Synthesis of monodisperse glycerol dimethacrylate-based microgel particles by precipitation polymerization

Industrial and Engineering Chemistry Research

Volumn 48, Issue 10, 2009, Pages 4844-4851

  Saraçoǧlu, Berna ^a   Uǧuzdoǧan, Erdal ^b   Gölgelioǧlu, Çiǧdem ^a   Tuncel, Ali ^a  

^a HACETTEPE UNIVERSITY   (Turkey)

^b PAMUKKALE UNIVERSITY   (Turkey)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS MEDIUM; BIOMEDICAL APPLICATIONS; CARBOXYL GROUPS; CONTINUOUS MEDIUM; CORE PART; CROSSLINKED; DIMETHACRYLATE; DISTRIBUTION CHARACTERISTICS; EFFECT OF PH; FEED CONCENTRATION; HYDRODYNAMIC SIZE; METHACRYLIC ACIDS; MICROGEL; MICROGEL PARTICLES; MICROMETER SIZES; MONODISPERSE; MONOMER CONVERSIONS; POLY HYDROXY ETHYL METHACRYLATES; POLYMERIZATION CONDITIONS; POLYMERIZATION KINETICS; PRECIPITATION POLYMERIZATIONS; PROMISING MATERIALS; SHELL LAYERS; SINGLE STAGE; SIZE RANGES; STABILIZING AGENTS; SURFACE DERIVATIZATION; SWELLING BEHAVIOR;

ACETONITRILE; ACRYLIC MONOMERS; BIOLOGICAL MATERIALS; FLUID DYNAMICS; FUNCTIONAL GROUPS; FUNCTIONAL POLYMERS; GLYCEROL; HYDRODYNAMICS; PH EFFECTS; POLYACRYLATES; POLYMERIZATION; POLYMERS; TOLUENE;

PRECIPITATION (CHEMICAL);

EID: 67249104971     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie801572w     Document Type: Article

References (25)

