A synthetic, structural and reactivity study of [(η4-C4R4)Co(η5- C5H4X)] complexes, R = Me or Et; X = CHO, CH{double bond, long}CHFc, CH{double bond, long}CH(η5-C5H4)Co(η4 -C4Ph4), CH{double bond, long}C(CN)2: Unexpected formation of...

Journal of Organometallic Chemistry

Volumn 694, Issue 16, 2009, Pages 2536-2547

  O'Donohue, Paul ^a   Brusey, Sarah A ^a   Seward, Corey M ^a   Ortin, Yannick ^a   Molloy, Bevin C ^a   Müller Bunz, Helge ^a   Manning, Anthony R ^a   McGlinchey, Michael J ^a  

^a UNIVERSITY COLLEGE DUBLIN   (Ireland)

Author keywords

Pyrone complex; Horner Wittig; Knoevenagel; Tetraalkylcyclobutadiene cobalt

Indexed keywords

CYCLOBUTADIENE COMPLEXES; CYCLOPENTADIENYL; DIRECT SYNTHESIS; DOUBLE BONDS; ETHYL FORMATE; HORNER-WITTIG; KNOEVENAGEL; KNOEVENAGEL REACTION; SECONDARY ALCOHOLS; TETRAALKYLCYCLOBUTADIENE-COBALT; TETRAMETHYL; WITTIG REACTION; X RAY CRYSTAL STRUCTURES;

ACETONITRILE; ALDEHYDES; BUTADIENE; CHEMICAL REACTIONS; COBALT; PHOTOLYSIS;

COBALT COMPOUNDS;

EID: 66749085094     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2009.04.004     Document Type: Article

References (64)

