Oil-in-water emulsions for encapsulated delivery of reactive iron particles

Environmental Science and Technology

Volumn 43, Issue 13, 2009, Pages 5060-5066

  Berge, Nicole D ^a   Ramsburg, C Andrew ^a  

^a Tufts University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BREAK THROUGH CURVE; COLUMN EXPERIMENTS; DARCY VELOCITY; DENSE NON-AQUEOUS PHASE LIQUIDS; DNAPL SOURCE ZONES; DROPLET DIAMETERS; DYNAMIC VISCOSITIES; FINE SAND; IRON PARTICLES; OIL-IN-WATER EMULSIONS; POROUS MEDIA; SATURATED POROUS MEDIA; SOIL INTERACTION; SOURCE ZONE; SUBMICROMETER SCALE; SUBSURFACE TRANSPORT;

EMULSIFICATION; EMULSIONS; EXPERIMENTS; IMPURITIES; POROUS MATERIALS; STRATEGIC PLANNING;

SUSPENSIONS (FLUIDS);

IRON; OIL;

EMULSION; IRON; OIL;

ARTICLE; EMULSION; ENCAPSULATION; FEASIBILITY STUDY; IRON TRANSPORT; KINETICS; NONAQUEOUS PHASE LIQUID; VISCOSITY;

CHEMISTRY, PHYSICAL; EMULSIONS; IRON; KINETICS; MICROSCOPY, ELECTRON, SCANNING; OILS; PARTICLE SIZE; POROSITY; SOLUBILITY; SOLUTIONS; TIME FACTORS; WATER; WATER PURIFICATION;

EID: 67649968485     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es900358p     Document Type: Article

References (43)

