Reactions of Cp*2 Yb(THF)2 with TCNQ and TCNB. A Novel Type of Reactivity of TCNQ toward Metallocenes. The First Example of the π-Dimer [TCNB2]2-

Organometallics

Volumn 28, Issue 12, 2009, Pages 3421-3425

  Trifonov, Alexander A ^a   Gudilenkov, Ivan D ^a   Fukin, Georgy K ^a   Cherkasov, Anton V ^a   Larionova, Julia ^b  

^a G A RAZUVAEV INSTITUTE OF ORGANOMETALLIC CHEMISTRY   (Russian Federation)

^b UNIVERSITÉ DE MONTPELLIER   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLIC CARBON; EQUIMOLAR AMOUNT; METAL CENTERS; METALLOCENES; MOLAR RATIO; ONE-ELECTRON REDUCTIONS; TETRACYANOQUINODIMETHANE;

ATOMS; ORGANOMETALLICS;

YTTERBIUM;

EID: 67449123370     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9001318     Document Type: Article

References (47)

1. (a) Miller, J. S. Angew. Chem., Int. Ed. 2006, 45, 2508-2525.
2. (b) Dunbar, K. R. Angew. Chem., Int. Ed. Engl. 1996, 35, 1659-1661.
3. (a) Peover, M. E. Trans. Faraday Soc. 1962, 58, 2370-2374.
4. (b) Moscherosch, M.; Waldhor̈, E.; Binder, H.; Kaim, W.; Fiedler, J. Inorg. Chem. 1995, 34, 4326-4335.
5. (c) Munakata, M.; Ling Ning, G.; Kuroda-Sowa, T.; Maekawa, M.; Suenaga, Y.; Horino, T. Inorg. Chem. 1998, 37, 5651-5656.
6. (a) Kaim, W.; Moscherosch, M. Coord. Chem. Rev. 1994, 129, 157-193.
7. (b) Miller, J. S.; Calabrese, J. C.; Epstein, A. J.; Bigelow, R. W.; Zhang, J. H.; Reiff, W. M. J. Chem. Soc., Chem. Commun. 1986, 1026-1028.
8. (c) Miller, J. S.; Calabrese, J. S.; Rommelmann, H.; Chittipeddi, S. R.; Zhang, J. H.; Reiff, W. M.; Epstein, A. J. J. Am. Chem. Soc. 1987, 109, 769-781.
9. (d) Taliaferro, M. L.; Thorum, M. S.; Miller, J. S. Angew. Chem., Int. Ed. 2006, 45, 5326-5331.
10. (e) Zhao, H.; Bazile, M. J., Jr.; Galań-Mascaroś, J.R.; Dunbar, K. R. Angew. Chem., Int. Ed. 2003, 42, 1015-1018.
11. (f) Miller, J. S.; Epstein, A. J. Angew. Chem., Int. Ed. 1994, 33, 385-415.
12. (a) Zhao, H.; Heintz, R. A.; Dunbar, K. R.; Rogers, R. D. J. Am. Chem. Soc. 1996, 118, 12844-12845.
13. (b) Zhao, H.; Heintz, R. A.; Ouyang, X.; Dunbar, K. R.; Campana, C. F.; Rogers, R. D. Chem. Mater. 1999, 11, 736-746.
14. (c) Carlucci, L.; Ciani, G.; van Gudenberg, D. W.; Proserpio, D. M. New J. Chem. 1999, 23, 397-401.
15. (a) Candela, G. A.; Swartzenbruder, L. J.; Miller, J. S.; Rice, M. J. J. Am. Chem. Soc. 1979, 101, 2755-2756.
16. (b) Miller, J. S.; Reis, A. H.; Gebert, E.; Ritsko, J. J.; Salaneck, W. R.; Kovnat, L.; Cape, T. W.; Dyune, R. P. J. Am. Chem. Soc. 1979, 101, 7111-7113.
17. (c) Reis, A. H.; Preston, L. D.; Williams, J. M.; Peterson, S. W.; Candela, G. A.; Swartzenbruder, L. J.; Miller, J. S. J. Am. Chem. Soc. 1979, 101, 2756-2758.
18. (d) Miller, J. S.; Zhang, J. H.; Reiff, W. M.; Dixon, D. A.; Preston, L. D.; Reis, A. H.; Gebert, E.; Extine, M.; Troup, J.; Epstein, A. J.; Ward, M. D. J. Phys. Chem. 1987, 91, 4344-4360.
