One-pot route to produce hierarchically porous titania thin films by controlled self-assembly, swelling, and phase separation

Chemistry of Materials

Volumn 21, Issue 13, 2009, Pages 2763-2769

  Malfatti, Luca ^a   Bellino, Martín G ^b,c   Innocenzi, Plinio ^a   Soler Illia, Galo J A A ^b,c,d,e  

^a UNIVERSITY OF SASSARI   (Italy)

^b CENTRO ATÓMICO CONSTITUYENTES   (Argentina)

^c Centro Interdisciplinario de Nanociencia y Nanotecnologia   (Argentina)

^d UNIVERSIDAD DE BUENOS AIRES   (Argentina)

^e Facultad de Ciencias Naturales e Instituto M Lillo   (Argentina)

Author keywords

[No Author keywords available]

Indexed keywords

CONTROLLED SELF-ASSEMBLY; COSOLVENT; DIFFERENT LENGTH SCALE; IN-SITU; LARGE PORES; MESO-PORES; MESOPORE SIZES; MESOPOROUS FILMS; MESOPOROUS THIN FILMS; MESOSTRUCTURED; MULTI-MODAL; ONE POT; ONE-POT SYNTHESIS; POLY(PROPYLENE GLYCOL); POROUS THIN FILMS; POROUS TITANIA; SOFT CHEMISTRY ROUTES; SUPRAMOLECULAR TEMPLATING;

ETHYLENE GLYCOL; PHASE MODULATION; PORE SIZE; PROPYLENE; THIN FILMS; TITANIUM DIOXIDE; TITANIUM OXIDES; TUNING;

PHASE SEPARATION;

EID: 67650699254     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm900289c     Document Type: Article

References (50)