1. Arnold, W. A.; Roberts, A. L. Pathways and kinetics of chlorinated ethylene and chlorinated acetylene reaction with Fe(O) particles. Environ. Sci. Technol. 2000, 34, 1794-1805. (Pubitemid 30246857)
2. Lien, H. L.; Zhang, W. X. Nanoscale iron particles for complete reduction of chlorinated ethenes. Colloids Surf., A 2001, 191, 97-105. (Pubitemid 32717579)
3. Liu, Y. Q.; Majetich, S. A.; Tilton, R. D.; Sholl, D. S.; Lowry, G. V. TCE dechlorination rates, pathways, and efficiency of nanoscale iron particles with different properties. Environ. Sci. Technol. 2005, 39, 1338-1345. (Pubitemid 40333395)
4. Elliott, D. W.; Zhang, W. Field assessment of nanoscale bimetallic particles for groundwater treatment. Environ. Sci. Technol. 2001, 35, 4922-4926. (Pubitemid 33144358)
5. Quinn, J.; Geiger, C.; Clausen, C.; Brooks, K.; Coon, C.; O'Hara, S.; Krug, T.; Major, D.; Yoon, W. S.; Gavaskar, A.; Holdsworth, T. Field demonstration of DNAPL dehalogenation using emulsified zerovalent iron. Environ. Sci. Technol. 2005, 39, 1309-1318. (Pubitemid 40333391)
6. Phenrat, T.; Saleh, N.; Sirk, K.; Tilton, R. D.; Lowry, G. V. Aggregationandsedimentation of aqueous nanoscale zerovalent iron dispersions. Environ. Sci. Technol. 2007, 41, 284-290. (Pubitemid 46047855)
7. Saleh, N.; Sirk, K.; Liu, Y. Q.; Phenrat, T.; Dufour, B.; Matyjaszewski, K.; Tilton, R. D.; Lowry, G. V. Surface modifications enhance nanoiron transport and NAPL targeting in saturated porous media. Environ. Eng. Sci. 2007, 24, 45-57. (Pubitemid 46036184)
8. Tratnyek, P. G.; Johnson, R. L. Nanotechnologies for environmental cleanup. Nanotoday 2006, 1, 44-48.
9. Morales, M. A.; Jain, T. K.; Labhasetwar, V.; Leslie-Pelecky, D. L. Magnetic studies of iron oxide nanoparticles coated with oleic acid and Pluronic (R) block copolymer. J. Appl. Phys. 2005, 97.
10. Kanel, S. R.; Choi, H. Transport characteristics of surface modified nanoscale zero-valent iron in porous media. Water Sci. Technol. 2007, 55, 157-162. (Pubitemid 46231403)
11. Phenrat, T.; Saleh, N.; Sirk, K.; Kim, H. J.; Tilton, R. D.; Lowry, G. V. Stabilization of aqueous nanoscale zerovalent iron dispersions by anionic polyelectrolytes: adsorbed anionic polyelectrolyte layer properties and their effect on aggregation and sedimentation. J. Nanopart. Res. 2008, 10, 795-814. (Pubitemid 351579782)
12. Tiraferri, A.; Sethi, R. Enhanced transport of zerovalent iron nanoparticles in saturated porous media by gum agar. J. Nanopart. Res. 2009, 11, 635-645.
13. Hsieh, S. H.; Horng, J. J. Deposition of Fe-Ni nanoparticles on Al2O3 for dechlorination of chloroform and trichloroethylene. Appl. Surf. Sci. 2006, 253, 1660-1665. (Pubitemid 44709351)
14. Zhan, J.; Zheng, T.; Piringer, G.; Day, C.; McPherson, G.; Lu, Y.; Papadopoulus, K.; John, V. Transport characteristics of nanoscale functional zerovalent iron/silica composites for in situ remediation of trichloroethylene. Environ. Sci. Technol. 2008, 42 (23), 8871-8876. (Pubitemid 351842396)
15. Powers, S. E.; Abriola, L. M.; Weber, W. J. An Experimental Investigation of Nonaqueous Phase Liquid Dissolution in Saturated Subsurface Systems - Transient Mass-Transfer Rates. Water Resour. Res. 1994, 30, 321-332. (Pubitemid 24405808)
16. Geiger, C. L.; Clausen, C. A.; Brooks, K.; Clausen, C.; Huntley, C.; Filipek, L.; Reinhart, D. R.; Quinn, J.; Krug, T.; O'Hara, S.; Major, D. Nanoscale and microscale iron emulsions for treating DNAPL. In Chlorinated Solvent and DNAPL Remediation: Innovative Strategies for Subsurface Cleanup; Henry, S. M., Warner, S. D., Eds.; American Chemical Society: Washington DC, 2003; Vol.837, p 2003.
17. Pennell, K. D.; Pope, G. A.; Abriola, L. M. Influence of viscous and buoyancy forces on the mobilization of residual tetrachloroethylene during surfactant flushing. Environ. Sci. Technol. 1996, 30, 1328-1335. (Pubitemid 26100880)
18. McClements, D. J.; Decker, E. A.; Weiss, J. Emulsion-based delivery systems for lipophilioc bioactive components. J. Food Sci. 2007, 72, R109-R124. (Pubitemid 47583566)
