Degree of rate control: How much the energies of intermediates and transition states control rates

Journal of the American Chemical Society

Volumn 131, Issue 23, 2009, Pages 8077-8082

  Stegelmann, Carsten ^a,d   Andreasen, Anders ^b,e   Campbell, Charles T ^c  

^a AALBORG UNIVERSITY   (Denmark)

^b TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

^c UNIVERSITY OF WASHINGTON   (United States)

^d RAMBOLL   (Denmark)

^e Process Development   (Denmark)

Author keywords

[No Author keywords available]

Indexed keywords

BASIC RESEARCH; CHEMICAL KINETICS; CHEMICAL SPECIES; CONTROL RATES; ELEMENTARY STEPS; KINETIC MODELS; MULTISTEP REACTIONS; RATE CONTROLS; RATE DETERMINING STEP; RATE-CONTROLLING; REACTION MECHANISM; RELATIVE ENERGIES; STERIC CONTROL; TRANSITION STATE;

REACTION RATES;

ACCURACY; ARTICLE; CATALYST; CHEMICAL ANALYSIS; CHEMICAL MODIFICATION; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLOADDITION; ELECTRICITY; ENERGY YIELD; KINETICS; REACTION TIME; STEREOCHEMISTRY; STEREOSPECIFICITY;

EID: 67650308083     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9000097     Document Type: Article

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