Femtosecond pump-probe transient absorption study of the photolysis of [Cp′Mo(CO) 3] 2 (Cp′ = η 5-C 5H 4CH 3): Role of translational and rotational diffusion in the radical cage effect

Journal of Physical Chemistry A

Volumn 111, Issue 25, 2007, Pages 5353-5360

  Oelkers, Alan B ^a   Scatena, Lawrence F ^a   Tyler, David R ^a  

^a UNIVERSITY OF OREGON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FEMTOSECOND PUMP PROBES; ROTATIONAL DIFFUSION; SOLVENT VISCOSITY;

ABSORPTION; DIFFUSION; DIMERS; MOLYBDENUM COMPOUNDS; PHOTODISSOCIATION; PHOTOLYSIS; VISCOSITY;

ORGANOMETALLICS;

EID: 34547371360     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp064849z     Document Type: Article

References (63)

1. Lorand, J. P. Prog. Inorg. Chem, 1972, 17, 207-325.
2. Franck, J.; Rabinowitch, E. Trans. Faraday. Soc. 1934, 30, 120-131.
3. Noyes, R. M. J. Chem. Phys. 1955, 23, 1982.
4. Noyes, R. M. J. Am. Chem. Soc. 1955, 77, 2042-2045.
5. Noyes, R. M. J. Am. Chem. Soc. 1956, 78, 5486-5490.
6. Zimmerman, J.; Noyes, R. M. J. Chem. Phys. 1950, 18, 658-666.
7. Lampe, F. W.; Noyes, R. M. J. Am. Chem. Soc. 1954, 76, 2140-2144.
8. Booth, D.; Noyes, R. M. J. Am. Chem. Soc. 1960, 82, 1868-1872.
9. Meadows, L. F.; Noyes, R. M. J. Am. Chem. Soc. 1960, 82, 1872-1876.
10. Xu, X.; Yu, S. C.; Lingle, R., Jr.; Zhu, H.; Hopkins, J. B. J. Chem. Phys. 1991, 95, 2445-2457.
11. Smith, D. E.; Harris, C. B. J. Chem. Phys. 1987, 87, 2709-2715.
12. Schwartz, B. J.; King, J. C.; Harris, C. B. Understanding Chem. React. 1994, 7, 235-248.
13. Schwartz, B. J.; King, J. C.; Zhang, J. Z.; Harris, C. B. Chem. Phys. Lett. 1993, 203, 503-508.
14. Liu, Q.: Wang, J. K.; Zewail, A. H. Nature (London) 1993, 364, 427-430.
15. Lienau, C.; Zewail, A. H. J. Phys. Chem. 1996, 100, 18629-18649.
16. Scott, T. W.; Doubleday, C., Jr. Chem. Phys. Lett. 1991, 178, 9-18.
17. Hyde, M. G.; Reid, G. D.; Beddard, G. S. Chem. Phys. Lett. 1992, 190, 130-134.
18. Lenderink, E.; Duppen, K.; Wiersma, D. A. Chem. Phys. Lett. 1992, 194, 403-409.
19. Scott, T. W.; Liu, S. N. J. Phys. Chem. 1989, 93, 1393-1396.
20. Bultmann, T.; Ernsting, N. P. J. Phys. Chem. 1996, 100, 19417-19424.
21. Lochschmidt, A.; Eilers-Koenig, N.; Heineking, N.; Ernsting, N. P. J. Phys. Chem. A 1999, 103, 1776-1784.
22. Turro, N. J. Abstracts of Papers, 231st ACS National Meeting, Atlanta, GA, March 26-30, 2006; American Chemical Society: Washington, DC, 2006; ORGN-040.
23. Sivaguru, J.; Saito, H.; Solomon, M. R.; Kaanumalle, L. S.; Poon, T.; Jockusch, S.; Adam, W.; Ramamurthy, V.; Inoue, Y.; Turro, N. J. Photochem. Photobiol. 2006, 82, 123-131.
24. Poon, T.; Turro, N. J.; Chapman, J.; Lakshminarasimhan, P.; Lei, X.; Adam, W.; Bosio, S. G. Org. Lett. 2003, 5, 2025-2028.
25. Turro, N. J.; Buchachenko, A. L.; Tarasov, V. F. Acc. Chem. Res. 1995, 28, 69-80.
26. Zhang, J. Z.; Harris, C. B. J. Chem. Phys. 1991, 95, 4024-4032.
27. Wrighton, M. S.; Ginley, D. S. J. Am. Chem. Soc. 1975, 97, 4246-4251.
28. Meyer, T. J.; Caspar, J. V. Chem. Rev. 1985, 85, 187-218.
29. Bitterwolf, T. E. Coord. Chem. Rev. 2001, 211, 235-254.
