Synthesis and curing kinetics of phosphorus-containing unsaturated polyester with reactive flame retardant

Shiyou Huagong/Petrochemical Technology

Volumn 38, Issue 5, 2009, Pages 515-520

  Zhang, Chen ^a,c   Liu, Shumei ^a   Huang, Junyi ^a   Zhao, Jianqing ^a   Zhang, Jieyuan ^b   Xu, Guanjun ^b  

^a SOUTH CHINA UNIVERSITY OF TECHNOLOGY   (China)

^b Guangzhou Better New Materials Co Ltd   (China)

^c Normal University   (China)

Author keywords

Bis phenoxy(3 hydrogen) phenyl phosphine oxide; Curing kinetics; Flame retardant; Reactive phosphorus containing unsaturated polyester resin

Indexed keywords

EID: 66449134526     PISSN: 10008144     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (15)

1. Horold S R. Phosphorus flame retar dants in thermoset resins. Polym Degrad Stab, 1999, 64(3): 427-431
2. Nazare S, Kandola B K, Horrocks A R. Flame-Retardant Unsaturated Polyester Resin Incorporating Nanoclays. Polym Adv Technol, 2006, 17(4): 294-303
3. Shih Yeng Fong, Wang Yih Tyng, Jeng Ru Jong, et al. Expandable graphite systems for phosphorus-containing unsaturated polyesters I. enhanced thermal properties and flame retardancy. Polym Degrad Stab, 2004, 86(2): 339-348
4. Kuan Jenn Fong, Lin King Fu. Synthesis of Hexa-allylamino-cyclotriphosphazene as a reactive fire retardant for unsaturated polyesters. J Appl Polym Sci, 2004, 91(2): 697-702
5. Ma Zhiling, Zhao Wenge, Liu Yangfang, et al. Synthesis and properties of intumescent, phosphorus-containing, flame-retardant polyesters. J Appl Polym Sci, 1997, 63(12): 1511-1515
6. Ren Hua, Sun Jianzhong, Wu Binjie, et al. Synthesis and properties of a phosphorus-containing flame retardant epoxy resin based on bis-phenoxy(3-hydroxy) phenyl phosphine oxide. Polym Degrad Stab, 2007, 92(6): 956-961
7. Liu Yingling, Chiu Yiechan, Chen Tsung Yu. Phosphorus-containing polyaryloxydiphenylsilanes with high flame retardance arising from a phosphorus-silicon synergistic effect. Polym Int, 2003, 52(8):1256-1261
8. Vilas J L, Laza J M, Garay M T, et al. Unsaturated polyester resins cure: kinetic, rheologic, and mechanical-dynamical analysis. I. cure kinetics by DSC and TSR. J Appl Polym Sci, 2001, 79(3): 447-457
9. Martín J L, Cadenato A, Salla J M. Comparative studies on the non-tsothermal DSC curing kinetics of an unsaturated polyester resin using free radicals and empirical models. Thermochim Acta, 1997, 306(1-2): 115-126
10. Kamal M R, Sourour S. Kinetics and thermal characterization of thermoset cure. Polym Eng Sci, 1973, 13(1): 59-64
11. Worzakowska M. Kinetics of the curing reaction of unsaturated polyester resins catalyzed with new initiators and a promoter. J Appl Polym Sci, 2006, 102(2): 1870-1876