Sensitizer immobilization in photochemistry: Evaluation of a novel green support

Journal of Chemical Technology and Biotechnology

Volumn 84, Issue 7, 2009, Pages 1026-1030

  Santos, Diego T ^a   Albarelli, Juliana Q ^a   Joyce, Kieran ^b   Oelgemöller, Michael ^b  

^a UNIVERSITY OF CAMPINAS   (Brazil)

^b DUBLIN CITY UNIVERSITY   (Ireland)

Author keywords

Ca alginate beads; Green support; Photochemistry; Sensitizer immobilization

Indexed keywords

ALGINATE BEADS; AMYL ALCOHOL; CA-ALGINATE BEADS; ENVIRONMENTAL-FRIENDLY; ENVIRONMENTALLY-FRIENDLY; GREEN CHEMISTRY; GREEN SUPPORT; JUGLONE; LOWER COST; PHOTOCHEMISTRY; PHOTOREACTION; PHOTOREACTOR; REACTION YIELDS; ROSE BENGAL; SAFER PRODUCTS; SENSITIZER IMMOBILIZATION; SUSTAINABLE CHEMISTRY;

ALGINATE; CALCIUM; CALCIUM CHLORIDE; ENERGY CONVERSION;

CELL IMMOBILIZATION;

CALCIUM ALGINATE; CALCIUM CHLORIDE; JUGLONE; PENTANOL; ROSE BENGAL;

ARTICLE; CONTROLLED STUDY; COST CONTROL; ENVIRONMENTAL PROTECTION; ENZYME IMMOBILIZATION; IMMOBILIZED CELL; INDUSTRIAL PRODUCTION; PHOTOCATALYSIS; PHOTOCHEMISTRY; PHOTOOXIDATION; PHOTOREACTIVITY;

EID: 67650885608     PISSN: 02682575     EISSN: 10974660     Source Type: Journal    
DOI: 10.1002/jctb.2129     Document Type: Article

References (23)

1. Thomson RH, Naturally Occurring Quinones IV. Blackie, London (1997).
2. Lim MY, Jeon JH, Jeong EY, Lee CH and Lee HS, Antimicrobial activity of 5-hydroxy-1,4-naphthoquinone isolated from Caesalpinia sappan toward intestinal bacteria. Food Chem 100:1254-1258 (2007).
3. Oelgemoller M, Schiel C, Frohlich R and Mattay J, The "photo-Friedel-Crafts acylation" of 1,4-naphthoquinones. Eur J Org Chem 2002:2465-2474 (2002).
4. Wakamatsu T, Nishi T, Ohnuma T and Ban Y, A convenient synthesis of juglone via neutral salcomine oxidation. Synth Commun 14:1167-1173 (1984).
5. Suchard O, Kane R, Roe BJ, Zimmermann E, Jung C, Waske PA, et al, Photooxygenations of 1-naphthols: an environmentally friendly access to 1,4-naphthoquinones. Tetrahedron 62:1467-1473 (2006).
6. Antoniou MG and Dionysiou DD, Application of immobilized titanium dioxide photocatalysts for the degradation of creatinine and phenol, model organic contaminants found in NASA's spacecrafts wastewater streams. Catal Today 124:215-223 (2007).
7. Blossey EC, Neckers DC, Thayer AL and Schaap AP, Polymerbased sensitizers for photooxidations. J Am Chem Soc 95:5820 (1973).
8. Braun AM, Maurette MT and Oliveros E, Technologie Photochemique. Presses Polytechniques Romandes, Lausanne (1986).
9. Neckers DC, Blossey EC and Schaap AP, Polymer-bound photosensitizing catalysts. US Patent 4315998 (1982).
10. Yates SF, Good ML and Brubaker IM, Polysiloxane bound photo-sensitizer for producing singlet oxygen. US Patent 4921589 (1988).
11. Quast H, Dietz T and Witzel A, Tetra(2,6-dichlorophenyl)porphyrin, a superior sensitizer for the singlet-oxygen ene reaction (Schenck reaction) Liebigs Ann 1495 (1995).
12. Robbins RJ and Ramamurthy V, Generation and reactivity of singlet oxygen within zeolites: remarkable control of hydroperoxidation of alkenes. J Chem Soc Chem Commun 1071 (1997).
13. Santos DT, Sarrouh BF, Rivaldi JD, Converti A and Silva SS, Use of sugarcane bagasse as biomaterial for cell immobilization for xylitol production. J Food Eng 86:542-548 (2008).
14. Sarrouh BF, Santos DT and Silva SS, Biotechnological production of xylitol in a three-phase fluidized bed bioreactor with immobilized yeast cells in Ca-alginate beads. Biotechnol J 2:759-763 (2007).
15. Rousseau I, Le Cerf D, Picton L, Argillier JF and Muller G, Entrapment and release of sodium polystyrene sulfonate (SPS) from calcium alginate gel beads. Eur Polym J 40:2709-2715 (2004).
16. Jeon C, Park JY and Yoo YJ, Characteristics of metal removal using carboxylated alginic acid. Water Res 36:1814-1824 (2002).
17. +2 from dilute aqueous metal solutions. Desalination 224:293-306 (2008).
18. George M and Abraham TE, Polyionic hydrocolloids for the intestinal delivery of protein drugs: Alginate and chitosan - a review. J Control Release 114:1-14 (2006).
19. Fundueanu G, Nastruzzi C, Carpov A, Desbrieres J and Rinaudo M, Physico-chemical characterization of Ca-alginate microparticles produced with different methods. Biomater 20:1427-1435 (1999).
20. Roopa BS and Bhattacharya S, Alginate gels: I. Characterization of textural attributes. J Food Eng 85:123-131 (2008).
21. 2 in suspended and immobilized form for the photocatalytic degradation of nitrobenzenesulfonic acids. Appl Catal B: Environ 37:301-308 (2002).
22. 2 photocatalysts. Appl Catal B: Environ 49:195-205 (2004).
23. 2. Appl Catal B: Environ 51:107-116 (2004).