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67650410405
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3P), were only partially successful, resulting in incomplete cleavage as determined by the presence of bimodal peaks in the GPC RI traces.
-
3P), were only partially successful, resulting in incomplete cleavage as determined by the presence of bimodal peaks in the GPC RI traces.
-
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46
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67650451629
-
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The low PDI values of the polymers relative to the apparent broadness of the GPC RI traces are due to limitations of the GPC-MALLS system which uses light scattering data to calculate the Mw and PDI. This technique is generally considered to be very accurate, but unfortunately the high molecular weight of the star polymers being analyzed generates a very intense light scattering (LS) signal which can mask the LS signal of lower molecular weight polymers and hence underestimate the PDI
-
w and PDI. This technique is generally considered to be very accurate, but unfortunately the high molecular weight of the star polymers being analyzed generates a very intense light scattering (LS) signal which can mask the LS signal of lower molecular weight polymers and hence underestimate the PDI.
-
-
-
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47
-
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67650415971
-
-
A 15:1 MI:TMI ratio indicates that 1 mol of TMI is added for every 15 mol of MIs used in the synthesis of the core cross-linked assemblies. 25:1 and 35:1 ratios indicate the respective reduction in the amount of TMIs used.
-
A 15:1 MI:TMI ratio indicates that 1 mol of TMI is added for every 15 mol of MIs used in the synthesis of the core cross-linked assemblies. 25:1 and 35:1 ratios indicate the respective reduction in the amount of TMIs used.
-
-
-
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48
-
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67650412806
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w (113 to 119 kDa) of polymer fraction P12c (prepared using TMI P3 at a MI:TMI = 35) after attempted cleavage is the polymerization of accessible pendent double bonds present on partially formed stars or low molecular weight material initiated by radicals generated by BPO.
-
w (113 to 119 kDa) of polymer fraction P12c (prepared using TMI P3 at a MI:TMI = 35) after attempted cleavage is the polymerization of accessible pendent double bonds present on partially formed stars or low molecular weight material initiated by radicals generated by BPO.
-
-
-
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49
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67650424686
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Arm number calculation based on a core fraction of 0.2 (derived from the complete conversion of EGDMA determined via GC-MS).
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Arm number calculation based on a core fraction of 0.2 (derived from the complete conversion of EGDMA determined via GC-MS).
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