamide, and raffinose in aqueous solution at 25 °C. J. Phys. Chem. 68 (1964) 398-402
10. 4 on the solubility of glycine and DL-alanine in water at 298.15 K. Ind. Eng. Chem. Res. 44 (2005) 8892-8898
11. Givand J.C., Teja A.S., and Rousseau R.W. Effect of relative solubility on amino acid crystal purity. A.I.Ch.E. J. 47 (2001) 2705-2712
12. Grant M.L. Effects of thermodynamic nonideality in protein crystal growth. J. Cryst. Growth 209 (2000) 130-137
13. Hamer W.J., and Wu Y. Osmotic coefficients and mean activity coefficients of uni-univalent electrolytes in water at 25 °C. J. Phys. Chem. Ref. Data 1 (1972) 1047-1077
14. Han G., and Tan R.B.H. A steady state shifting technique for the potentiometric method: application to supersaturated solutions. Chem. Eng. Sci. 61 (2006) 6530-6539
15. Izmailov A.F., and Myerson A.S. Thermodynamic and statistical studies of supersaturated ternary solutions. Phys. Rev. E 60 (1999) 3211-3218
16. Kelly J.T., Wexler A.S., Chan C.K., and Chan M.N. Aerosol thermodynamics of potassium salts, double salts, and water content near the eutectic. Atmos. Environ. 42 (2008) 3717-3728
17. 2O+NaCl+DL-Alanine at 25 °C. Ind. Eng. Chem. Res. 35 (1996) 2735-2742
18. Khoshkbarchi M.K., and Vera J.H. Effect of NaCl and KCl on the solubility of amino acids in aqueous solutions at 298.2 K: measurements and modeling. Ind. Eng. Chem. Res. 36 (1997) 2445-2451
19. Knezic D., Zaccaro J., and Myerson A.S. Thermodynamic properties of supersaturated protein solutions. Cryst. Growth Des. 4 (2004) 199-208
20. Koop T., Luo B., Tsias A., and Peter T. Water activity as the determinant for homogeneous ice nucleation in aqueous solutions. Nature 406 (2000) 611-614
21. Lampreia I.M.S., Magalhaes S., Rodrigues S., and Mendonca A. Solubility of proline-leucine dipeptide in water and in aqueous sodium chloride solutions from T=(288.15-313.15) K. J. Chem. Thermodyn. 38 (2006) 240-244
22. Larson M.A., and Garside J. Solute clustering in supersaturated solutions. Chem. Eng. Sci. 41 (1986) 1285-1289
23. Mohan R., and Myerson A.S. Growth kinetics: a thermodynamic approach. Chem. Eng. Sci. 57 (2002) 4277-4285
24. Na H., Arnold S., and Myerson A.S. Water activity in supersaturated aqueous solutions of organic solutes. J. Cryst. Growth 149 (1995) 229-235
25. Ohgaki K., Makihara Y., and Morishita M. Solute clusters in aqueous citric-acid solutions. Chem. Eng. Sci. 46 (1991) 3283-3287
26. Ohgaki K., Hirokawa N., and Ueda M. Heterogeneity in aqueous solutions: electron microscopy of citric acid solutions. Chem. Eng. Sci. 47 (1992) 1819-1823
27. Öncül A.A., Sundmacher K., and Thévenin D. Numerical investigation of the influence of the activity coefficient on barium sulphate crystallization. Chem. Eng. Sci. 60 (2005) 5395-5405
28. Peng C., Chan M.N., and Chan C.K. The hygroscopic properties of dicarboxylic and multifunctional acids: measurements and UNIFAC predictions. Environ. Sci. Technol. 35 (2001) 4495-4501
29. Phang S., and Steel B.J. Activity coefficients from e.m.f. measurements using cation-responsive glass electrode. NaCl+glycine+water at 273.15, 283.15, 298.15 and 323.15 K. J. Chem. Thermodyn. 6 (1974) 537-548
30. Pradhan A.A., and Vera J.H. Effect of anions on the solubility of zwitterionic amino acids. J. Chem. Eng. Data. 45 (2000) 140-143
31. Prausnitz J.M., Lichtenthaler R.N., and Azevedo E.G. Molecular thermodynamics of fluid-phase equilibria. fourth ed (1999), Prentice-Hall PTR, New Jersey
32. Rak M., Eremin N.N., Eremina T.A., Kuznetsov O.V.A., Furmanova N.G., and Efremova E.P. On the mechanism of impurity influence on growth kinetics and surface morphology of KDP crystals-I: defect centres formed by bivalent and trivalent impurity ions incorporated in KDP structure-theoretical study. J. Cryst. Growth 273 (2005) 577-585
33. Rodriguez-Raposo R., Fernandez-Merida L., and Esteso M.A. Activity coefficients in (electrolyte+amino acid) (aq). The dependence of the ion-zwitterion interactions on the ionic strength and on the molality of the amino acid analysed in terms of Pitzer's equation. J. Chem. Thermodyn. 26 (1994) 1121-1128
34. Sakai H., Hosogai H., and Kawakita T. Transformation of α-glycine to γ-glycine. J. Cryst. Growth 116 (1991) 421-426
35. Scherier E.E., and Robison R.A. A study of free energy relationships in some amino acid-sodium chloride-water systems. J. Biol. Chem. 246 (1971) 2870-2874
36. Smith P.K., and Smith E.R.B. Thermodynamic properties of solutions of amino acids and related substances. ii. The activity of aliphatic amino acids in aqueous solution at twenty-five degrees. J. Biol. Chem. 121 (1937) 607-613
37. Soto-Campus A.M., Khoshkbarchi M.K., and Vera J.H. Effect of the anion and the cation of an electrolyte on the activity coefficient of DL-Alanine in aqueous solutions. Fluid Phase Equilib. 142 (1998) 193-204
38. Tjahjono M., Guo L., and Garland M. The development of a response surface model for the determination of infinite dilution partial molar volumes and excess volumes from dilute multi-component data alone. Implications for the characterization of non-isolatable solutes in complex homogeneous reactive systems. Chem. Eng. Sci. 60 (2005) 3239-3249
39. Towler C.S., Davey R.J., Lancaster R.W., and Price C.J. Impact of molecular speciation on crystal nucleation in polymorphic systems: the conundrum of γ-glycine and molecular 'self poisoning'. J. Am. Chem. Soc. 126 (2004) 13347-13353
40. Zemaitis, J.F., Clark, D.M., Refal, M., Scrivner, N.C., 1986. Handbook of aqueous electrolyte thermodynamics. Design Institute for Physical Property Data sponsored by A.I.Ch.E. New York.