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Volumn 9, Issue 6, 2009, Pages 2552-2555

Novel coordinated-solvent induced assembly of Cd(II) coordination polymers containing 4,4′-dipyridylsulfide

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EID: 66849104067     PISSN: 15287483     EISSN: 15287505     Source Type: Journal    
DOI: 10.1021/cg900119a     Document Type: Article
Times cited : (55)

References (41)
  • 7
    • 4444275259 scopus 로고    scopus 로고
    • Kitagawa, S.; Kitaura, R.; Noro, S.-I. Ansew. Chem. Int. Ed. 2004, 43, 2334.
    • (g) Kitagawa, S.; Kitaura, R.; Noro, S.-I. Ansew. Chem. Int. Ed. 2004, 43, 2334.
  • 16
    • 33645078919 scopus 로고    scopus 로고
    • Silva, R. M.; M.; Smith, M. D.; Gardinier, J. R. Inors. Chem. 2006, 45, 2132.
    • (d) Silva, R. M.; M.; Smith, M. D.; Gardinier, J. R. Inors. Chem. 2006, 45, 2132.
  • 32
    • 66849141923 scopus 로고    scopus 로고
    • Synthesis of [Cd2(Py2S)3(NO 3)4]n 1: Cd(NO3)2 · 4H 2O (25 mg, 0.08 mmol) dissolved in an acetonitrile solution (2 mL) was carefully layered onto a 2 mL CH2Cl2 solution of Py2S (23 mg, 0.12 mmol, Colorless crystals were obtained in two days in ca. 63% yield. FT-IR (KBr, vc=c, 1581 and 1479 cm-1; vN-o, 1833 cm-1. Anal. Calcd, ) for C 30H24Cd2N10O12S 3: C, 34.73; H, 2.33; N, 13.50. Found, C, 34.86; H, 2.46; N, 13.25. Synthesis of, Cd(Py2S)2(DMF)2](ClO 4)2}n 2: Cd(ClO4) 2·6H2O (34 mg, 0.08 mmol) dissolved in a DMF solution (2 mL) was carefully layered onto a 2 mL CH2Cl2 solution of Py2S 30 mg, 0
    • 5: C, 38.36; H, 2.97; N, 8.60. Found (%): C, 38.12; H, 2.76; N, 8.79.
  • 35
    • 66849140838 scopus 로고    scopus 로고
    • Crystal data: 1·CH2Cl2, C 31H26Cd2Cl2N10O 12S3, M, 1122.50, triclinic, space group P1̄, T, 295(2) K, a, 11.2141(1, b, 12.5092(1, c, 17.2612(2) Å, α, 104.4338(4, β, 100.1570(5, γ, 109.3781(5)°, V= 2121.32(4) Å3, Z, 2, μ, 1.345 mm-1, F(000, 1112, 30 381 reflections collected, 9720 independent, Rint, 0.0396, final residuals R1, 0.0560, wR2, 0.1529 [I > 2σ(I, R1, 0.0886, wR2, 0.1878 (all data, Crystal data: 2, C26H30CdCl 2N6O10S2, M, 834.01, mono-clinic, space group P21/c, T, 273(2) K, a, 10.4730(8, b, 19.2211(14, c, 19.0207(11) Å, β, 113.114(3)°, V
    • int = 0.0575, final residuals R1 = 0.0364, wR2 = 0.0853 [I > 2σ(I)]; R1 = 0.0407, wR2 = 0.0872 (all data).


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