19. Borden, R. C. Effective distribution of emulsified edible oil for enhanced anaerobic bioremediation. J. Contam. Hydrol. 2007, 94, 1-12. (Pubitemid 47503454)
20. Lee, Y. C.; Kwon, T. S.; Yang, J. S.; Yang, J. W. Remediation of groundwater contaminated with DNAPLs by biodegradable oil emulsion. J. Hazard. Mater. 2007, 140, 340-345. (Pubitemid 46239937)
21. Ramsburg, C. A.; Pennell, K. D.; Kibbey, T. C. G.; Hayes, K. F. Use of a surfactant-stabilized emulsion to deliver 1-butanol for density-modified displacement of trichloroethene. Environ. Sci. Technol. 2003, 37, 4246-4253. (Pubitemid 37108313)
22. Soo, H.; Radke, C. J. The Flow Mechanism of Dilute, Stable Emulsions in Porous Media. Ind. Eng. Chem. Fundam. 1984, 23, 342-347.
23. Coulibaly, K. M.; Borden, R. C. Impact of edible oil injection on the permeability of aquifer sands. J. Contam. Hydrol 2004, 71, 219-237. (Pubitemid 38625706)
24. Becher, P. Emulsions: theory and practice, 3rd ed.; Oxford University Press: Washington D.C., U.S.A., 2001.
25. Bünger, R. Phenomenological foundation and mathematical theory of sedimentation - consolidation processes. Chem. Eng. J. 2000, 80, 177-188. (Pubitemid 32051211)
26. 4.5 nanowires in common solvents: a sedimentation study. J. Phys. Chem. B 2005, 109, 7124-7133.
27. Christenson, H. K. Non-DLVO forces between surfaces - solvation, hydration and capillary effects. J. Dispersion Sci. Technol. 1988, 9, 171-206. (Pubitemid 18608075)
28. Adamson, A. A.; Gast, A. P. Physical Chemistry of Surfaces, 6th ed.; Wiley-Interscience, New York, 1997.
29. Kandori, K.; Ishikawa, T. Effects of water on dispersion stability of colloid particles in nonpolar organic media: specification by in situ FT-IR spectroscopy. J. Colloid Interface Sci. 1992, 154, 202-209.
30. Sinha, A.; Ganguly, R.; De, A. K.; Puri, I. K. Single magnetic particle dynamics in a microchannel. Phys. Fluids 2007, 19 (11), 5.
31. Dailey, J. P.; Phillips, J. P.; Li, C.; Riffle, J. S. Synthesis of silicone magnetic fluid for use in eye surgery. J. Magn. Magn. Mater. 1999, 194, 140-148.
32. Landfester, K.; Ramirez, L. P. Encapsulated magnetite particles for biomedical application. J. Phys.: Condens. Matter 2003, 15, S1345-S1361.
33. Maity, D.; Agrawal, D. C. Synthesis of iron oxide nanoparticle sunder oxidizing environment and their stabilization in aqueous and non-aqueous media. J. Magn. Magn. Mater. 2007, 308, 46-55. (Pubitemid 44537578)
34. Tadmor, R.; Rosensweig, R. E.; Frey, J.; Klein, J. Resolving the puzzle of ferrofluid dispersants. Langmuir 2000, 16, 9117-9120.
35. Suchomel, E. J.; Ramsburg, C. A.; Pennell, K. D. Evaluation of trichloroethene recovery processes in heterogeneous aquifer cells flushed with biodegradable surfactants. J. Contam. Hydrol. 2007, 94, 195-214. (Pubitemid 350052359)
36. Zhai, X. H.; Hua, I.; Rao, P. S. C.; Lee, L. S. Cosolvent-enhanced chemical oxidation of perchloroethylene by potassium permanganate. J. Contam. Hydrol. 2006, 82, 61-74. (Pubitemid 41811207)
37. Pfeiffer, P. R.; Bielefeldt, A. R.; Illangasekare, T.; Henry, B. Physical properties of vegetable oil and chlorinated ethene mixtures. J. Environ. Eng. - Asce 2005, 131, 1447-1452. (Pubitemid 41419733)
38. Coupland, J. N.; McClements, J. Physical properties of liquid edible oils. J. Am. Oil Chemists' Soc. 1997, 74, 1559-1564. (Pubitemid 127638967)
39. Mason, T. G. New fundamental concepts in emulsion rheology. Curr. Opin. Colloid Interface Sci. 1999, 4, 231-238. (Pubitemid 29431629)
40. Carbonell, V.; Mauri, A. R.; Salvador, A.; Guardia, M. d. l. Direct determination of copper and iron in edible oils using flow injection flame atomic absorption spectrometry. J. Anal. At. Spectrom. 1991, 6, 581-584.
41. Yépez, O. On the chemical reaction between carboxylic acids and iron, including the special case of naphthenic acid. Fuel 2007, 86, 1162-1168. (Pubitemid 46096490)
42. Barr, D. W. Coefficient of permeability determined by measurable parameters. Ground Water 2001, 39, 356-361. (Pubitemid 32398666)
43. Hayter, A. J. Probability and Statistics for Engineers and Scientists, 2nd ed.; Duxbury Thomson Learning: Pacific Grove, CA, 2002.