Solvent-dependent cage dynamics of small nonpolar radicals: Lessons from the photodissociation and geminate recombination of alkylcobalamins

Journal of Physical Chemistry A

Volumn 113, Issue 30, 2009, Pages 8513-8522

  Stickrath, Andrew B ^a   Carroll, Elizabeth C ^a   Dai, Xiaochuan ^a   Harris, D Ahmasi ^a   Rury, Aaron ^a   Smith, Broc ^a   Tang, Kuo Chun ^a   Wert, Jonathan ^a   Sension, Roseanne J ^a  

^a UNIVERSITY OF MICHIGAN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADENOSYLCOBALAMIN; ALKYL RADICALS; CAGE DYNAMICS; CALCULATED VALUES; DIFFUSION COEFFICIENTS; DIFFUSION CONSTANT; GEMINATE RECOMBINATION; HYDRODYNAMIC MODEL; METHYL RADICAL; NON-POLAR; ON TIME; PICOSECONDS; QUANTITATIVE AGREEMENT; RADICAL PAIR; SOLVENT DEPENDENCE; SOLVENT FLUIDITY; STOKES EINSTEIN EQUATIONS; SUCROSE SOLUTION; TEMPERATURE RANGE; TIME-RESOLVED TRANSIENT ABSORPTION SPECTROSCOPY; ULTRA-FAST; UNIMOLECULAR;

ABSORPTION SPECTROSCOPY; EQUATIONS OF MOTION; ETHYLENE; ETHYLENE GLYCOL; FLUID DYNAMICS; FLUIDITY; PHOTODISSOCIATION; PHOTOEXCITATION; PHOTOLYSIS; SOLVENTS; SUGAR (SUCROSE); WATER ABSORPTION;

RATE CONSTANTS;

CYANOCOBALAMIN; ETHYLENE GLYCOL; FREE RADICAL; SOLVENT; SUCROSE; WATER;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; PHOTOCHEMISTRY; QUANTUM THEORY; TEMPERATURE; THERMODYNAMICS;

ETHYLENE GLYCOL; FREE RADICALS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; PHOTOCHEMISTRY; QUANTUM THEORY; SOLVENTS; SUCROSE; TEMPERATURE; THERMODYNAMICS; VITAMIN B 12; WATER;

EID: 67651152779     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9017986     Document Type: Article

References (80)

