Short-range order of Fe2+ in sphalerite by 57Fe Mössbauer spectroscopy and magnetic susceptibility

Physics and Chemistry of Minerals

Volumn 32, Issue 5-6, 2005, Pages 339-348

  Di Benedetto, F ^a   Andreozzi, G B ^b   Bernardini, G P ^c   Borgheresi, M ^a   Caneschi, A ^a   Cipriani, C ^a   Gatteschi, D ^a   Romanelli, M ^a  

^a UNIVERSITY OF FLORENCE   (Italy)

^b SAPIENZA UNIVERSITY OF ROME   (Italy)

^c NONE   (Italy)

Author keywords

57Fe M ssbauer spectroscopy; Fe bearing sphalerite; Fe Fe interactions; Magnetic susceptibility

Indexed keywords

ELECTRON ENERGY LEVELS; IONS; LOW TEMPERATURE EFFECTS; MAGNETIC SUSCEPTIBILITY; MAGNETIC VARIABLES MEASUREMENT; MOSSBAUER SPECTROSCOPY; SULFIDE MINERALS; ZINC SULFIDE;

ANTIFERROMAGNETIC INTERACTIONS; FE-BEARING SPHALERITE; POLYMORPHS;

IRON ANALYSIS;

IRON; MAGNETIC SUSCEPTIBILITY; MINERALOGY; MOSSBAUER SPECTROSCOPY; SPHALERITE;

EID: 27644597169     PISSN: 03421791     EISSN: 14322021     Source Type: Journal    
DOI: 10.1007/s00269-005-0002-9     Document Type: Article

References (45)

