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2-forming methylenetetrahydromethanopterin-dehydrogenase (Hmd): (a) Zirngibl, C.; Hedderich, R.; Thauer, R. K. FEBS Lett. 1990, 261, 112.
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2-forming methylenetetrahydromethanopterin-dehydrogenase (Hmd): (a) Zirngibl, C.; Hedderich, R.; Thauer, R. K. FEBS Lett. 1990, 261, 112.
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2
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33750086029
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(b) Korbas, M.; Vogt, S.; Meyer-Klaucke, W.; Bill, E.; Lyon, E. J.; Thauer, R. K.; Shima, S. J. Biol. Chem. 2006, 281, 30804.
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4
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For recent insights on mechanism, see refs 1b, 6, and 9
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Berkessel, A.; Thauer, R. K. Angew. Chem., Int. Ed. Engl. 1995, 34, 2247. For recent insights on mechanism, see refs 1b, 6, and 9.
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5
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67649985770
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Superelectrophiles5 bear more than a single positive charge and are considerably more reactive than their monocationic precursors
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5 bear more than a single positive charge and are considerably more reactive than their monocationic precursors.
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6
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(a) Olah, G. A.; Germain, A.; Lin, H. C.; Forsyth, D. A. J. Am. Chem. Soc. 1975, 97, 2928.
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(a) Shima, S.; Pilak, O.; Vogt, S.; Schick, M.; Stagni, M. S.; Meyer-Klaucke, W.; Warkentin, E.; Thauer, R. K.; Ermler, U. Science 2008, 321, 572.
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(b) Hiromoto, T.; Ataka, K.; Pilak, O.; Vogt, S.; Stagni, M. S.; Meyer-Klaucke, W.; Warkentin, E.; Thauer, R. K.; Shima, S.; Ermler, U. FEBS Lett. 2009, 583, 585.
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Computational studies: (a) Cioslowski, J.; Boche, G. Angew. Chem., Int. Ed. Engl. 1997, 36, 107.
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14
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0027340209
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(a) Schwörer, B.; Fernandez, V. M.; Zirngibl, C.; Thauer, R. K. Eur. J. Biochem. 1993, 212, 255.
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Schwörer, B.1
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(b) Klein, A. R.; Hartmann, G. C.; Thauer, R. K. Eur. J. Biochem. 1995, 233, 372.
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(b) Rasul, G.; Surya Prakash, G. K.; Olah, G. A. J. Org. Chem. 1994, 59, 2552.
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For P,N-dications, see: (g) Conejero, S.; Canac, Y.; Tham, F. S.; Bertrand, G. Angew. Chem., Int. Ed. 2004, 43, 4089.
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For P,N-dications, see: (g) Conejero, S.; Canac, Y.; Tham, F. S.; Bertrand, G. Angew. Chem., Int. Ed. 2004, 43, 4089.
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