1. Ortin Y., Ahrenstorf K., O'Donohue P., Foede D., Müller-Bunz H., McArdle P., Manning A.R., and McGlinchey M.J. J. Organomet. Chem. 689 (2004) 1657
2. Ortin Y., Grealis J., Scully C., Müller-Bunz H., Manning A.R., and McGlinchey M.J. J. Organomet. Chem. 689 (2004) 4683
3. Behrendt C., Dabek S., Heck J., Courtney D., Manning A.R., McGlinchey M.J., Müller-Bunz H., and Ortin Y. J. Organomet. Chem. 691 (2006) 1183
4. a Prediction for Organic Acids and Bases (1981), Chapman and Hall, London & New York p. 109
5. Criegee R., Schröder G., and Liebigs J. Ann. Chem. 623 (1959) 1
6. Markby R., Sternberg H.W., and Wender I. Chem. Ind. (1959) 1381
7. Piper T.S., Cotton F.A., and Wilkinson G. J. Inorg. Nucl. Chem. (1955) 165
8. Bruce R., and Maitlis P.M. Can. J. Chem. 45 (1967) 2017
9. Herberich G.E., and Naithani A.K. J. Organomet. Chem. 241 (1983) 1
10. Mutseneck E.V., Loginov D.A., Perekalin D.S., Starikova Z.A., Golovanov D.G., Petrovskii P.V., Zanello P., Corsini M., Laschi F., and Kudinov A.R. Organometallics 23 (2004) 5944
11. Kudinov A.R., I Meshcheryakov V., Petrovskii P.V., and Rybinskaya M.I. Russ. Chem. Bull. 48 (1996) 176
12. Kudinov A.R., Fil'chikov A.A., I Rybinskaya M., and Petrovskii P.V. Russ. Chem. Bull. Int. Ed. 48 (1999) 1352
13. Kudinov A.R., Mutseneck E.V., and Loginov D.A. Coord. Chem. Rev. 248 (2004) 571
14. Gath S., Gleiter R., Rominger F., and Bleiholder C. Organometallics 26 (2007) 644
15. Uhm J.-K., An H.-W., Chung C., and Kim H.-R. Bull. Korean Chem. Soc. 15 (1994) 1124
16. Schmidt G., and Schuetz M. J. Organomet. Chem. 492 (1995) 185
17. Boston J.L., Sharp D.W.A., and Wilkinson G. J. Chem. Soc. (1962) 3488
18. Rausch M.D., and Ginetti R.A. J. Am. Chem. Soc. 89 (1967) 5502
19. Nakamura A., and Hagihara N. Bull. Chem. Soc. Jpn. 34 (1961) 452
20. Stevens A.M., and Richards C.J. Organometallics 18 (1999) 1346
21. Butovskii M.V., Englert U., Fil'chikov A.A., Herberich G.E., Koelle U., and Kudinov A.R. Eur. J. Inorg. Chem. (2002) 2656
22. Koster J.B., Timmermans G.J., and van Bekkum H. Synthesis (1971) 139
23. Krüger C., Roberts P.J., Tsay Y.-H., and Koster J.B. J. Organomet. Chem. 78 (1974) 69
24. Härter P., Pauson P.L., and Ullah S.S. J. Organomet. Chem. 247 (1983) C27
25. Coombs D.L., Aldridge S., Rossin A., Jones C., and Willock D.J. Organometallics 23 (2004) 2911
26. Zeller M., Lazich E., and Hunter A.D. Acta Crystallogr., Sect. E 59 (2003) m914
27. Greene P.T., and Bryan R.F. J. Chem. Soc. A (1970) 2261
28. Greene P.T., and Bryan R.F. J. Chem. Soc. A (1970) 1696
29. Maitlis P.M., and Efraty A. J. Organomet. Chem. 4 (1965) 175
30. Donaldson W.A., Hughes R.P., Davis R.E., and Gadol S.M. Organometallics 1 (1982) 812
31. Tolxdorff C., Hu D., Hoeferth B., Schaeufele H., Pritzkow H., and Zenneck U. Z. Naturforsch. B: Chem. Sci. 46 (1991) 729
32. Herberich G.E., Englert U., and Marken F. J. Chem. Soc., Dalton Trans. (1993) 1979
33. Kudinov A.R., Loginov D.A., Ashikhmin S.N., Fil'chikov A.A., Shul'pina L., and Petrovskii P.V. Russ. Chem. Bull. Int. Ed. 49 (2000) 1637
34. Cook M.R., Härter P., Pauson P.L., and Sraga J. J. Chem. Soc., Dalton Trans. (1987) 2757
35. Kennedy A.R., and Pauson P.L. Acta Crystallogr., Sect. E 61 (2005) m302
36. Alley S.R., and Henderson W. J. Organomet. Chem. 637-639 (2001) 216
37. Oms O., Maurel F., Carré F., Le Bideau J., Vioux A., and Leclercq D. J. Organomet. Chem. 689 (2004) 2654
38. Wittig G., and Geissler G. Liebigs Ann. Chem. 580 (1953) 44
39. Wittig G., and Schöllkopf U. Chem. Ber. 87 (1954) 1318
40. Horner L., Klink W., and Hoffmann H. Chem. Ber. 96 (1963) 3133
41. Wadsworth W.S., and Emmons W.D. J. Am. Chem. Soc. 83 (1961) 1733
42. Pauson P.L., and Watts W.E. J. Chem. Soc. (1963) 2990
43. Knoevenagel E. Chem. Ber. 31 (1898) 2596
44. Corey E.J., and Streith J. J. Am. Chem. Soc. 86 (1964) 950
45. Mitsudo T., Ogino Y., Komiya Y., Watanabe H., and Watanabe Y. Organometallics 2 (1983) 1202
46. Mitsudo T., Watanabe H., Sasaki T., Takegami Y., Watanabe Y., Kafuku K., and Nakatsu K. Organometallics 8 (1989) 368
47. Dickson R.S., Evans G.S., and Fallon G.D. Aust. J. Chem. 38 (1985) 273
48. Fairlamb I.J.S., Syvänne S.M., and Whitwood A.C. Synlett 11 (2003) 1693
49. Holland J.M., and Jones D.W. Chem. Comm. (1967) 946
50. Park J., and Kim J. Organometallics 14 (1995) 4431
51. Rosenblum M., North B., Wells D., and Giering W.P. J. Am. Chem. Soc. 94 (1972) 1239
52. Rosenblum M., and Gatsonis C. J. Am. Chem. Soc. 89 (1967) 5074
53. Gleiter R., and Kratz D. Angew. Chem., Int. Ed. Engl. 29 (1990) 276
54. Schaefer C., Werz D.B., Staeb T.H., Gleiter R., and Rominger F. Organometallics 24 (2005) 2106
55. Gleiter R., and Werz D.B. Organometallics 24 (2005) 4316
56. Haltiwanger R.C., Jones T., and DePuy C.H. Cryst. Struct. Commun. 11 (1982) 273
57. O'Connor J.M., Ji H.L., and Rheingold A.L. J. Am. Chem. Soc. 115 (1993) 9846
58. Alvarez-Toledano C., Hernándes-Ortega S., Bernès S., Gutiérrez-Pérez R., and García-Mellado O. J. Organomet. Chem. 549 (1997) 49
59. Bond A., and Green M. J. Chem. Soc., Dalton Trans. (1972) 763
60. Dalton J., Paul I., and Stone F.G.A. J. Chem. Soc. A (1969) 2744
61. Guillaneux D., and Kagan H.B. J. Org. Chem. 60 (1995) 2502
62. G.M. Sheldrick, sadabs, Bruker AXS Inc., Madison, WI 53711, 2000.
63. G.M. Sheldrick, shelxs-97, University of Göttingen, 1997.
64. G.M. Sheldrick, shelxl-97-2, University of Göttingen, 1997.