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0036495325
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For the influence of arene complexes on the catalytic activity of asymmetric hydrogenations see
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(b) For the influence of arene complexes on the catalytic activity of asymmetric hydrogenations see: Heller, D.; Drexler, H.-J.; Spannenberg, A.; Heller, B.; You, J.; Baumann, W. Angew. Chem., Int. Ed. 2002, 41, 777-780.
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Heller, D.1
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67650316302
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Halpern's X-ray structure of the DPPE dimer was not deposited in the Cambridge database. A new X-ray crystal structure of the DPPE dimer 1 is included in the Supporting Information, Figure S1, of this work.
-
Halpern's X-ray structure of the DPPE dimer was not deposited in the Cambridge database. A new X-ray crystal structure of the DPPE dimer 1 is included in the Supporting Information, Figure S1, of this work.
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(c) DIPH: Allen, D. G.; Wild, S. B.; Wood, D. L. Organometallics 1986, 5, 1009-1015.
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(a) Preetz, A.; Drexler, H.-J.; Fischer, C.; Dai, Z.; Borner, A.; Baumann, W.; Spannenberg, A.; Thede, R.; Heller, D. Chem.-Eur. J. 2008, 14, 1445-1451, and references therein,
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de Vries, H. G, Elsevier, C, Eds, Wiley-VCH: New York, Chapter 14, pp
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(b) Heller, D.; de Vries, A. H. M.; de Vries, J. G. Catalyst Inhibition and Deactivation in Homogeneous Hydrogenation. In Handbook of Homogeneous Hydrogénation; de Vries, H. G., Elsevier, C., Eds.; Wiley-VCH: New York, 2007; Chapter 14, pp 1483-1516.
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Drexler, H.-J.; Preetz, A.; Schmidt, T.; Heller, D. Kinetics of Homogeneous Hydrogenation: Measurement and Interpretation. In Handbook of Homogeneous Hydrogenation; de Vries, H. G., Elsevier, C., Eds.; Wiley-VCH: New York, 2007; Chapter 10, pp 1483-1516.
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Drexler, H.-J.1
Preetz, A.2
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Heller, D.4
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36
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67650316111
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-
31P NMR spectrum of [Rh(DIPAMP)(MeOH)2]BF4, with the widely investigated dimethyl itaconate (Rh:substrate =1:1), the same signals are visible, which were then left unidentified; see Supporting Information, Figure S12 and ref 9c.
-
31P NMR spectrum of [Rh(DIPAMP)(MeOH)2]BF4, with the widely investigated dimethyl itaconate (Rh:substrate =1:1), the same signals are visible, which were then left unidentified; see Supporting Information, Figure S12 and ref 9c.
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-
-
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37
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3843065835
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Drexler, H.-J.; Zhang, S.; Sun, A.; Spannenberg, A.; Arrieta, A.; Preetz, A.; Heller, D. Tetrahedron: Asymmetry 2004, 15, 2139-2150.
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Heller, D.7
-
38
-
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67650338667
-
-
This temperature was chosen owing to the high viscosity of MeOH and to the low solubility of 1 in MeOH at lower temperatures
-
This temperature was chosen owing to the high viscosity of MeOH and to the low solubility of 1 in MeOH at lower temperatures.
-
-
-
-
39
-
-
67650341889
-
-
The chemical shifts are in the range of known values for rhodium DIPAMP arene complexes, e.g, Rh(DIPAMP(p-xylene)]BF4 with 956 ppm and [Rh(DIPAMP)(benzene)]BF4 with -1006 ppm; see ref 1b
-
4 with -1006 ppm; see ref 1b.
-
-
-
-
40
-
-
67650334950
-
-
31P NMR data are not suitable due to the fact that signals of all species overlap.
-
31P NMR data are not suitable due to the fact that signals of all species overlap.
-
-
-
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