Gold in the Brunswick No. 12 volcanogenic massive sulfide deposit, Bathurst Mining Camp, Canada: Evidence from bulk ore analysis and laser ablation ICP-MS data on sulfide phases

Mineralium Deposita

Volumn 44, Issue 5, 2009, Pages 523-557

  McClenaghan, Sean H ^a   Lentz, David R ^b   Martin, Jillian ^b   Diegor, Wilfredo G ^c  

^a GEOLOGICAL SURVEY OF CANADA   (Canada)

^b UNIVERSITY OF NEW BRUNSWICK   (Canada)

^c MEMORIAL UNIVERSITY OF NEWFOUNDLAND   (Canada)

Author keywords

Bathurst Mining Camp; Brunswick No. 12; Canada; Gold; Laser Ablation ICP MS; Massive Sulfide; Volcanogenic

Indexed keywords

GOLD; GREENSCHIST FACIES; HYDROTHERMAL FLUID; LASER METHOD; MASSIVE SULFIDE; ORDOVICIAN; ORE DEPOSIT; SEDIMENTARY SEQUENCE; VOLCANOGENIC DEPOSIT;

BATHURST ISLAND [NUNAVUT]; CANADA; NORTH AMERICA; NUNAVUT; QUEEN ELIZABETH ISLANDS;

EID: 67649780602     PISSN: 00264598     EISSN: None     Source Type: Journal    
DOI: 10.1007/s00126-009-0233-7     Document Type: Article

References (124)