1. Amthauer G, Rossman GR (1984) Mixed valence of iron in minerals with cation clusters. Phys Chem Miner 11:37-51 10.1007/BF00309374
2. 2+ and Mg in the synthetic spinel s.s.-hercynite system by single-crystal X-ray diffraction. Am Miner 87:1113-1120
3. xS. J Magn Magn Mater 195:76-80 10.1016/ S0304-8853(98)00626-X
4. Balabin AI, Sack RO (2000) Thermodynamics of (Zn,Fe)S sphalerite. A CVM approach with large basis clusters. Miner Mag 64(5):923-943 10.1180/ 002646100549751
5. Barton PB, Toulmin P III (1966) Phase relations involving in the Fe-Zn-S system. Econ Geol 61(5):815-849
6. Bergstresser TK, Cohen ML (1967) Electronic structure and optical properties of hexagonal CdSe, CdS and ZnS. Phys Rev 164(3):1069-1080 10.1103/PhysRev.164.1069
7. Bernardini GP, Borgheresi M, Cipriani C, Di Benedetto F, Romanelli M (2004) Mn distribution in sphalerite: An EPR study. Phys Chem Miner 31:80-84 10.1007/s00269-003-0374-7
8. 2+ impurities in cubic ZnS. Observation of metastable electronic levels. II Dynamical Jahn-Teller effect study. Phys Rev B 23(9):4310-4432
9. Craig JR, Vaughan DJ (1994) Ore microscopy and ore petrography. Wiley, London New York, p 434
10. Di Benedetto F (2003) Indagini minero-chimiche e spettroscopiche su sfaleriti naturali e analoghi sintetici. PhD thesis, University of Florence, Italy
11. Di Benedetto F, Bernardini GP, Cipriani C, Plant D, Romanelli M, Vaughan DJ (2003) Mn distribution in natural sphalerites: A microanalytical and EPR study. Geophys Res Abstr 5:13985
12. Di Benedetto F, Bernardini GP, Costagliola P, Plant D, Vaughan DJ (2005) Compositional zoning in sphalerite crystals. Am Mineral (in press)
13. RS Drago 1977 Physical methods in inorganic chemistry Van Nostrand Reinhold Drago New York
14. Furdyna JK (1988) Diluted magnetic semiconductors. J Appl Phys 64:R29-R64 10.1063/1.341700
15. 2+ impurities, isolated and in pairs, in ZnS and CdS studied by the Mössbauer effect. J Phys Chem Solids 32:2091-2100
16. Green GR, Solomon M, Walshe JL (1981) The formation of the volcanic-hosted massive sulfide ore deposit at Rosebery, Tasmania. Econ Geol 76:304-338
17. 3+ clusters. Phys Chem Miner 29:319-330
18. Hawthorne FC (1988) Mössbauer spectroscopy. In: Ribbe PH (ed) Spectroscopic methods in mineralogy and geology. Rev Miner 18:255-340
19. KreissN J, Gehlhoff W (1984) EPR investigations of ZnS:MN and ZnSe:Mn. Phys Status Solidi A 81:701-707
20. G Kullerud 1971 Experimental techniques in dry sulphide research In: GC Ulmer (ed.) Research techniques for high pressure and high temperature Springer Berlin Heidelberg New York 289-315
21. Lenaz D, Andreozzi GB, Mitra S, Bidyananda M, Princivalle F (2004) Crystal chemical and 57 Fe Mössbauer study of chromite from the Nuggihalli schist belt (India). Miner Petrol 80:45-57 10.1007/ s00710-003-0024-2
22. Lepetit P, Bente K, Doering T, Luckhaus S (2003) Crystal chemistry of Fe-containing sphalerites. Phys Chem Miner 30:185-191 10.1007/ s00269-003-0306-6
23. 4 system. Geochim Cosmochim Acta 66(3):417-429 10.1016/ S0016-7037(01)00792-X
24. Low W, Weger M (1960) Paramagnetic resonance and optical spectra of divalent iron in cubic fields; I. theory. Phys Rev 118(5):1119-1130 10.1103/PhysRev.118.1119
25. 5E state of Fe in ZnO, ZnS, CdS, ZnSe, CdSe, ZnTe and CdTe crystals by magnetic susceptibilities. J Chem Phys 33(11):4286-4290 10.1063/1.1673934
26. 57Fe in sulphides. Geokhimiya 10:1094-1103
27. 3, using Mössbauer spectroscopy, optical spectroscopy and transmission electron microscopy. Phys Chem Miner 22:11-20
28. Nikolov S, Boyanov B, Moldovanska N, Dimitrov R (2001) Mössbauer spectroscopy study on the oxidation of sulfide zinc concentrate rich in marmatite. Thermochim Acta 380:37-41 10.1016/S0040-6031(01)00638-4
29. O'Connor CJ (1982) Magnetochemistry. Advances in theory and experimentation. In: Lippard SJ (ed) "Progress in inorganic chemistry". 29:203-277
30. Pattrick RAD, Mosselmans JFW, Charnock JM (1998) An X-ray absorption study of doped sphalerites. Eur J Miner 10:239-249
31. 4. J Solid State Chem 35:77-82
32. Scott SD (1971) Mössbauer spectra of synthetic iron-bearing sphalerite Can Miner 1:882-885
33. Scott SD (1973) Experimental calibration of the sphalerite geobarometer. Econ Geol 68:466-474
34. x Te. Phys Rev Lett 75(13):2590-2593 10059350
35. 4. Phys Rev 152(1):376-402 10.1103/PhysRev.152.376
36. Spalek J, Lewicki A, Tarnawski Z, Furdyna JK, Galazka RR, Obuszko Z (1986) Magnetic susceptibility of semimagnetic semiconductors: The high temperature regime and the role of superexchange. Phys Rev B 33(5):3407-3418 10.1103/PhysRevB.33.3407
37. Sykes MF, Glen M (1976a) Percolation processes in two dimension: Loe density series expansions. J Phys A: Math Gen 9(1):87-95 10.1088/ 0305-4470/9/1/014
38. Sykes MF, Gaunt DS, Glen M (1976b) Percolation processes in three dimension. J Phys A: Math Gen 9(10):1705-1712 10.1088/0305-4470/9/10/021
39. Trigunayat GC, Chadha GK (1971) Progress in the study of polytipism in crystals (I). Phys Status Solidi A 4:9-42
40. Twardowski A (1990) Magnetic properties of Fe-based diluted magnetic semiconductors. J Appl Phys 67(9):5108-5113 10.1063/1.344685
41. Twardowski A, Lewicki A, Arciszewska M, de Jonge WJM, Swagten HJM, Demianiuk M (1988) Magnetic susceptibility of iron-based semimagnetic semiconductors: High-temperature regime. Phys Rev B 38(15):10749-10754 10.1103/PhysRevB.38.10749
42. xS. Phys Rev B 44(5):2220-2226 10.1103/PhysRevB.44.2220
43. Twardowski A, Fries T, Shapira Y, Demianiuk M (1993) The d-d exchange interaction in the diluted magnetic semiconductor ZnFeS. J Appl Phys 73(10):6087-6089 10.1063/1.353478
44. Vaughan DJ, Burns RG (1972) Mössbauer spectroscopy and bonding in sulphide minerals containing four-coordinated Iron. Proc 24th IGC, 14:158-167
45. Waerenborgh JC, Annersten H, Ericsson T, Figueiredo MO, Cabral JMP (1990) A Mössbauer study of natural gahnite spinels showing strongly temperature-dependent quadrupole splitting distributions. Eur J Miner 2:267-271