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Experiments were carried out under argon atmosphere by standard Schlenk techniques (Table 1, Entry 11, To a solution of, 2E, 2-(1, 2, 6, 7-tetrahydro-8H-indeno[5, 4-b]furan-8-ylidene) ethyl]amine (1, 20 mg, 0.1 mmol) in methanol (0.5 mL) in a glass autoclave was added a solution of (R)-11, S, 2-(di-2-furylphosphino) ferrocenyl]ethyldi (tert-butyl) phosphine (ligand 3k, 2.7 mg, 1.3 equiv to Rh) and [Rh (cod) Cl]2 (1.0 mg, s/c=25) in methanol (0.5 mL) by cannula. Hydrogen (0.7 MPa) was introduced, and the reaction mixture was stirred at room temperature. After 5 h, enantiomeric excess (92, and chemical yield (95, were determined by HPLC analysis (CHIRALCEL OD-RH, eluted with 0.1 M KPF6 (pH 2) /acetonitrile=750/250 v/v, 0.5 mL/rnin
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