The unusual magnetic properties of kuramite-stannite pseudobinary series: A SQUID and EPR survey

Physics and Chemistry of Minerals

Volumn 36, Issue 6, 2009, Pages 301-309

  Di Benedetto, F ^a   Evstigneeva, T ^b   Borgheresi, M ^a   Caneschi, A ^a   Romanelli, M ^a  

^a UNIVERSITY OF FLORENCE   (Italy)

^b INSTITUTE OF GEOLOGY OF ORE DEPOSITS   (Russian Federation)

Author keywords

Crystal chemistry; Cu(II); Direct magnetometry; EPR; Kuramite; Local order; Stannite; Superexchange interaction

Indexed keywords

CU(II); DIRECT MAGNETOMETRY; EPR; KURAMITE; LOCAL ORDER; STANNITE; SUPEREXCHANGE INTERACTION;

ANTIFERROMAGNETISM; ELECTRON RESONANCE; ELECTRON SPIN RESONANCE SPECTROSCOPY; IRON COMPOUNDS; MAGNETIC PROPERTIES; MAGNETOMETERS; PARAMAGNETIC MATERIALS; PARAMAGNETIC RESONANCE; PARAMAGNETISM; QUANTUM THEORY; SULFUR; TERNARY SYSTEMS; TIN;

CRYSTAL CHEMISTRY;

COPPER; CRYSTAL CHEMISTRY; ELECTRON SPIN RESONANCE; ION EXCHANGE; MAGNETIC PROPERTY; SULFIDE;

EID: 67349248134     PISSN: 03421791     EISSN: 14322021     Source Type: Journal    
DOI: 10.1007/s00269-008-0278-7     Document Type: Article

References (28)

1. Andreasen JW, Makovicky E, Lebech B, Karup Møller S (2008) The role of iron in tetrahedrite and tennantite determined by Rietveld refinement of neutron powder diffraction data. Phys Chem Miner (in press). doi: 10.1007/s00269-008-0239-1
2. Bente K (1987) Stabilization of Cu-Fe-Bi-Pb-Sn-Sulfides. Mineral Petrol 36:205-217. doi: 10.1007/BF01163260
3. Borgheresi M, Cipriani C, Di Benedetto F, Pratesi G, Romanelli M (2006) Revisione delle collezioni del Museo di Mineralogia di Firenze: Le covelline. Museol Sci 21(2):317-328
4. Borgheresi M, Di Benedetto F, Caneschi A, Pratesi G, Romanelli M, Sorace L (2007) An EPR and SQUID magnetometry study of bornite. Phys Chem Miner 34:609-619. doi: 10.1007/s00269-007-0175-5
5. 4, the synthetic analogue of stannite. Phys Chem Miner 31:190-193. doi: 10.1007/s00269-004-0381-3
6. 3. J Solid State Chem 139:144-151. doi: 10.1006/jssc.1998.7822
7. Chen XY, Wang X, An CH, Liu JW, Qian YT (2003) Preparation and characterization of ternary Cu-Sn-E (E = S, Se) semiconductor nanocrystallites via a solvothermal element reaction route. J Cryst Growth 256:368-376. doi: 10.1016/S0022-0248(03)01338-1
8. Danti C, Bente K, Doering Th, Bernardini GP, Cipriani C (2001). The aikinite-bismuthinite isoseries: A minerochemical study. N Jb Miner Mh 221-234
9. 4). Università di Firenze, unpublished "Laurea" thesis
10. 13. Phys Chem Miner 32:155-164. doi: 10.1007/ s00269-005-0449-8
11. 57Fe Mössbauer spectroscopy. Phys Chem Miner 32:339-348. doi: 10.1007/ s00269-005-0002-9
12. Di Benedetto F, Bernardini GP, Borrini D, Lottermoser W, Tippelt G, Amthauer G (2005c) 57Fe- and 119Sn-Mössbauer study on stannite (Cu2FeSnS4)-kesterite (Cu2ZnSnS4) solid solution. Phys Chem Miner 31:683-690. doi: 10.1007/s00269-004-0430-y
13. Di Benedetto F, Borgheresi M, Caneschi A, Chastanet G, Cipriani C, Matteschi D, Pratesi G, Romanelli M, Sessoli R (2006) First evidence of natural superconductivity: Covellite. Eur J Mineral 18(3):283-287. doi: 10.1127/0935-1221/2006/0018-0283
14. Drago RS (1992) Physical methods for chemists. 2nd edn, Saunders, Philadelphia
15. 4 system, http://www.scgis.ru/cp1251.h-dgggms/1-2002/informbul01.htn#term-5
16. Evstigneeva TL, Rusakov VS, And Kabalov YuK (2003) Isomorphism in the minerals of stannite-family. New Data Mineral 38:65-69
17. Fleisher M, Cabri LJ, Chao GY, Pabst A (1980) New mineral names. Am Mineral 65:1065-1069
18. 4 nanoshell tubes. J Cryst Growth 284:226-234. doi: 10.1016/j.jcrysgro.2005.07.004
19. 4. J Alloy Comp 306:6-10. doi: 10.1016/S0925-8388(00)00761-1
20. 4, a new mineral of the stannite group. Zap Vses Miner Obsh 108:564-569 in Russian
21. Kulikova IM, Evstigneeva TL, Bortnikov NS (2005) Study of chemical bonding of copper atoms in minerals of the stannite group, kuramite-stannite series. Dokl Earth Sci 401(3):403-405
22. mindat.org (2008) http://www.mindat.org/min-2291.html
23. Moh GM (1960) Experimentelle Untersuchungen am Zinnkiesen und analogen Germaniumverbindungen. N Jb Mineral Abh 94:1125-1144
24. Pattrick RAD, Mosselmans JFW, Charnock JM, England KER, Helz GR, Garner CD, Vaughan DJ (1997) The structure of amorphous copper sulfide precipitates: An X-ray absorption study. Geochim Cosmochim Acta 61(10):2023-2036
25. 4. J Phys Chem Solids 27:655-666
26. Spalek J, Lewicki A, Tarnawski Z, Furdyna JK, Galazka RR, Obuszko Z (1986) Magnetic susceptivity of semimagnetic semiconductors: The high-temperature regime and the role of super exchange. Phys Rev B 33:3407-3418
27. 3. N Jb Mineral Abh 131:26-27
28. 4 nanorods. Inorg Chem 41:2953-2959