Cationic Rh-bisphosphine-diolefin complexes as precatalysts for enantioselective catalysis - What information do single crystal structures contain regarding product chirality?

Tetrahedron Asymmetry

Volumn 15, Issue 14, 2004, Pages 2139-2150

  Drexler, Hans Joachim ^a   Zhang, Songlin ^a   Sun, Ailing ^a   Spannenberg, Anke ^a   Arrieta, Antonio ^a   Preetz, Angelika ^a   Heller, Detlef ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ALKADIENE; CATION; PHOSPHINE DERIVATIVE; RHODIUM;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL BOND; CHIRALITY; CORRELATION ANALYSIS; CRYSTAL STRUCTURE; DATA BASE; ENANTIOSELECTIVITY; PRECURSOR; PRIORITY JOURNAL; ROTATION;

EID: 3843065835     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetasy.2004.06.036     Document Type: Review

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79. As a kinetic phenomenon the enantioselectivity is determined as the ratio of the enantiomeric products, from the ratio of reactivity of the diastereomeric substrate complexes as well as the ratio of the concentration of these intermediates and thus is dependent on several possible reaction pathways. The selectivity experimentally obtained is not only the result of the potential of the catalyst intrinsically present and determined by the chiral ligand, but also the result of external parameters such as hydrogen pressure and temperature. In other words, a chiral ligand is a necessary but not sufficient condition for stereoselection