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67650913024
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See the Supporting Information for full details
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See the Supporting Information for full details.
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67650867012
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Interestingly, the reaction was completed after 2 h and gave a 70:30 mixture of (E)- and (Z)-l,2-bis-silylethene 5.
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Interestingly, the reaction was completed after 2 h and gave a 70:30 mixture of (E)- and (Z)-l,2-bis-silylethene 5.
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21
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0012414457
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Note that the formation of 4 was reported as a 29:71 mixture of (E)-4 and the internal adduct formed by ruthenium-catalyzed hydrosilylation; see: Y. Kawanami, Y. Sonoda, T. Mori, K. Yamamoto, Org. Lett. 2002, 4, 2825.
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Note that the formation of 4 was reported as a 29:71 mixture of (E)-4 and the internal adduct formed by ruthenium-catalyzed hydrosilylation; see: Y. Kawanami, Y. Sonoda, T. Mori, K. Yamamoto, Org. Lett. 2002, 4, 2825.
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See the Supporting Information. a K. Kokubo, M. Matsumasa, M. Miura, M. Nomura, J. Org. Chem. 1996, 61, 6941;
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67650892969
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Under rhodium catalysis conditions, no coupling reaction occurred with 5 and iodobenzene in the presence of TBAF, whereas only degradation was observed when 1,2-bis-silylethene 5 and acetic anhydride were subjected to palladium acylation catalysis.
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Under rhodium catalysis conditions, no coupling reaction occurred with 5 and iodobenzene in the presence of TBAF, whereas only degradation was observed when 1,2-bis-silylethene 5 and acetic anhydride were subjected to palladium acylation catalysis.
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38
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67650860844
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This reagent was prepared by quaternarisation of nBu3N from Merrifield resin followed by anionic exchange with NaF
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3N from Merrifield resin followed by anionic exchange with NaF.
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