-
5
-
-
33645387715
-
-
Shekhar, S.; Ryberg, P.; Hartwig, J. F.; Mathew, J. S.; Blackmond, D. G.; Strieter, E. R.; Buchwald, S. L. J. Am. Chem. Soc. 2006, 128, 3584.
-
(2006)
J. Am. Chem. Soc
, vol.128
, pp. 3584
-
-
Shekhar, S.1
Ryberg, P.2
Hartwig, J.F.3
Mathew, J.S.4
Blackmond, D.G.5
Strieter, E.R.6
Buchwald, S.L.7
-
6
-
-
33644962633
-
-
Shekhar, S.; Ryberg, P.; Hartwig, J. F. Org. Lett. 2006, 8, 851.
-
(2006)
Org. Lett
, vol.8
, pp. 851
-
-
Shekhar, S.1
Ryberg, P.2
Hartwig, J.F.3
-
7
-
-
33745506850
-
-
Mathew, J. S.; Klussmann, M.; Iwamura, H.; Valera, F.; Futran, A.; Emanuelsson, E. A. C.; Blackmond, D. G. J. Org. Chem. 2006, 71, 4711.
-
(2006)
J. Org. Chem
, vol.71
, pp. 4711
-
-
Mathew, J.S.1
Klussmann, M.2
Iwamura, H.3
Valera, F.4
Futran, A.5
Emanuelsson, E.A.C.6
Blackmond, D.G.7
-
8
-
-
0041519420
-
-
Lewis, A. K. K.; Caddick, S.; Cloke, F. G. N.; Billingham, N. C.; Hitchcock, P. B.; Leonard, J. J. Am. Chem. Soc. 2003, 125, 10066.
-
(2003)
J. Am. Chem. Soc
, vol.125
, pp. 10066
-
-
Lewis, A.K.K.1
Caddick, S.2
Cloke, F.G.N.3
Billingham, N.C.4
Hitchcock, P.B.5
Leonard, J.6
-
9
-
-
0034679009
-
-
Alcazar-Roman, L. M.; Hartwig, J. F.; Rheingold, A. L.; Lable-Sands, L. M.; Guzei, I. A. J. Am. Chem. Soc. 2000, 122, 4618.
-
(2000)
J. Am. Chem. Soc
, vol.122
, pp. 4618
-
-
Alcazar-Roman, L.M.1
Hartwig, J.F.2
Rheingold, A.L.3
Lable-Sands, L.M.4
Guzei, I.A.5
-
11
-
-
34748881599
-
-
For the dependence on [BINAP, the graph gives 1/kobsd in the range of 10-40, but kobsd must be on the order of 10-4, on the basis of the dependence on [PhBr] and the latter results of ref 6. However, when this correction is made, the [BINAP] and [PhBr] variation studies give two distinctly different lines on a plot of l/kobsd versus [BINAP/[PhBr, When the k4 term is insignificant, eq 2 predicts one line. On the basis of the more recent results, the original [PhBr] dependence is erroneous for some reason; no change in [BINAP] during the [PhBr] variation will make the results internally consistent. There is an analogous problem with the PhOTf data. Either [BINAP] is double the 1.7 × 10-4 M value given for the [PhOTf] study, or [PhOTf] is double the 2.26 × 10-4 M value given for the [BINAP] study
-
-4 M value given for the [BINAP] study.
-
-
-
-
12
-
-
34748878085
-
-
The data have been extracted from published graphs and therefore are not the exact raw data but closely representative of the experimental results
-
The data have been extracted from published graphs and therefore are not the exact raw data but closely representative of the experimental results.
-
-
-
-
16
-
-
33751386097
-
-
H) plot.
-
H) plot.
-
-
-
-
19
-
-
0348134860
-
-
Int. Ed, and references therein
-
Hills, I. D.; Netherton, M. R.; Fu, G. C. Angew. Chem., Int. Ed. 2003, 42, 5749 and references therein.
-
(2003)
Angew. Chem
, vol.42
, pp. 5749
-
-
Hills, I.D.1
Netherton, M.R.2
Fu, G.C.3
-
20
-
-
34748865794
-
-
4 pathway is neither required nor inconsistent with the data for PhOTf.
-
4 pathway is neither required nor inconsistent with the data for PhOTf.
-
-
-
-
21
-
-
34748890288
-
-
obsd always represents the same quantity here.
-
obsd always represents the same quantity here.
-
-
-
-
23
-
-
34748922696
-
-
This estimate is based on the rate constant for solvolysis of cis-Pt-(PEt3)2(Ph)(Cl) in ethanol of 0.04 s -1, Basolo, F, Chatt, J, Gray, H. B, Pearson, R. G, Shaw, B. L. J. Chem. Soc. 1961, 2207
-
-1. (Basolo, F.; Chatt, J.; Gray, H. B.; Pearson, R. G.; Shaw, B. L. J. Chem. Soc. 1961, 2207).
-
-
-
-
24
-
-
0041935947
-
-
-1.
-
-1.
-
-
-
-
25
-
-
34748869397
-
-
-1 have the same ΔH‡.
-
-1 have the same ΔH‡.
-
-
-
-
26
-
-
34748858353
-
-
2)[NHC]} using numerical integration to obtain the time dependence of the concentrations.
-
2)[NHC]} using numerical integration to obtain the time dependence of the concentrations.
-
-
-
-
27
-
-
34748813458
-
-
2 = 6.6, as shown in the Supporting Information.
-
2 = 6.6, as shown in the Supporting Information.
-
-
-
-
28
-
-
0034712161
-
-
The nature of the catalytic species formed from these reagents was studied by Wolfe and Buchwald: Wolfe, J. P.; Buchwald, S. L. J. Org. Chem. 2000, 65, 1144.
-
The nature of the catalytic species formed from these reagents was studied by Wolfe and Buchwald: Wolfe, J. P.; Buchwald, S. L. J. Org. Chem. 2000, 65, 1144.
-
-
-
-
29
-
-
34748879815
-
-
The calculations assume that the total Pd is 5 mM as in ref 25 and there is no excess BINAP.
-
The calculations assume that the total Pd is 5 mM as in ref 25 and there is no excess BINAP.
-
-
-
|