1. Barton PB Jr, Toulmin PIII (1966) Phase relations involving sphalerite in the Fe-Zn-S system. Econ Geol 61:815-849
2. Benning LG, Seward TM (1996) Hydrosulphide complexing of Au (I) in hydrothermal solutions from 150-400°C and 500-1500 bar. Geochim et Cosmochim Acta 60:1849-1871
3. Bischoff JL, Rosenbauer RJ (1985) An empirical equation of state for hydrothermal seawater (3.2 percent NaCl). Am J Sci 285:725-763
4. Boyle RW (1979) The geochemistry of gold and its deposits. Bull Geol Surv Can 280:584
5. Bürg GH (1930) Die Sichtbarmachung des feinverteilten Goldes in goldhaltigen Erzenund ihre wirtschaftliche Bedeutung. Metall und Erz 27:333-338
6. Cabri LJ, Chryssoulis SL, de Villiers JPR, Laflamme JHG, Buseck PR (1989) The nature of "invisible" gold in arsenopyrite. Can Mineral 27:353-362
7. Chen TT (1978) Colloform and framboidal pyrite from the Caribou deposit, New Brunswick. Can Mineral 16:9-15
8. Chryssoulis SL, Agha U (1990) Gold mineralogical balance in two Brunswick ore samples. Unpublished report, University of Western Ontario
9. Chryssoulis SL, Cabri LJ, Lennard W (1989) Calibration of the ion microprobe for quantitative trace precious metal analyses of ore minerals. Econ Geol 84:1684-1689
10. Clark LA (1960) The Fe-As-S system: Phase relations and applications. Econ Geol 55:1345-1381
11. Cook NJ, Chryssoulis SL (1990) Concentrations of "invisible gold" in the common sulfides. Can Mineral 28:1-16
12. Craig JR (2001) Ore-mineral textures and the tales they tell. Can Mineral 39:937-956
13. Craig JR, Vokes FM (1992) Ore mineralogy of the Appalachian-Caledonian stratabound sulfide deposits. Ore Geol Rev 7:77-123
14. de Roo JA, van Staal CR (2003) Sulfide remobilization and sulfide breccias in the Heath Steele and Brunswick deposits, Bathurst Mining Camp, New Brunswick. In: Goodfellow WD, McCutcheon SR, Peter JM (eds) Massive sulfide deposits of the Bathurst Mining Camp, New Brunswick and northern Maine. Econ Geol Mon 11:479-496
15. Eldridge CS, Barton PB Jr., Ohmoto H (1983) Mineral textures and their bearing on formation of the Kuroko orebodies. In: Ohmoto H, Skinner BJ (eds) The Kuroko and related volcanogenic massive sulfide deposits. Econ Geol Mon 5:241-281
16. Fleet ME, MacLean PJ, Barbier J (1989) Oscillatory-zoned As-bearing pyrite from strata-bound and stratiform gold deposits: An indicator of ore fluid evolution. In: Keays RR, Ramsay WRH, Groves DI (eds) The geology of gold: The perspective in 1988. Econ Geol Mon 6:356-362
17. Fouquet Y, von Stackelberg U, Charlou JL, Donval JP, Erzinger J, Foucher JP, Herzig PM, Mühe RK, Soakai S, Wiedicke M, Whitechurch H (1991) Hydrothermal activity and metallogenesis in the Lau back-arc basin. Nature 349:778-781
18. Fouquet Y, von Stackelberg U, Charlou JL, Erzinger J, Herzig PM, Mühe RK, Wiedicke M (1993) Metallogenesis in back-arc environments: the Lau Basin example. Econ Geol 88:2154-2181
19. Franklin JM, Lydon JW, Sangster DF (1981) Volcanic-associated massive sulfide deposits. In: Skinner BJ (ed) 75 th anniversary volume. Econ Geol 75:485-627
20. Franklin JM, Gibson HL, Jonasson IR, Galley AG (2005) Volcanogenic massive sulfide deposits. In: Hedenquist JW, Thompson JFH, Goldfarb RJ, Richards JP (eds) 100 th anniversary volume. Econ Geol 100:523-560
21. Galley AG, Hannington MD, Jonasson IR (2007) Volcanogenic massive sulphide deposits. In: Goodfellow WD (ed)AMineral deposits of Canada: a synthesis of major deposit types, district metallogeny, the evolution of geological provinces, and exploration methods. Geological Association of Canada, Mineral Deposits Division, Special Publication No. 5, pp 141-161
22. Gammons CH, Williams-Jones AE (1995) The solubility of Au-Ag alloy + AgCl in HCl/NaCl solutions at 300°C: New data on the stability of Au (I) chloride complexes in hydrothermal fluids. Geochim Cosmochim Acta 59:3453-3468
23. Gaspar OC (2002) Mineralogy and sulfide mineral chemistry of the Neves-Corvo ores, Portugal: Insight into their genesis. Can Mineral 40:611-636
24. Gilligan LB, Marshall B (1987) Textural evidence for remobilization in metamorphic environments. Ore Geol Rev 2:205-229