30. Levenson, R. A.; Gray, H. B. J. Am. Chem. Soc. 1975, 97, 6042-6047.
31. Scott, S. L.; Espenson, J. H.; Zhu, Z. J. Am. Chem. Soc. 1993, 115, 1789-1797.
32. Yao, Q.; Bakac, A.; Espenson, J. H. Organometallics 1993, 12, 2010-2012.
33. Peters, J.; George, M. W.; Turner, J. J. Organometallics 1995, 14, 1503-1506.
34. Linehan, J. C.; Yonker, C. R.; Addleman, R. S.; Autrey, S. T.; Bays, J. T.; Bitterwolf, T. E.; Daschbach, J. L. Organometallics 2001, 20, 401-407.
35. Hooker, R. H.; Mahmoud, K. A.; Rest, A. J. J. Chem. Soc., Dalton Trans. 1990, 1231-1241.
36. Baker, M. L.; Bloyce, P. E.; Campen, A. K.; Rest, A. J.; Bitterwolf, T. E. J. Chem. Soc., Dalton Trans. 1990, 2825-2832.
37. Hooker, R. H.; Mahmoud, K. A.; Rest, A. J. J. Organomet. Chem. 1983, 254, C25-C28.
38. Mahmoud, K. A.; Rest, A. J.; Alt, H. J. Chem. Soc., Dalton Trans. 1984, 187-197.
39. Waldman, A.; Ruhman, S.; Shaik, S.; Sastry, G. N. Chem. Phys. Lett. 1994, 230, 110-116.
40. Kim, S. K.; Pedersen, S.; Zewail, A. H. Chem. Phys. Lett. 1995, 233, 500-508.
41. Owrutsky, J. C.; Baronavski, A. P. J. Chem. Phys. 1996, 105, 9864-9873.
42. Yang, H.; Snee, P. T.; Kotz, K. T.; Payne, C. K.; Harris, C. B. J. Am. Chem. Soc. 2001, 123, 4204-4210.
43. Manning, A. R.; Hackett, P.; Birdwhistell, R.; Soye, P. Inorg. Synth. 1990, 28, 148-50.
44. Kafka, J. D.; Baer, T. Opt. Lett. 1987, 12, 401-403.
45. Ziolek, M.; Lorenc, M.; Naskrecki, R. Appl. Phys. B: Lasers Opt. 2001, 72, 843-847.
46. Rasmusson, M.; Tarnovsky, A. N.; Akesson, E.; Sundstrom, V. Chem. Phys. Lett. 2001, 335, 201-208.
47. See, for example: Rice, S. A. In Comprehensive Chemical Kinetics; Bamford, C. H., Tipper, C. F. H., Compton, R. G., Eds.; Elsevier: Amsterdam, 1985; Vol. 25.
48. Braden, D. A.; Parrack, E. E.; Tyler, D. R. Coord. Chem. Rev. 2001, 211, 279-294.
49. Kiefer, H. R.; Traylor, T. G. J. Am. Chem. Soc. 1967, 89, 6667-6671.
50. Kodama, S. Bull. Chem. Soc. Jpn. 1962, 35, 827-832.
51. Pryor, W. A.; Smith, K. J. Am. Chem. Soc. 1970, 92, 5403-5412.
52. Smith, W. F., Jr.; Eddy, K. L. Tetrahedron 1970, 26, 1255-1259.
53. Owrutsky, J. C.; Raftery, D.; Hochstrasser, R. M. Annu. Rev. Phys. Chem. 1994, 45, 519-555.
54. Joly, A. G.; Nelson, K. A. Chem. Phys. 1991, 152, 69-82.
55. Steinhurst, D. A.; Baronavski, A. P.; Owrutsky, J. C. Chem. Phys. Lett. 2002, 361, 513-519.
56. George, M. W.; Dougherty, T. P.; Heilweil, E. J. J. Phys. Chem. 1996, 100, 201-206.
57. Harris, A. L.; Brown, J. K.; Harris, C. B. Annu. Rev. Phys. Chem. 1988, 39, 341-366.
58. Elsaesser, T.; Kaiser, W. Annu. Rev. Phys. Chem. 1991, 42, 83-107.
59. Fleming, G. R. Chemical Applications of Ultrafast Spectroscopy; International Series of Monographs on Chemistry 13; Oxford University Press: Oxford, 1986.
60. Adams, R. D.; Collins, D. M.; Cotton, F. A. Inorg. Chem. 1974, 13, 1086-1090.
61. Adams, R. D.; Cotton, F. A. Inorg. Chim. Acta 1973, 7, 153-156.
62. Lian, T.; Locke, B.; Iannone, M.; Hochstrasser, R. M. Springer Proc. Phys. 1992, 68, 93-95.
63. Beddard, G. S.; Masters, A. J. Chem. Phys. Lett. 1992, 188, 513-519.