Reconfirmation of recognition site in composites of imprinted β-cyclodextrin polymer/solid support as stationary phase of HPLC

Chemistry Letters

Volumn 37, Issue 11, 2008, Pages 1148-1149

  Nagaoka, Suguru ^a   Song, Shi Hui ^a   Sumaoka, Jun ^a   Komiyama, Makoto ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

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Indexed keywords

EID: 67650494413     PISSN: 03667022     EISSN: 13480715     Source Type: Journal    
DOI: 10.1246/cl.2008.1148     Document Type: Article

References (7)

1. M. Komiyama, T. Takeuchi, T. Mukawa, H. Asanuma, Molecular Imprinting-From Fundamentals to Applications, Wiley-VCH, Weinheim, 2003.
2. H. Asanuma, T. Hishiya, M. Komiyama, Adv. Mater. 2000, 12, 1019.
3. T. Hishiya, H. Asanuma, M. Komiyama, J. Am. Chem. Soc. 2002, 124, 570.
4. S. Song, K. Shirasaka, M. Katayama, S. Nagaoka, S. Yoshihara, T. Osawa, J. Sumaoka, H. Asanuma, M. Komiyama, Macromolecules 2007, 40, 3530.
5. J. J. Pesek, M. T. Matyska, J. Chromatogr., A 2002, 952, 1.
6. In pH 8.0 Tris-HCl buffer, solid supports were dispersed at 1 wt % concentrations, and these mixtures were diluted to 1/8 (for the silica-gels 1 and 2) and 1/16 (for the alumina support). Under these conditions, these solid supports were satisfactorily dispersed.
7. In this case, reproducibility of the α value was rather poor, probably because the support is partially decomposed by the radicals formed during the imprinting.