25. Goodfellow WD (2003) Geology and genesis of the Caribou deposit, Bathurst Mining Camp, New Brunswick, Canada. In: Goodfellow WD, McCutcheon SR, Peter JM (eds) Massive sulfide deposits of the Bathurst Mining Camp, New Brunswick and northern Maine. Econ Geol Mon 11:327-360
26. Goodfellow WD (2007) Metallogeny of the Bathurst Mining Camp, northern New Brunswick. In: Goodfellow WD (ed) MinAral deposits of Canada: a synthesis of major deposit-types, district metallogeny, the evolution of geological provinces, and exploration methods. Geological Association of Canada, Mineral Deposits Division, Special Publication No. 5, pp 449-469
27. Goodfellow WD, Peter JM (1999) Reply: Sulphur isotope composition of the Brunswick No. 12 massive sulphide deposit, Bathurst Mining Camp, New Brunswick: Implications for ambient environment, sulphur source, and ore genesis. Can J Earth Sci 36:127-134
28. Goodfellow WD, McCutcheon SR (2003) Geologic and genetic attributes of volcanic sediment-hosted massive sulfide deposits of the Bathurst Mining Camp, northern New Brunswick - a synthesis. In: Goodfellow WD, McCutcheon SR, Peter JM (eds) Massive sulfide deposits of the Bathurst Mining Camp, New Brunswick and northern Maine. Econ Geol Mon 11:245-302
29. Goodfellow WD, Peter JM, Winchester JA, van Staal CR (2003) Ambient marine environment and sediment provenance during formation of massive sulfide deposits in the Bathurst Mining Camp: Importance of reduced bottom waters to sulfide precipitation and sulfide preservation. In: Goodfellow WD, McCutcheon SR, Peter JM (eds) Massive sulfide deposits of the Bathurst Mining Camp, New Brunswick and northern Maine. Econ Geol Mon 11:129-156
30. Gross GA, McLeod CR (1980) A preliminary assessment of the chemical composition of iron formations in Canada. Can Mineral 18:223-229
31. Hannington MD, Scott SD (1989) Sulfidation equilibria as guides to gold mineralization in volcanogenic massive sulfides: Evidence from sulfide mineralogy and the composition of sphalerite. Econ Geol 84:1978-1995
32. Hannington MD, Peter JM, Scott SD (1986) Gold in sea-floor polymetallic sulfide deposits. Econ Geol 81:1867-1883
33. Hannington MD, Herzig PM, Scott SD (1991) Auriferous hydrothermal precipitates on the modern seafloor. In: Foster RP (ed) Gold metallogeny and exploration. Blackie, Glasgow, pp 249-282
34. Hannington MD, Tivey MK, Larocque ACL, Petersen S, Rona PA (1995) The occurrence of gold in sulfide deposits of the TAG hydrothermal field, Mid-Atlantic Ridge. Can Mineral 33:1285-1310
35. Hannington MD, Galley AG, Herzig PM, Petersen S (1998) Comparison of the TAG mound and stockwork complex with Cyprus-type massive sulfide deposits. In Herzig PM, Humphris SE, Miller DJ, Zierenberg RA (eds) Proceedings of the ocean drilling program, scientific results. 158:389-415
36. Hannington MD, Poulsen KH, Thompson JFH, Sillitoe RH (1999a) Volcanogenic gold in the massive sulfide environment. In: Barrie CT, Hannington MD (eds) Volcanic-associated massive sulfide deposits: processes and examples in modern and ancient settings. Rev Econ Geol 8:325-356
37. Hannington MD, Bleeker W, Kjarsgaard I (1999b) Sulfide mineralogy, geochemistry and ore genesis of the Kidd Creek deposit: Part I. north, central, and south orebodies. In: Hannington MD, Barrie CT (eds) The giant Kidd Creek volcanogenic massive sulfide deposit, western Abitibi subprovince, Canada. Econ Geol Mon 10:163-244
38. 2 S-bearing aqueous solutions at 250-350°C. Geochim Cosmochim Acta 55:2111-2126
39. Heinrich CA, Eadington PJ (1986) Thermodynamic predictions of the hydrothermal chemistry of arsenic, and their significance for the paragenetic sequence of some cassiterite-arsenopyrite-base metal sulfide deposits. Econ Geol 81:511-529
40. Helgeson HC (1969) Thermodynamics of hydrothermal systems at elevated temperatures and pressures. Am J Sci 267:729-804
41. Henley RW (1973) Solubility of gold in hydrothermal chloride solutions. Chem Geol 11:73-87