1. See, tor example, Special Issue: Templated Materials; Jaroniec, M., Schüth, F., Eds.; Chem. Mater. 2008, 20, 599-600.
2. Soler-Illia, G. J. A. A.; Sanchez, C.; Lebeau, B.; Patarin, J. Chem. Rev. 2002, 102(11), 4093.
3. Sanchez, C.; Boissière, C.; Grosso, D.; Laberty, C.; Nicole, L. Chem. Mater. 2008, 20, 682.
4. (a) Shi, J. L.; Hua, Z. L.; Zhang, L. X. J. Mater. Chem. 2004, 14, 795.
5. (b) Nicole, L.; Boissière, C.; Grosso, D.; Quach, A.; Sanchez, C. J. Mater. Chem. 2005, 15, 3598.
6. (c) Soler-Illia, G. J. A. A.; Innocenzi, P. Chem.-Eur. J. 2006, 12, 4478.
7. Soler-Illia, G. J. A. A.; Crepaldi, E. L.; Grosso, D.; Sanchez, C. C. Curr. Opin. Colloid Interface Sci. 2003, 8, 109.
8. Yiu, H. H. P.; Wright, P. A. J. Mater. Chem. 2005, 15, 3690.
9. Tortajada, M.; Ramón, D.; Beltrán, D.; Amorós, P. J. Mater. Chem. 2005, 15, 3859.
10. (a) Lu, Y.; Ganguli, R.; Drewien, C.; Anderson, M.; Brinker, C. J.; Gong, W.; Guo, Y.; Soyez, H.; Dunn, B.; Huang, M.; Zink, J. Nature 1997, 389, 364.
11. (b) Brinker, C. J.; Lu, Y.; Sellinger, A.; Fan, H. Adv. Mater. 1999, 11, 579.
12. (a) Fischer, A.; Kuemmel, M.; Järn, M.; Lindén, M.; Boissière, C.; Nicole, L.; Sanchez, C.; Grosso, D. Small 2006, 4, 569.
13. (b) Kuemmel, M.; Allouch, J.; Nicole, L.; Boissiere, C.; Laberty, C.; Amenitsch, H.; Sanchez, C.; Grosso, D. Chem. Mater. 2007, 119, 3717.
14. Brezesinski, T.; Groenewolt, M.; Gibaud, A.; Pinna, N.; Antonietti, M.; Smarsly, B. M. Adv. Mater. 2006, 18, 2260.
15. (a) Cheng, Y.-J.; Müller-Buschbaum, P.; Gutmann, J. S. Small 2007, 3, 1379.
16. (b) Cheng, Y.-J.; Zhou, S.; Gutmann, J. S. Macromol. Rapid Commun. 2007, 28, 1392.
17. (a) Yang, P.; Deng, T.; Zhao, D. Y.; Feng, P.; Pine, D.; Chmelka, B. F.; Whitesides, G. M.; Stocky, G. D. Science 1998, 282, 2244.
18. (b) Zhao, D.; Huo, Q.; Feng, 1; Chmelka, B. F.; Stocky, G. D. J. Am. Chem. Soc. 1998, 120, 6024.
19. Nakanishi, K.; Tanaka, N. Acc. Chem. Res. 2007, 40, 863.
20. Fujita, S.; Nakano, H.; Ishii, M.; Nakamura, H.; Inagaki, S. Microporous Mesoporous Mater. 2006, 96, 205.
21. Kuang, D.; Brezesinski, T.; Smarsly, B. J. Am. Chem. Soc. 2004, 126, 10534.
22. Brandhuber, D.; Torma, V.; Raab, C.; Peterlik, H.; Kulak, A.; Hüsing, N. Chem. Mater. 2005, 17, 4262.
23. Li, F.; Wang, Z.; Ergang, N. S.; Fyfe, C. A.; Stein, A. Langmuir 2007, 23, 3996.
24. Grosso, D.; Soler-Illia, G. J. A. A.; Crepaldi, E. L.; Charleux, B.; Sanchez, C. Adv. Funct. Mater. 2003, 13, 37.
25. Sel, O.; Kuang, D.; Thommes, M.; Smarsly, B. Langmuir 2006, 22, 2311.
26. Kumon, S.; Nakanishi, K.; Hirao, K. J. Sol-Gel Sci. Technol. 2000, 19, 1573.
27. Fuertes, M. C.; Soler-Illia, G. J. A. A. Chem. Mater. 2006, 18, 2109.
28. Bouchara, A.; Soler-Illia, G. J. A. A.; Chane-Ching, J.-Y.; Sanchez, C. Chem. Commun. 2002, 1234.
29. Sakatani, Y.; Boissière, C.; Grosso, D.; Nicole, L.; Soler-Illia, G. J. A. A.; Sanchez, C. Chem. Mater. 2008, 20, 1049.
30. (a) Angelomé, P. C.; Aldabe-Bilmes, S.; Calvo, M. E.; Crepaldi, E. L.; Grosso, D.; Sanchez, C.; Soler-Illia, G. J. A. A. New J. Chem. 2005, 29, 59.
31. (b) Angelomé, P. C.; Soler-Illia, G. J. A. A. Chem. Mater. 2005, 17, 322.
32. Otal, E. H.; Angelomé, P. C.; Aldabe-Bilmes, S.; Soler-Illia, G. J. A. A. Adv. Mater. 2006, 18, 934.
33. (a) Sakatani, Y.; Grosso, D.; Nicole, L.; Boissiere, C.; Soler-Illia, G. J. A. A.; Sanchez, C. J. Mater. Chem. 2006, 16, 77-82.
34. (b) Angelomé, P. C.; Andrini, L.; Calvo, M. E.; Requejo, F. G.; Bilmes, S. A.; Soler-Illia, G. J. A. A. J. Phys. Chem. C 2007, 111, 10886, and references therein.
35. (a) Malfatti, L.; Falcaro, P.; Amenitsch, H.; Caramori, S.; Argazzi, R.; Bignozzi, C. A.; Enzo, S.; Maggini, M.; Innocenzi, P. Microporous Mesoporous Mater. 2006, 88, 304.
36. (b) Lancelle-Beltran, E.; Prené, P.; Boscher, C.; Belleville, P.; Buvat, P.; Lambert, S.; Guillet, F.; Boissière, C.; Grosso, D.; Sanchez, C. Chem. Mater. 2007, 19, 4349.
37. Bass, J. D.; Grosso, D.; Boissiere, C.; Belamie, E. T.; Coradin; Sanchez, C. Chem. Mater. 2006, 18, 6152.
38. (a) Crepaldi, E. L.; Soler-Illia, G. J. A. A.; Grosso, D.; Cagnol, F.; Ribot, F.; Sanchez, C. J. Am. Chem. Soc. 2003, 125, 9770.
39. (b) Crepaldi, E. L.; Soler-Illia, G. J. A. A.; Grosso, D.; Sanchez, C. New J. Chem. 2003, 27, 9.
40. Van der Lee, A. Solid State Sci. 2000, 2, 257.
41. Choi, S. Y.; Lee, B.; Carew, D. B.; Mamak, M.; Peiris, F. C.; Speakman, S.; Chopra, N.; Ozin, G. A. Adv. Funct. Mater. 2006, 16, 1731.
42. It is important to stress that under our SAXS conditions (camera length 584 mm), any periodic feature larger that 25 nm cannot be detected, for it falls inside the beam stopper.
43. Nakanishi, K. J. Porous Mater. 1997, 4, 67.
44. Grosso, D.; Cagnol, F.; Soler-Illia, G. J. A. A.; Crepaldi, E. L.; Amenitsch, H.; Brunet-Bruneau, A.; Bourgeois, A.; Sanchez, C. Adv. Funct. Mater. 2004, 14, 309.
45. Sterner, O. Chemistry Health and the Environment; Wiley: Weinheim, 1999; p 42.
46. (a) Schmidt-Winkel, P.; Lukens, P. P.; Zhao, D. Y.; Yang, P.; Chmelka, B. F.; Stucky, G. D. J. Am. Chem. Soc. 1999, 121, 254.
47. (b) Lettow, J. S.; Han, Y. H.; Schmidt-Winkel, P.; Yang, P.; Zhao, D. Y.; Stucky, G. D.; Ying, J. Y. Langmuir 2000, 16, 8291.
48. (a) Sanchez, C.; Soler-Illia, G. J. A. A.; Ribot, F.; Grosso, D. C. R. Acad. Sci. 2003, 6, 1131.
49. (b) Angelomé, P. C.; Soler-Illia, G. J. A. A. J. Mater. Chem. 2005, 15, 3903.
50. Falcaro, P.; Costacurta, S.; Malfatti, L.; Takahashi, M.; Kidchob, T.; Casula, M. F.; Piccinini, M.; Marcelli, A.; Marmiroli, B.; Amenitsch, H.; Schiavuta, P.; Innocenzi, P. Adv. Mater. 2008, 20, 1864.