19. (e) Broderick, E.; Eichhorn, D. M.; Liu, X.; Toscano, P. J.; Owens, S. M.; Hoffman, B. M. J. Am. Chem. Soc. 1995, 117, 3641-3642.
20. (f) Broderick, W. E.; Hoffman, B. M. J. Am. Chem. Soc. 1991, 113, 6334-6335.
21. (g) Eichhorn, D. M.; Skee, D. C.; Broderick, W. E.; Hoffman, B. M. Inorg. Chem. 1993, 32, 491-492.
22. (h) Broderick, W. E.; Thompson, J. A.; Day, E. P.; Hoffman, B. M. Science 1990, 249, 401-403.
23. (i) Chi, K.-M.; Calabrese, J. C.; Reiff, W. M.; Miller, J. S. Organometallics 1991, 10, 688-693.
24. (j) Choukroun, R.; Lorber, C.; de Caro, D.; Vendier, L. Organometallics 2006, 25, 4243-4246.
25. (a) Raebiger, J. W.; Miller, J. S. Inorg. Chem. 2002, 41, 3308-3312.
26. (b) Maunder, G. H.; Sella, A.; Elsegood, M. R. J. J. Organomet. Chem. 2001, 619, 152-156.
27. (c) Klapshina, L. G.; Grigoryev, I. S.; Douglas, W. E.; Trifonov, A. A.; Gudilenkov, I. D.; Semenov, V. V.; Bushuk, B. A.; Bushuk, S. B. Chem. Commun. 2007, 1942-1944.
28. Tilley, T. D.; Andersen, R. A.; Spencer, B.; Zalkin, A. Inorg. Chem. 1982, 21, 2647-2649.
29. (a) Watson, P. L.; Tulip, T. H.; Williams, I. Organometallics 1990, 9, 1999-2009.
30. (b) Tilley, T. D.; Andersen, R. A.; Zalkin, A. Inorg. Chem. 1983, 22, 856-859.
31. Zhang, J.; Ma, L.; Cai, R.; Wenig, L.; Zhou, X. Organometallics 2005, 24, 738-742.
32. Long, R. E.; Sparks, R. A.; Trueblood, K. N. Acta Crystallogr. 1965, 18, 932-939.
33. Allen, F. A.; Konnard, O.; Watson, D. G.; Brammer, L.; Orpen, G.; Taylor, R. J. Chem. Soc., Perkin Trans. 1987, 1-34.
34. (a) Carlin, R. D. L., Magnetochemistry; Springer-Verlag: Berlin, 1986; p 86.
35. (b) Cotton, S. Lanthanide and Actinide Chemistry; Wiley: New York, 2006, p 64.
36. Benelli, C.; Caneschi, A.; Gatteschi, D.; Guillou, O.; Pardi, L. Inorg. Chem. 1990, 29, 1750-1755.
37. Wang, Y.; Shen, Q.; Xue, F.; Yu, K. J. Organomet. Chem. 2000, 598, 359-364.
38. (a) Pi, C.; Zhang, Z.; Pang, Z.; Zhang, J.; Luo, J.; Chen, Z.; Wenig, L.; Zhou, X. Organometallics 2007, 26, 1934-1946.
39. (b) Schulz, M.; Boncella, J. M.; Berg, D. J.; Tilley, T. D.; Andersen, R. A. Organometallics 2002, 21, 460-472.
40. (c) Zhou, X.; Huang, Z.; Cai, R.; Zhang, L.-B.; Zhang, L.-X.; Huang, X. Organometallics 1999, 18, 4128-4133.
41. Prout, C. K.; Tickle, I. J. J. Chem. Soc., Perkin Trans. 2 1973, 520-523.
42. Janiak, C. Dalton Trans. 2000, 3885-3896.
43. Bagnato, J. D.; Shum, W. W.; Strohmeier, M.; Grant, D. M.; Arif, A. M.; Miller, J. S. Angew. Chem., Int. Ed. 2006, 45, 5322-5326.
44. Watson, P. L. J. Chem. Soc., Chem. Commun. 1980, 652-654.
45. Boudreaux, E. A. L.; Mulay, N. Theory and Applications of Molecular Paramagnetism; Wiley: New York, 1976.
46. Sheldrick, G. M. SHELXTL v.6.12, Structure Determination Software Suite; Bruker AXS, Madison, WI, 2000.
47. Sheldrick, G. M. SADABS v.2.01, Bruker/Siemens Area Detector Absorption Correction Program; Bruker AXS, Madison, WI, 1998.