Solubility enhancement of seven metal contaminants using carboxymethyl-β-cyclodextrin (CMCD)

Journal of Contaminant Hydrology

Volumn 107, Issue 3-4, 2009, Pages 108-113

  Skold, Magnus E ^a   Thyne, Geoffrey D ^a   Drexler, John W ^b   McCray, John E ^a  

^a Department of Geology and Geological Engineering   (United States)

^b UNIVERSITY OF COLORADO   (United States)

Author keywords

Cyclodextrin; Metals; Remediation; Solubility enhancement

Indexed keywords

CARBOXYMETHYL; COMPLEXATION MODELS; COMPLEXING AGENTS; CONDITIONAL FORMATION CONSTANTS; CONDITIONAL STABILITY; CONFIDENCE INTERVAL; CONTAMINATED SOILS; EXPERIMENTAL DATA; METAL CONTAMINANTS; METAL SALT; SOLUBILITY ENHANCEMENT; STABLE METALS; TEMPERATURE VARIATION;

BARIUM; CADMIUM; CADMIUM COMPOUNDS; CALCIUM; GEOLOGIC MODELS; GROUNDWATER; GROUNDWATER POLLUTION; HYDROGEOLOGY; METAL COMPLEXES; METAL IONS; METALS; ORGANIC POLLUTANTS; REMEDIATION; SOIL POLLUTION; SOLUBILITY; TERNARY SYSTEMS; ZINC;

SOIL POLLUTION CONTROL;

BARIUM ION; CADMIUM; CALCIUM ION; CARBOXYMETHYL BETA CYCLODEXTRIN; LEAD; METAL ION; NICKEL; STRONTIUM; ZINC ION;

CONCENTRATION (COMPOSITION); CONFIDENCE INTERVAL; EXPERIMENTAL STUDY; GROUNDWATER POLLUTION; ORGANIC POLLUTANT; REACTION KINETICS; REMEDIATION; SOIL POLLUTION; SOLUBILITY; WASTE TREATMENT;

ARTICLE; BIOREMEDIATION; COMPLEX FORMATION; GEOCHEMISTRY; PRIORITY JOURNAL; SOIL POLLUTION; SOLUBILITY; TEMPERATURE DEPENDENCE; WATER CONTAMINATION;

BETA-CYCLODEXTRINS; ENVIRONMENTAL POLLUTION; METALS; SOLUBILITY; SURFACE-ACTIVE AGENTS;

EID: 67649207608     PISSN: 01697722     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jconhyd.2009.04.006     Document Type: Article

References (24)