42. Hennigh Q, Hutchinson RW (1999) Cassiterite at Kidd Creek: An example of volcanogenic massive sulfide-hosted tin mineralization. In: Hannington MD, Barrie CT (eds) The giant Kidd Creek volcanogenic massive sulfide deposit, western Abitibi subprovince, Canada. Econ Geol Mon 10:431-440
43. Hinchey JG, Wilton DHC, Tubrett MN (2003) A LAM-ICP-MS study of the distribution of gold in arsenopyrite from the Lodestar prospect, Newfoundland, Canada. Can Mineral 41:353-364
44. Huston DL(2000) Gold in volcanic-hosted massive sulfide deposits: distribution, genesis, and exploration. In Hagemann SG, Brown PE (eds) Gold in 2000. Rev Econ Geol 13:401-426
45. Huston DL, Large RR (1987) Precious metals in the Rosebery north-end orebody, Tasmania, Australia. Proceedings Pacific Rim Congress 87, abastract, pp 199-203
46. Huston DL, Large RR (1989) A chemical model for the concentration of gold in volcanogenic massive sulphide deposits. Ore Geol Rev 4:171-200
47. Huston DL, Bottrill RS, Creelman RA, Zaw K, Ramsden TR, Rand SW, Gemmell JB, Jablonski W, Sie SH, Large RR (1992) Geologic and geochemical controls on the mineralogy and grain size of gold-bearing phases, eastern Australian volcanic-hosted massive sulfide deposits. Econ Geol 87:542-563
48. 34S values and implications for the source of sulfur in volcanogenic hydrothermal systems. Econ Geol 90:1167-1196
49. Hutchinson RW (1973) Volcanogenic sulfide deposits and their metallogenic significance. Econ Geol 68:1223-1246
50. Ishibashi J, Urabe T (1995) Hydrothermal activity related to arc-backarc magmatism in the western Pacific. In: Taylor B (ed) Backarc basins: tectonics and magmatism. Plenum, New York, pp 451-495
51. Jackson SE (2001) The application of Nd:YAG laser in LA-ICP-MS. In: Sylvester P (ed) Laser-ablation in the earth sciences: Principles and application, short course, vol 29. Mineralogical Association of Canada, Ontario, pp 29-45
52. Jambor JL (1979) Mineralogical evaluation of proximal-distal features in New Brunswick massive-sulfide deposits. Can Mineral 17:649-664
53. Jonasson IR, Sangster DF (1978) Zn:CD ratios for sphalerites separated from some Canadian sulphide ore samples. Curr Res Geol Surv Can, pp 195-201
54. Kretschmar U, Scott SD (1976) Phase relations involving arsenopyrite in the system Fe-As-S and their application. Can Mineral 14:364-386
55. Large RR (1977) Chemical evolution and zonation of massive sulfide deposits in volcanic terrains. Econ Geol 72:549-572
56. Large RR (1992) Australian volcanic-hosted massive sulfide deposits: features, styles and genetic models. Econ Geol 87:471-510
57. Larocque ACL, Hodgson CJ, Lafleur PJ (1993) Gold distribution in the Mobrun volcanic-associated massive sulfide deposit, Noranda, Quebec: A preliminary evaluation of the role of metamorphic remobilization. Econ Geol 88:1443-1459
58. Larocque ACL, Hodgson CJ, Cabri LJ, Jackman JA (1995) Ion-microprobe analysis of pyrite, chalcopyrite and pyrrhotite from the Mobrun VMS deposit in northwestern Quebec: Evidence for metamorphic remobilization of gold. Can Mineral 33:373-388
59. LeBlanc S (1989) Massive sulphide-associated gold: Brunswick No. 12 Mine, Bathurst, New Brunswick. B.Sc. thesis, University of New Brunswick, Fredericton, NB, p 51
60. Leistel JM, Marcoux E, Deschamps Y, Joubert M (1998) Antithetic behaviour of gold in the volcanogenic massive sulphide deposits of the Iberian Pyrite Belt. Miner Depos 33:82-97
61. Lentz DR (1996a) Trace-element systematics of felsic volcanic rocks associated with massive-sulphide deposits in the Bathurst Mining Camp: petrogenetic, tectonic and chemostratigraphic implications for VMS exploration. In: Wyman DA (ed) Trace element geochemistry of volcanic rocks: Applications for massive sulphide exploration, short course, vol 12. Geological Association of Canada, pp 359-402
62. Lentz DR (1996b) Recent advances in lithogeochemical exploration for massive-sulphide deposits in volcano-sedimentary environments: petrogenetic, chemostratigraphic, and alteration aspects with examples from the Bathurst Camp, New Brunswick. In: Carroll BMW (ed) Current research 1995. New Brunswick Department of Natural Resources and Energy, Minerals and Energy Division, Mineral Resource Report 96-1, pp 73-119