1. Lampe, F. W.; Noyes, R. M. J. Am. Cham. Soc. 1954, 76, 2140-2144.
2. Noyes, R. M. J. Chem. Phys. 1954, 22, 1349-1359.
3. Noyes, R. M. J. Am. Chem. Soc. 1955, 77, 2042-2045.
4. Gerards, L. E. H.; Bulthuis, H.; de Bolster, M. W. G.; Balt, S. Inorg. Chim. Acta 1991, 190, 47-53.
5. Gerards, L. E. H.; De Bolster, M. W. G.; Bait, S. Inorg. Chim. Acta 1992, 192, 287-290.
6. Hippler, H.; Troe, J.; Luther, K. Chem. Phys. Lett. 1972, 16, 174
7. Nesbitt, D. J.; Hynes, J. T. J. Chem. Phys. 1982, 77, 2130-2143.
8. Balk, M. W.; Brooks, C. L.; Adelman, S. A. J. Chem. Phys. 1983, 79, 804-815.
9. Kelley, D. F.; Abulhaj, N. A.; Jang, D. J. J. Chem. Phys. 1984, 80, 4105-4109.
10. Otto, B.; Schroeder, I.; Troe, J. J. Chem. Phys. 1984, 81, 202-213.
11. Berg, M.; Harris, A. L.; Harris, C. B. Phys. Rev. Lett. 1985, 54, 951-954.
12. Abulhaj, N. A.; Kelley, D. F. J. Chem. Phys. 1986, 84, 1335-1344.
13. Harris, A. L.; Berg, M.; Harris, C. B. J. Chem. Phys. 1986, 84, 788-806.
14. Paige, M. E.; Russell, D. I.; Harris, C. B. J. Chem. Phys. 1986, 85, 3699-3700.
15. Smith, D. E.; Harris, C. B. J. Chem. Phys. 1987, 87, 2709-2715.
16. Phtlippoz, J. M.; Monot, R.; Vandenbergh, H. J. Chem. Phys. 1990, 93, 8676-8681.
17. Xu, X. B.; Lingle, R.; Yu, S. C.; Chang, Y. J.; Hopkins, J. B. J. Chem. Phys. 1990, 92, 2106-2107.
18. Besnard, M.; Delcampo, N.; Deviolet, P. R.; Rulliere, C. Laser Chem. 1991, 11, 109-118.
19. Yan, Y. J.; Whitnell, R. M.; Wilson, K. R.; Zewail, A. H. Chem. Phys. Lett. 1992, 193, 402-412.
20. Scott, T. W.; Liu, S. N. J. Phys. Chem. 1989, 93, 1393-1396.
21. Scott, T. W.; Doubleday, C. Chem. Phys. Lett. 1991, 178, 9-18.
22. Covert, K. J.; Askew, E. F.; Grunkemeier, J.; Koenig, T.; Tyler, D. R. J. Am. Chem. Soc. 1992, 114, 10446-10448.
23. Lindfors, B. E.; Male, J. L.; Covert, K. J.; Tyler, D. R. Chem. Commun. 1997, 1687-1688.
24. Male, J. L.; Lindfors, B. E.; Covert, K. J.; Tyler, D. R. J. Am. Chem. Soc. 1998, 120, 13176-13186.
25. Braden, D. A.; Parrack, E. E.; Tyler, D. R. Coord. Chem. Rev. 2001, 211, 279-294.
26. Schutte, E.; Weakley, T. J. R.; Tyler, D. R. J. Am. Chem. Soc. 2003, 125, 10319-10326.
27. Harris, J. D.; Oelkers, A. B.; Tyler, D. R. J. Organomet. Chem. 2007, 692, 3261-3266.
28. Harris, J. D.; Oelkers, A. B.; Tyler, D. R. J. Am. Chem. Soc. 2007, 129, 6255-6262.
29. Oelkers, A. B.; Scatena, L. F.; Tyler, D. R. J. Phys. Chem. A 2007, 111, 5353-5360.
30. Oelkers, A. B.; Schutte, E. J.; Tyler, D. R. Phptochem. Photobiol. Sci. 2008, 7, 228-234.
31. Oelkers, A. B.; Tyler, D. R. Phptochem. Photobiol. Sci. 2008, 7, 1386-1390.
32. Bultmann, T.; Ernsting, N. P. J. Phys. Chem. 1996, 100, 19417-19424.
33. Lochschmidt, A.; Eilers-König, N.; Heineking, N.; Ernsting, N. P. J. Phys. Chem. A 1999, 103, 1776-1784.
34. Bagdasar'yan, K. S. Russ. Chem. Rev. 1984, 53, 623-639.
35. Shin, K. J.; Kapral, R. J. Chem. Phys. 1978, 69, 3685-3696.
36. Collins, F. C. J. Coll. Sci. 1950, 5, 499-505.
37. Collins, F. C.; Kimball, G. E. J. Colloid Sci. 1949, 4, 422-437.
38. Cole, A. G.; Yoder, L. M.; Shiang, J. J.; Anderson, N. A.; Walker II, L. A.; Banaszak Holl, M. M.; Sension, R. J. J. Am. Chem. Soc. 2002, 124, 434-441.
39. Walker, L. A., II; Jarrett, J. T.; Anderson, N. A.; Pullen, S. H.; Matthews, R. G.; Sension, R. J. J. Am. Chem. Soc. 1998, 120, 3597-3603.
