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2+, 3a, and 3b, see the Supporting Information.
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2+, 3a, and 3b, see the Supporting Information.
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w = 0.1425 (all data), GOF = 1.038.
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w = 0.1425 (all data), GOF = 1.038.
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A related homoaromatic cyclotetrasilenylium derivative was recently isolated, see
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However, given the characteristic high-field resonances of the bridgehead silicons in 3a,b and unimportant alternation of bond orders and NPA charges in 3b′ vs 4, it is likely that the extent of the homoaromatic contribution B is not predominant.
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However, given the characteristic high-field resonances of the bridgehead silicons in 3a,b and unimportant alternation of bond orders and NPA charges in 3b′ vs 4, it is likely that the extent of the homoaromatic contribution B is not predominant.
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