63. Lentz DR (1999a) Petrology, geochemistry, and oxygen isotope interpretation of felsic volcanic and related rocks hosting the Brunswick 6 and 12 massive sulfide deposits (Brunswick Belt), Bathurst Mining Camp, New Brunswick, Canada. Econ Geol 94:57-86
64. Lentz DR (1999b) Deformation-induced mass transfer in felsic volcanic rocks hosting the Brunswick No. 6 massive sulfide deposit, New Brunswick: Geochemical effects and petrogenetic implications. Can Mineral 37:489-512
65. Lentz DR (2002) Sphalerite and arsenopyrite at the Brunswick No. 12 massive-sulfide deposit, Bathurst Camp, New Brunswick: Constraints on P-T evolution. Can Mineral 40:19-31
66. Lentz DR, Goodfellow WD (1993) Petrology and mass-balance constraints on the origin of quartz-augen schist associated with the Brunswick massive sulfide deposits, Bathurst, New Brunswick. Can Mineral 31:877-903
67. Lentz DR, van Staal CR (1995) Predeformational origin of massive sulfide mineralization and associated footwall alteration at the Brunswick 12 Pb-Zn-Cu deposit, Bathurst, New Brunswick: Evidence from the porphyry dike. Econ Geol 90:453-463
68. Lentz DR, Goodfellow WD (1996) Intense silicification of footwall sedimentary rocks in the stockwork alteration zone beneath the Brunswick No. 12 massive sulphide deposit, Bathurst, New Brunswick. Can J Earth Sci 33:284-302
69. Longerich HP (2001) Chemometrics. In: Sylvester P (ed) Laser-ablation in the earth sciences: Principles and application, short course, vol 29. Mineralogical Association of Canada, Ontario, pp 21-28
70. Longerich HP, Jackson SE, Günther D (1996) Laser ablation inductively coupled plasma mass spectrometric transient signal data acquisition and analyte concentration calculation. J Anal At Spectrom 11:899-904
71. Luff WM (1986) Silver distribution at the Brunswick No. 12 massive sulphide deposit. Min Eng Mag 38:963-968
72. Luff WM, Goodfellow WD, Juras S (1992) Evidence for a feeder pipe and associated alteration at the Brunswick No. 12 massive sulphide deposit. Explor Min Geol 1:167-185
73. Lusk J (1969) Base metal zoning in the Heath Steele B-1 orebody, New Brunswick, Canada. Econ Geol 64:509-518
74. Lusk J, Krouse HR (1997) Comparative stable isotope and temperature investigation of minerals and associated fluids in two regionally metamorphosed (Kuroko-type) volcanogenic massive sulfide deposits. Chem Geol 143:231-253
75. MacLellan KL, Lentz DR, McClenaghan SH (2006) Petrology, geochemistry, and genesis of the copper zone at the Brunswick No. 6 volcanogenic massive sulfide deposit, Bathurst Mining Camp, New Brunswick, Canada. Explor Min Geol 15:53-76
76. Marshall B, Gilligan LB (1987) An introduction to remobilization: information from ore-body geometry and experimental considerations. Ore Geol Rev 2:87-131
77. Marshall B, Vokes FM, Larocque ACL (2000) Regional metamorphic remobilization: Upgrading and formation of ore deposits. In: Spry PG, Marshall B, Vokes FM (eds) Metamorphosed and metamorphogenic ore deposits. Rev Econ Geol 11:19-38
78. Martin J, McClenaghan SH, Lentz DR (2006) Form and distribution of gold in the Brunswick No. 12 volcanogenic massive sulfide deposit, Bathurst Mining Camp, New Brunswick. IAGOD Conference Proceedings, Moscow, p 4
79. McAllister AL (1960) Massive sulphide deposits in New Brunswick. CIM Bull 53:88-98
80. McClay KR, Ellis PG (1983) Deformation and recrystallization of pyrite. Min Mag 47:527-538
81. McClenaghan SH (2002) Gold in massive sulphide deposits, Bathurst Mining Camp, New Brunswick: Form, distribution and genesis. M.Sc. thesis, University of Ottawa, Ottawa, ON, p 371
82. McClenaghan SH, Goodfellow WD, Lentz DR(2003) Gold in massive sulfide deposits, Bathurst Mining Camp: Distribution and genesis. In: Goodfellow WD, McCutcheon SR, Peter JM (eds) Massive sulfide deposits of the Bathurst Mining Camp, New Brunswick and northern Maine. Econ Geol Mon 11:303-326
83. McClenaghan SH, Lentz DR, Cabri LJ (2004) Abundance and speciation of gold in massive sulfides of the Bathurst Mining Camp, New Brunswick, Canada. Can Mineral 42:851-871
