SPEEK based composite PEMs containing tungstophosphoric acid and modified with benzimidazole derivatives

Journal of Membrane Science

Volumn 336, Issue 1-2, 2009, Pages 118-127

  Celso, Fabrício ^a   Mikhailenko, Serguei D ^a   Kaliaguine, Serge ^a   Duarte, Ueiler L ^b   Mauler, Raquel S ^b   Gomes, Ailton S ^c  

^a UNIVERSITÉ LAVAL   (Canada)

^b FEDERAL UNIVERSITY OF RIO GRANDE DO SUL   (Brazil)

^c FEDERAL UNIVERSITY OF RIO DE JANEIRO   (Brazil)

Author keywords

Benzimidazole derivatives; Composite PEM; Heteropolyacid; SPEEK

Indexed keywords

CROSSLINKING; PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC);

BENZIMIDAZOLE DERIVATIVES; COMPOSITE PEM; CROSS LINKING AGENTS; HETEROPOLY ACIDS; MEMBRANE PROPERTIES; PHYSICOCHEMICAL METHODS; SPEEK; TUNGSTOPHOSPHORIC ACID;

COMPOSITE MEMBRANES;

BENZIMIDAZOLE DERIVATIVE; ELECTROLYTE; PHOSPHOTUNGSTIC ACID; POLYMER;

ARTICLE; ARTIFICIAL MEMBRANE; COMPOSITE MATERIAL; CROSS LINKING; DEVICE; ELECTRIC CONDUCTIVITY; FUEL CELL; MOLECULAR STABILITY; POLYMER ELECTROLYTE MEMBRANE; PRIORITY JOURNAL;

EID: 67349255244     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2009.03.017     Document Type: Article

References (22)

1. http://isiknowledge.com.
2. Savadogo O. Emerging membranes for electrochemical systems: (I) solid polymer electrolyte membranes for fuel cell systems. J. New Mater. Electrochem. Syst. 1 1 (1998) 47-66
3. Kreuer K.D. On the development of proton conducting polymer membranes for hydrogen and methanol fuel cells. J. Membr. Sci. 185 (2002) 29-39
4. Roziere J., and Jones D.J. Non-fluorinated polymer materials for proton exchange membrane fuel cells. Annu. Rev. Mater. Res. 33 (2003) 503-555
5. Alberti G., and Casciola M. Composite membranes for medium-temperature PEM fuel cells. Annu. Rev. Mater. Res. 33 (2003) 129-154
6. Jin X., Bishop M.T., Ellis T.S., and Karasz F.E. A sulfonated poly(aryl-ether-ketone). Brit. Polym. J. 17 (1985) 4
7. Kerres J.A. Development of ionomer membranes for fuel cells. J. Membr. Sci. 185 (2001) 3-27
8. Kerres J., Zhang W., Jorissen L., and Gogel V. Application of different types of polyaryl-blend-membranes in DMFC. J. New Mater. Electrochem. Syst. 5 (2002) 97-107
9. Kerres J., Ullrich A., Hein M., Gogel V., Friedrich K.A., and Jorissen L. Cross-linked polyaryl blen membranes for polymer electrolyte fuel cells. Fuel Cells 4 (2004) 105-112
10. Mikhailenko S.D., Wang K.P., Kaliaguine S., Xing P., Robertson G., and Guiver M.D. Proton conducting membranes based on cross-linked sulfonated poly(ether ether ketone). J. Membr. Sci. 233 (2004) 93
11. Mikhailenko S.D., Robertson G.P., Guiver M.D., and Kaliaguine S. Properties of PEMs based on cross-linked sulfonated poly(ether ether ketone). J. Membr. Sci. 285 (2006) 306-316
12. Gao Y., Robertson G.P., Kim D.S., Guiver M.D., Mikhailenko S.D., Li X., and Kaliaguine S. Comparison of PEM properties of copoly(arylether nitrile)s containing sulfonic acid bonded to naphthalene in structurally different ways. Macromolecules 40 (2007) 1512-1520
13. Gao Y., Robertson G.P., Guiver M.D., Wang G., Jian X., Mikhailenko S.D., Li X., and Kaliaguine S. Sulfonated copoly(phthalazinone ether ketone nitrile)s as proton exchange membrane materials. J. Membr. Sci. 278 (2006) 26-34
14. Zaidi S.M.J., Mikhailenko S.D., Robertson G.P., Guiver M.D., and Kaliaguine S. Proton conducting composite membranes from polyether ether ketone and heteropolyacids for fuel cell applications. J. Membr. Sci. 173 (2000) 17
15. Nunes S.P., Ruffmann B., Rikowski E., Vetter S., and Richau K. Inorganic modification of proton conductive polymer membranes for direct methanol fuel cells. J. Membr. Sci. 203 (2002) 215-225
16. Deluca N.W., and Elabd Y.A. PEM for the DMFC: a review. J. Polym. Sci. Part B: Polym. Phys. 44 (2006) 2201-2225
17. Tan A.R., Carvalho L.M., and Gomes A.S. Nanostructured proton-conducting membranes for fuel cell applications. Macromol. Symp. 229 (2005) 168-178
18. Kaliaguine S., Mikhailenko S.D., Wang K.P., Xing P., Robertson G., and Guiver M.D. Properties of SPEEK based PEMs for fuel cell application. Catal. Today 82 (2003) 213
19. Essayem N., Tong Y.Y., Jobic H., and Vedrine J.C. Characterization of protonic sites in H3PW12O40 and Cs1.9H1.1PW12O40: a solid-state 1H,2H,31P MAS-NMR and inelastic neutron scattering study on samples prepared under standard reaction conditions. Appl. Catal. A: Gen. 194-195 13 March (2000) 109-122
20. Kopitzke R.W., Linkous C.A., and Nelson G.L. Thermal stability of high temperature polymers and their sulfonated derivatives under inert, and saturated vapour conditions. Polym. Degrad. Stab. 67 (2000) 335
21. Jones D.J., and Roziere J. Protonic species and their structures. In: Colomban Ph. (Ed). Proton Conductors: Solids, Membranes and Gels-materials and Devices (1992), Cambridge University Press, New York 18-37
22. Colomban P., and Novak A. From crystalline to amorphous hydrates: inorganic polymers, glasses, clays, gels and porous media. In: Colomban Ph. (Ed). Proton Conductors: Solids, Membranes and Gels-materials and Devices (1992), Cambridge University Press, New York 272-293