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The porosity of the alumina membrane is 25-50% according to the manufacturer. For the silica material around 50% of the are pores, estimated from TEM micrographs. The density of the alumina (without pores) is about 3.98 g/cm3 (α-alumina, and the density of the silica (without pores) is about 2.65 g/cm3 (quarz, Hence, from 1 cm 3 composite material, 0.75-0.5 cm3 originate from alumina material while only 0.125-0.25 cm3 is silica material. With the respective densities, 1 cm3 composite contains 0.33-0.66 g silica and 2.98-1.99 g alumina depending on the original membrane porosity (25-50, This corresponds to a silica content of 10-25 wt, in the composite. Thus, only one-fourth to one-tenth of the specific surface area of pure mesoporous material can be obtained for the composite highly ordered SB A-15 materials show specific surface areas of 500-800 m2/g; for the corresponding composite, surfac
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2/g can be expected). Note that the discussed weight correction does not take into account possible incomplete filling of the AAM, pore-blocking effects due to the long channel system, or reduction of the surface area due to formation of relatively large pores in the confined environment (see text).
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