1. Li, K.; Stover, H. D. H. Synthesis of Monodisperse Poly(divinylbenzene) Microspheres. J. Polym. Sci., Part A: Polym. Chem. 1993, 31, 3257.
2. Hattori, M.; Sudol, E. D.; El-Aasser, M. S. Highly Crosslinked Polymer Particles by Dispersion Polymerization. J. Appl. Polym. Sci. 1993, 50, 2027.
3. Li, W. H.; Li, K.; Stover, H. D. H. Monodisperse Poly(chloromethylstyrene- co-divinylbenzene) Microspheres by Precipitation Polymerization. J. Polym. Sci., Part A: Polym. Chem. 1999, 37, 2295.
4. Li, W. H.; Li, K.; Stover, H. D. H. Mono- or Narrow Disperse Poly(methacrylate-co-divinylbenzene) Microspheres by Precipitation Polymerization. J. Polym. Sci., Part A: Polym. Chem. 1999, 37, 2899.
5. Frank, R. S.; Downey, J. S.; Yu, K.; Stover, H. D. H. Functional Microspheres and Microgels by Precipitation Polymerization of Divinylbenzene- 55 and Maleic Anhydride. Abstr. Pap.-Am. Chem. Soc. 1999, 218, U461.
6. Gawdzik, B.; Maciejewska, M. Synthesis of Isobutyl Maleate- Divinylbenzene Microspheres by Different Techniques of Heterogeneous Polymerizations. J. Appl. Polym. Sci. 2004, 91, 2008.
7. Gawdzik, B.; Maciejewska, M. Preparation and Porous Structure Characterization of 4,4′-Diphenylmethane Dimethacrylate/Divinylbenzene Polymeric Particles. J. Appl. Polym. Sci. 2005, 95, 863.
8. Downey, J. S.; McIsaac, G.; Frank, R. S.; Stover, H. D. H. Poly(divinylbenzene) Microspheres as an Intermediate Morphology between Microgel, Macrogel, and Coagulum in Cross-Linking Precipitation Polymerization. Macromolecules 2001, 34, 4534.
9. Shim, S. E.; Yang, S.; Jin, M. J.; Chang, Y. H.; Choe, S. Effect of the Polymerization Parameters on the Morphology and Spherical Particle Size of Poly(styrene-co-divinylbenzene) Prepared by Precipitation Polymerization. Colloid Polym. Sci. 2004, 283, 41.
10. Shim, S. E.; Yang, S. Y.; Choe, S. J. Mechanism of the Formation of Stable Microspheres by Precipitation Copolymerization of Styrene and Divinylbenzene. J. Polym. Sci., Part A: Polym. Chem. 2004, 42, 3967.
11. Zheng, G. D.; Stover, H. D. H. Formation and Morphology of Methacrylic Polymers and Block Copolymers Tethered on Polymer Microspheres. Macromolecules 2003, 36, 1808.
12. Wang, J. F.; Cormack, P. A. G.; Sherrington, D. C.; Khoshdel, E. Monodisperse, Molecularly Imprinted Polymer Microspheres Prepared by Precipitation Polymerization for Affinity Separation Applications. Angew. Chem., Int. Ed. 2003, 42, 5336.
13. Wei, S. T.; Molinelli, A.; Mizaikoff, B. Molecularly Imprinted Micro and Nanospheres for the Selective Recognition of 17 Beta-Estradiol. Biosens. Bioelectron. 2006, 21, 1943.
14. Ni, H. M.; Kawaguchi, H. Mechanism of Preparing Monodisperse Poly(acrylamide/methacrylic acid) Microspheres in Ethanol. I. J. Polym. Sci., Part A: Polym. Chem. 2004, 42, 2823.
15. Bai, F.; Yang, X. L.; Huang, W. Q. Synthesis of Narrow or Monodisperse Poly(Divinylbenzene) Microspheres by Distillation- Precipitation Polymerization. Macromolecules 2004, 37, 9746.
16. Bai, F.; Li, R.; Yang, X. L.; Li, S. N.; Huang, W. Q. Preparation of Narrow-Dispersion or Monodisperse Polymer Microspheres with Active Hydroxyl Group by Distillation-Precipitation Polymerization. Polym. Int. 2006, 55, 319.
17. Bai, F.; Yang, X. L.; Huang, W. Q. Preparation of Narrow or Monodisperse Poly(ethyleneglycol dimethacrylate) Microspheres by Distillation- Precipitation Polymerization. Eur. Polym. J. 2006, 42, 2088.
18. Bai, F.; Yang, X. L.; Li, R.; Huang, B.; Huang, W. Q. Monodisperse Hydrophilic Polymer Microspheres Having Carboxylic Acid Groups Prepared by Distillation Precipitation Polymerization. Polymer 2006, 47, 5775.
19. Eke, I.; Elmas, B.; Tuncel, M.; Tuncel, A. A New, Highly Stable Cationic-Thermosensitive Microgel: Uniform Isopropylacrylamide- Dimethylaminopropyl- Methacrylamide Copolymer Particles. Colloids Surf., A 2006, 279, 247.
20. Li, W. H.; Stöver, H. D. H. Porous Monodisperse Poly(divinylbenzene) Microspheres by Precipitation Polymerization. J. Polym. Sci., Part A: Polym. Chem. 1998, 36, 1543.
21. Polymer Handbook, 4th ed.; Brandrup, J., Immergut, E. H., Grulke, E. A., Eds.; Wiley: Hoboken, NJ, 2003.
22. Okay, O.; Gürün, Ç . Synthesis and Formation Mechanism of Porous 2-Hydroxyethyl Methacrylate-Ethylene Glycol Dimethacrylate Copolymer Beads. J. Appl. Polym. Sci. 1992, 46, 401.
23. Polymer Handbook, 2nd ed.; Brandrup, J., Immergut, E. H., Eds.; Wiley: New York, 1975.
24. Shen, S.; Sudol, E. D.; El-Aasser, M. S. Dispersion Polymerization of Methyl Methacrylate: Mechanism of Particle Formation. J. Polym. Sci., Part A: Polym. Chem. 1994, 32, 1087.
25. Smith, W. V.; Ewart, R. H. Kinetics of Emulsion Polymerization. J. Chem. Phys. 1948, 16, 592.