84. McClenaghan SH, Lentz DR, Beaumont-Smith CJ (2006) The gold-rich Louvicourt volcanogenic massive sulfide deposit, New Brunswick: A Kuroko analogue in the Bathurst Mining Camp. Explor Min Geol 15:127-154
85. McCutcheon SR, Luff WM, Boyle RW (2003) The Bathurst Mining Camp, New Brunswick, Canada: History of discovery and evolution of geologic models. In: Goodfellow WD, McCutcheon SR, Peter JM (eds) Massive sulfide deposits of the Bathurst Mining Camp, New Brunswick and northern Maine. Econ Geol Mon 11:17-36
86. Mercer W (1975) A solubility model for deposition of stratiform massive sulphide deposits, New Brunswick, and its relation to the distribution of gold and palladium. Ph.D. thesis, McMaster University, Hamilton ON, 225 p
87. Morrison GW, Rose WJ, Jaireth S (1991) Geological and geochemical controls on the silver content (fineness) of gold in gold-silver deposits. Ore Geol Rev 6:333-364
88. Moss R, Scott SD (2001) Geochemistry and mineralogy of gold-rich hydrothermal precipitates from the eastern Manus Basin, Papua New Guinea. Can Mineral 39:957-978
89. Newberry RJ, Schmidt JM (1990) Gold versus tin: Predictive mineralogy for zinc-copper-lead volcanogenic massive sulfide deposits. Geological Association of Canada Annual Meeting, Program with Abstracts, 15:A96
90. Newberry RJ, Crawford TC, Newkirk SR, Young LE, Nelson SW, Duke NA (1996) Volcanogenic massive sulfide deposits of Alaska. In: Goldfarb RJ, Miller LD (eds) Mineral deposits of Alaska. Econ Geol Mon 9:120-150
91. Ohmoto H (1996) Formation of volcanogenic massive sulfide deposits: The Kuroko perspective. Ore Geol Rev 10:135-177
92. Peter JM, Goodfellow WD (1996) Mineralogy, bulk and rare earth element geochemistry of massive sulphide-associated hydrothermal sediments of the Brunswick Horizon, Bathurst Mining Camp, New Brunswick. Can J Earth Sci 33:252-283
93. Petruk W, Schnarr JR (1981) An evaluation of the recovery of free and unliberated mineral grains, metals and trace elements in the concentrator of Brunswick Mining and Smelting Corp Ltd. CIM Bull 74:132-159
94. Pisutha-Arnond V, Ohmoto H (1983) Thermal history, and chemical and isotopic compositions of the ore-forming fluids responsible for the Kuroko massive sulfide deposits in the Hokuroku district of Japan. In: Ohmoto H, Skinner BJ (eds) The Kuroko and related volcanogenic massive sulfide deposits. Econ Geol Mon 5:523-558
95. Powe EM (2008) Petrology, geochemistry and distribution of the copper zones at the Brunswick No. 12 volcanogenic massive sulfide deposit, Bathurst Mining Camp, New Brunswick. B.Sc. thesis, University of New Brunswick, Fredericton NB, p 91
96. Renders PJ, Seward TM (1989) The stability of hydrosulphido- and sulphido-complexes of Au(I) and Ag(I) at 25°C. Geochim Cosmochim Acta 53:245-253
97. Rogers N, van Staal CR, McNicoll V, Theriault R (2003) Volcanology and tectonic setting of the northern Bathurst Mining Camp: Part 1. extension and rifting of the Popelogan Arc. In: Goodfellow WD, McCutcheon SR, Peter JM (eds) Massive sulfide deposits of the Bathurst Mining Camp, New Brunswick and northern Maine. Econ Geol Mon 11:157-180
98. Saif SI (1983) Petrographic and geochemical characteristics of iron-rich rocks and their significance in exploration for massive sulfide deposits, Bathurst, New Brunswick, Canada. J Geochem Explor 19:705-721
99. Sato T (1972) Behaviours of ore-forming solutions in seawater. Min Geol 22:31-42
100. Scott SD, Barnes HL (1971) Sphalerite geothermometry and geobarometry. Econ Geol 66:653-669
101. Seward TM (1973) Thio complexes of gold and the transport of gold in hydrothermal ore solutions. Geochim Cosmochim Acta 37:379-399
102. Seward TM (1991) The hydrothermal geochemistry of gold. In: Foster RP (ed) Gold metallogeny and exploration. Blackie, London, pp 37-62
103. Seward TM, Barnes HL (1997) Metal transport by hydrothermal fluids. In: Barnes HL (ed) Geochemistry of hydrothermal ore deposits, 3rd edn. Wiley, New York, pp 435-486
104. Shenberger DM, Barnes HL (1989) Solubility of gold in aqueous sulfide solutions from 150 to 350°C. Geochim Cosmochim Acta 53:269-278