1. Alter S.R., Brusseau M.L., Piatt J.J., Ray-Maitra A., Wang J.-M., and Cain R.B. Use of tracer tests to evaluate the impact of enhanced-solubility flushing on in-situ biodegradation. Journal of Contaminant Hydrology 34 (2003) 191-202
2. Blanford W.J., Barackman M.L., Boving T.B., Klingel G.R., Johnson G.R., and Brusseau M.L. Cyclodextrin-enhanced vertical flushing of a trichloroethane contaminated aquifer. Ground Water Monitoring and Remediation 21 4 (2001) 58-66
3. Boving T.B., and McCray J.E. Cyclodextrin-enhanced remediation of organic and metal contaminants in porous media and groundwater. Remediation Journal 10 (2000) 59-83
4. Brusseau M.L., Wang X., and Wang W.-Z. Simultaneous elution of heavy metals and organic compounds from soil by cyclodextrin. Environmental Science and Technology 31 (1997) 1087-1092
5. Chatain V., Hanna K., de Brauer C., Bayard R., and Germain P. Enhanced solubilization of arsenic and 2,3,4,6 tetrachlorophenol from soils by a cyclodextrin derivative. Chemosphere 57 (2004) 197-206
6. CRC Press. CRC Handbook of chemistry and physics. 85th Edition (2004), CRC Press, Cleveland, OH
7. Dean J.R. Lange's handbook of chemistry. 15th Edition (1999), McGraw-Hill, New York
8. Donia A.M. Synthesis, identification and thermal analysis of coprecipitates of silver-(cobalt, nickel, copper and zinc) oxalate. Polyhedron 16 (1997) 3013-3031
9. Martell A.E., and Smith R.M. Critical stability constants, Volume 3: Other organic ligands (1977), Plenum Press, New York
10. McCray J.E., and Brusseau M.K. Cyclodextrin-enhanced in situ flushing of multiple-component immiscible organic liquid contamination at the field scale: analysis of dissolution behavior. Environmental Science and Technology 33 (1999) 89-95
11. McCray E.M., Bryan K.D., Cain R.B., Johnson G.R., Blanford W.J., and Brusseau M.L. Field test of cyclodextrin for enhanced in-situ flushing of multiple-component immiscible organic liquid contamination: comparison to water flushing. In: Brusseau M.L., Sabatini D.A., Gierke J.S., and Annable M.D. (Eds). Innovative Subsurface Remediation, ASC Symposium Series vol. 725 (1999) 136-152
12. Mulligan C.N., Yong R.N., and Gibbs B.F. Remediation technologies for metal-contaminated soils and groundwater: an evaluation. Engineering Geology 60 (2001) 193-207
13. Parkhurst, D.L., Appelo, C.A.J., 1999. User's guide to phreeqc (version 2) - A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations; U.S. Geological Survey Water-Resources Investigations Report 99-4259; U.S. Geological Survey: Denver, CO.
14. Poeter, E.P., Hill, M.C., 1998. Documentation of UCODE, a computer code for universal inverse modeling: U.S. Geological Survey, Water-Resources Investigations Report 98-4080.
15. Poeter E.P., Hill M.C., Banta E.R., Mehl S., and Christensen S. UCODE_2005 and six other computer codes for universal sensitivity analysis, calibration, and uncertainty evaluation: U.S. Geological Survey Techniques and Methods 6-A11, 283p (2005)
16. Semer R., and Reddy K.R. Evaluation of soil washing process to remove mixed contaminants from a sandy loam. Journal of Hazardous Materials 45 (1996) 45-57
17. Skold M.E., Thyne G.D., Drexler J.W., and McCray J.E. Determining conditional stability constants for Pb complexation by carboxymethyl-β-cyclodextrin (CMCD). Journal of Contaminant Hydrology 93 (2007) 203-215
18. Skold M.E., Thyne G.D., and McCray J.E. Using UCODE_2005 and PHREEQC to determine thermodynamic constants from experimental data. Ground Water 45 (2007) 368-373
19. Smedley P.L., and Kinniburg D.G. A review of the source, behavior and distribution of arsenic in natural waters. Applied Geochemistry 17 (2002) 517-568
20. Stumm W., and Morgan J.J. Aquatic chemistry. 3rd Edition (1995), John Wiley and sons, New York
21. Tick G.R., Lourenso F., Wood A.L., and Brusseau M.L. Pilot-scale demonstration of cyclodextrin as a solubility-enhancement agent for remediation of a tetrachloroethene-contaminated aquifer. Environmental Science and Technology 37 (2003) 5829-5834
22. Wang X., and Brusseau M.L. Solubilization of some low-polarity organic compounds by hydroxypropyl-β-cyclodextrin. Environmental Science and Technology 27 (1993) 2821-2825
23. Wang X., and Brusseau M.L. Simultaneous complexation of organic compounds and heavy metals by a modified cyclodextrin. Environmental Science and Technology 29 (1995) 2632-2635
24. Wang X., Yolcubal I., Wang W., Artiola J., Maier R., and Brusseau M.L. Enhanced removal of mercury from soil by cyclodextrin, ramnolipid, and calcium chloride. Environmental Toxicology and Chemistry 23 (2004) 1888-1892