An NMR study of the rotational barriers in cobalt-stabilized carbocations: X-ray crystal structures of (η4-C4Ph4)Co-(η5 -C5H4R), where R is CH3C=O, CH=O, CH(tBu)OH

Journal of Organometallic Chemistry

Volumn 689, Issue 9, 2004, Pages 1657-1664

  Ortin, Yannick ^a   Ahrenstorf, Kirsten ^a   O'Donohue, Paul ^a   Foede, Daniel ^a   Müller Bunz, Helge ^a   McArdle, Patrick ^b   Manning, Anthony R ^a   McGlinchey, Michael J ^a  

^a UNIVERSITY COLLEGE DUBLIN   (Ireland)

^b NATIONAL UNIVERSITY OF IRELAND   (Ireland)

Author keywords

Cyclobutadiene cobalt complexes; Metal stabilized carbocations; NMR; X ray crystallography

Indexed keywords

ALCOHOL; ALDEHYDE; CARBON; CATION; COBALT; CYCLOBUTANE DERIVATIVE; KETONE; LIGAND; LITHIUM; PHENETHYL ALCOHOL; TERT BUTYL ALCOHOL;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; CONTROLLED STUDY; CRYSTAL STRUCTURE; DIASTEREOISOMER; NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; RATING SCALE; SOLID STATE; TEMPERATURE SENSITIVITY; X RAY CRYSTALLOGRAPHY;

EID: 1842666536     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2004.02.021     Document Type: Article

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