105. Solomon M (2008a) Brine pool deposition for the Zn-Pb-Cu massive sulphide deposits of the Bathurst mining camp, New Brunswick, Canada. I. Comparisons with the Iberian pyrite belt. Ore Geol Rev 33:329-351
106. Solomon M (2008b) Brine-pool deposition for the Zn-Pb-Cu massive sulphide deposits of the Bathurst mining camp, New Brunswick, Canada. II. Ocean anoxia during mineralisation. Ore Geol Rev 33:352-360
107. Solomon M, Walshe JL (1979) The formation of massive sulfide deposits on the sea floor. Econ Geol 74:797-813
108. Stanton RL (1959) Mineralogical features and possible mode of emplacement of the Brunswick Mining and Smelting ore bodies, Gloucester County, New Brunswick. CIM Bull 52:631-643
109. Stanton RL (1960) General features of the conformable "pyritic" orebodies: Part I.- field association. CIM Bull 53:24-29
110. Sullivan RW, van Staal CR (1990) Age of metarhyolite from the Tetagouche Group, Bathurst, New Brunswick, from U-Pb isochron analyses of zircons enriched in common Pb. In: RadiRgenic age and isotopic studies: report 3. Curr Res Geol Surv Can, pp 109-117
111. Sullivan RW, van Staal CR (1996) Preliminary chronostratigraphy of the Tetagouche and Fournier groups in northern New Brunswick. In: Radiogenic age and isotopic studies: Report 9. Curr Res Geol Surv Can, pp 43-56
112. Sylvester PJ (2001) A practical guide to platinum-group element analysis of sulphides by laser-ablation-ICPMS. In: Sylvester P (ed) Laser-ablation in the earth sciences: Principles and application, short course, vol 29. Mineralogical Association of Canada, Ontario, pp 203-213
113. Tubrett MN, Míková J, Sylvester PJ, Košler J (2003) Trace element composition and homogeneity of MASS-1 sulphide calibration standard. In: 5th International Conference on the analysis of Geological and Environmental Materials, Rovaniemi
114. van Achterbergh E, Ryan CG, Jackson SE, Griffin WL (2001) Data reduction software for LA-ICP-MS. In: Sylvester P (ed) Laser-ablation in the earth sciences: Principles and application, short course, vol 29. Mineralogical Association of Canada, Ontario, pp 239-243
115. van Staal CR (1985) The structure and metamorphism of the Brunswick Mines area, Bathurst, New Brunswick, Canada. Ph.D. thesis, University of New Brunswick, Fredericton, NB, p 484
116. van Staal CR (1987) Tectonic setting of the Tetagouche Group in northern New Brunswick: Implications for plate tectonic models of the northern Appalachians. Can J Earth Sci 24:1329-1351
117. van Staal CR (1994) Geology. Brunswick Mines, New Brunswick. Geol Surv Can Map 1836A, Scale 1:20 000
118. van Staal CR, Williams PF (1984) Structure, origin and concentration of the Brunswick 12 and 6 orebodies. Econ Geol 79:1669-1692
119. van Staal CR, Winchester JA, Bedard JH (1991) Geochemical variations in Middle Ordovician volcanic rocks of the northern Miramichi Highlands and their tectonic significance. Can J Earth Sci 28:1031-1049
120. van Staal CR, Wilson RA, Rogers N, Fyffe LR, Langton JP, McCutcheon SR, McNicoll V, Ravenhurst CE (2003) Geology and tectonic history of the Bathurst Supergroup, Bathurst Mining Camp and its relationship to coeval rocks in southwestern New Brunswick and adjacent Maine - a synthesis. In: Goodfellow WD, McCutcheon SR, Peter JM (eds) Massive sulfide deposits of the Bathurst Mining Camp, New Brunswick and northern Maine. Econ Geol Mon 11:37-60
121. Wagner FE, Marion P, Regnard JR (1986) Mössbauer study of the chemical state of gold in gold ores. In: Proc Int Conf, S. Afr Inst Min Metal, pp 435-443
122. Wagner T, Klemd R, Wenzel T, Mattsson B (2007) Gold upgrading in metamorphosed massive sulfide ore deposits: Direct evidence from laser-ablation-inductively coupled plasma-mass spectrometry analysis of invisible gold. Geology 35:775-778
123. Wilson SA, Ridley WI, Koenig AE (2002) Development of sulfide calibration standards for the laser ablation inductively-coupled mass spectrometry technique. J Anal At Spectrom 17:406-409
124. 2 solutions from 200° to 350°C. Econ Geol 82:1864-1887