40. Walker, L. A., II; Shiang, J. J.; Anderson, N. A.; Pullen, S. H.; Sension, R. J. J. Am. Chem. Soc. 1998, 120, 7286-7292.
41. Shiang, J. J.; Walker, L. A. U.; Anderson, N. A.; Cole, A. G.; Sension, R. J. J. Phys. Chem. B 1999, 103, 10532-10539.
42. Yoder, L. M.; Cole, A. G.; Walker, L. A. II; Sension, R. J. J. Phys. Chem. B 2001, 105, 12180-12188.
43. Sension, R. J.; Harris, D. A.; Cole, A. G. J. Phys. Chem. B 2005, 109, 21954-21962.
44. Sension, R. J.; Harris, D. A.; Stickrath, A.; Cole, A. G.; Fox, C. C.; Marsh, E. N. G. J. Phys. Chem. B 2005, 109, 18146-18152.
45. Hams, D. A.; Stickrath, A. B.; Carroll, E. C.; Sension, R. J. J. Am. Chem. Soc. 2007, 129, 7578-7585.
46. Sun, T.; Teja, A. S. J. Chem. Eng. Data 2003, 48, 198-202.
47. Bohne, D.; Fischer, S.; Obermeier, E. Buns-Ges. Phys. Chem. Chem. Phys. 1984, 88, 739-742.
48. Barber, E. J. NCI Monograph 1966, 21, 219-239.
49. Bouchard, C.; Grandjean, B. P. A. Food Sci. Technol. 1995, 28, 157-159.
50. Masuda, Y. J. Phys. Chem. A 2001, 105, 2989-2996.
51. Dutt, G. B.; Saehdeva, A. J. Chem. Phys. 2003, 118, 8307-8314.
52. Dutt, G. B.; Raman, S. J. Chem. Phys. 2001, 114, 6702-6713.
53. Dutt, G. B.; Krishna, G. R.; Raman, S. J. Chem. Phys. 2001, 115, 4732-1741.
54. Dutt, G. B.; Krishna, G. R. J. Chem. Phys. 2000, 112, 4676-4682.
55. Dutt, G. B. J. Chem. Phys. 2000, 113, 11154-11158.
56. Dutt, G. B.; Srivatsavoy, V. J. P.; Sapre, A. V. J. Chem. Phys. 1999, 111, 9705-9710.
57. Moog, R. S.; Ediger, M. D.; Boxer, S. G.; Fayer, M. D. J. Phys. Chem. 1982, 86, 4694-4700.
58. Rice, S. A.; Kenney-Wallace, G. A. Chem. Phys. 1980, 47, 161-170.
59. Dyke, B. P.; Hedwig, G. R. J. Chem. Thermodyn. 2008, 40, 957-965.
60. Kundu, A.; Kishore, N. J. Solution Chem. 2002, 31, 477-498.
61. Nishida, K.; Ando, Y.; Kawamura, H. Colloid Polym. Sci. 1983, 261, 1435-1536.
62. Bait, S.; Vanherk, A. M. Inorg. Chim. Acta 1986, 125, 27-30.
63. La-Scalea, M. A.; Souza Menezes, C. M.; Ferreira, E. I. J. Mol. Struct: THEOCHEM 2005, 730, 111-120.
64. Connors, T. F.; Arena, J. V.; Rusling, J. F. J. Phys. Chem. 1988, 92, 2810-2816.
65. Peirano, F.; Vincent, T.; Guibal, E. J. Appl. Polym. Sci. 2007, 107, 3568-3578.
66. Eyring, H. J. Chem. Phys. 1936, 4, 283-291.
67. Hsu, C. C.; Eyring, H. Proc. Natl. Acad. Sci.U.S.A. 1972, 69, 1342-1345.
68. Akgerman, A.; Gainer, J. L. Ind. Eng. Chem. Fundam. 1972, 11, 373-379.
69. Akgerman, A.; Gainer, J. L. J. Chem. Eng. Data 1972, 17, 372-377.
70. Akgerman, A. Ph.D. Dissertation University of Virginia, 1971.
71. Glasstone, W.; Laidler, K. J.; Eyring, H Theory of Rate Processes; McGraw-Hill; New York. 1941; pp. 477-551.
72. Northrup, S. H.; Hynes, J. T. J. Chem. Phys. 1979, 71, 871-883.
73. Koenig, T.; Scott, T. W.; Franz, J. A. ACS Symp. Ser. 1990, No. 428, 113-132.
74. Northrup, S. H.; Hynes, J. T. J. Chem. Phys. 1979, 71, 884-893.
75. Cukier, R. I.; Kapral, R.; Lebenhaft, J. R.; Mehaffey, J. R. J. Chem. Phys. 1980, 73, 5244-5253.
76. Cukier, R. I.; Kapral, R.; Mehaffey, J. R. J. Chem. Phys. 1981, 74, 2494-2504.
77. Cukier, R. I.; Mehaffey, J. R.; Kapral, R. J. Chem. Phys. 1978, 69, 4962-4975.
78. Ali, D. P.; Miller, W. H. Chem. Phys. Lett. 1984, 105, 501-505.
79. Schell, M.; Kapral, R.; Cukier, R. I. J. Chem. Phys. 1981, 75, 5879-5882.
80. Brooks, C. L.; Berkowitz, M.; Adelman, S. A. J. Chem. Phys. 1980, 73, 4353-4364.