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Volumn 28, Issue 13, 2009, Pages 3673-3677

Asymmetrie Hydrogénation. Dimerization of Solvate Complexes: Synthesis and Characterization of Dimeric [Rh(DIPAMP)]2+2, a Valuable Catalyst Precursor

Author keywords

[No Author keywords available]

Indexed keywords

ASYMMETRIC HYDROGENATION; CATALYST PRECURSORS; DIMERIC SPECIES; INDUCTION PERIODS; NORBORNADIENE; PROCHIRAL OLEFINS; SOLUTION STUDY; SOLVATE COMPLEXES; SUBSTRATE COMPLEXES; SYNTHESIS AND CHARACTERIZATION;

EID: 67650293102     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om801199q     Document Type: Article
Times cited : (26)

References (40)
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    • (b) For the influence of arene complexes on the catalytic activity of asymmetric hydrogenations see: Heller, D.; Drexler, H.-J.; Spannenberg, A.; Heller, B.; You, J.; Baumann, W. Angew. Chem., Int. Ed. 2002, 41, 777-780.
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    • Halpern's X-ray structure of the DPPE dimer was not deposited in the Cambridge database. A new X-ray crystal structure of the DPPE dimer 1 is included in the Supporting Information, Figure S1, of this work.
    • Halpern's X-ray structure of the DPPE dimer was not deposited in the Cambridge database. A new X-ray crystal structure of the DPPE dimer 1 is included in the Supporting Information, Figure S1, of this work.
  • 5
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    • and on the DPPP, DPPB, and CHIRAPHOS
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    • (c) DIPH: Allen, D. G.; Wild, S. B.; Wood, D. L. Organometallics 1986, 5, 1009-1015.
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    • (b) Heller, D.; de Vries, A. H. M.; de Vries, J. G. Catalyst Inhibition and Deactivation in Homogeneous Hydrogenation. In Handbook of Homogeneous Hydrogénation; de Vries, H. G., Elsevier, C., Eds.; Wiley-VCH: New York, 2007; Chapter 14, pp 1483-1516.
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    • 31P NMR spectrum of [Rh(DIPAMP)(MeOH)2]BF4, with the widely investigated dimethyl itaconate (Rh:substrate =1:1), the same signals are visible, which were then left unidentified; see Supporting Information, Figure S12 and ref 9c.
    • 31P NMR spectrum of [Rh(DIPAMP)(MeOH)2]BF4, with the widely investigated dimethyl itaconate (Rh:substrate =1:1), the same signals are visible, which were then left unidentified; see Supporting Information, Figure S12 and ref 9c.
  • 38
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    • This temperature was chosen owing to the high viscosity of MeOH and to the low solubility of 1 in MeOH at lower temperatures
    • This temperature was chosen owing to the high viscosity of MeOH and to the low solubility of 1 in MeOH at lower temperatures.
  • 39
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    • The chemical shifts are in the range of known values for rhodium DIPAMP arene complexes, e.g, Rh(DIPAMP(p-xylene)]BF4 with 956 ppm and [Rh(DIPAMP)(benzene)]BF4 with -1006 ppm; see ref 1b
    • 4 with -1006 ppm; see ref 1b.
  • 40
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    • 31P NMR data are not suitable due to the fact that signals of all species overlap.
    • 31P NMR data are not suitable due to the fact that signals of all species overlap.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.