Hydrogen for X-group exchange in CH 3X (X ) Cl, Br, I, OMe, and NMe 2) by monomeric [1,2,4-(Me 3C) 3C 5H 2] 2CeH: Experimental and computational support for a carbenoid mechanism

Organometallics

Volumn 28, Issue 11, 2009, Pages 3173-3185

  Werkema, Evan L ^a   Andersen, Richard A ^a   Yahia, Ahmed ^b,c,e   Maron, Laurent ^b,c   Eisenstein, Odile ^d  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b INSA   (France)

^c CNRS   (France)

^d UNIVERSITÉ DE MONTPELLIER   (France)

^e DIF   (France)

Author keywords

[No Author keywords available]

Indexed keywords

BARRIER PROCESS; BOND METATHESIS; C-H ACTIVATION; CARBENOID; CLASS A; CLASS B; DENSITY-FUNCTIONAL CALCULATIONS; DEUTERIUM LABELING; DFT CALCULATION; EXPERIMENTAL STUDIES; H NMR SPECTRA; LOW ACTIVATION; METHOXYMETHYL; TRANSITION STATE; TWO-STEP REACTIONS;

CERIUM; CERIUM COMPOUNDS; DEUTERIUM; HYDROGEN; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC COMPOUNDS; PROBABILITY DENSITY FUNCTION; SULFUR COMPOUNDS;

DENSITY FUNCTIONAL THEORY;

EID: 66349117667     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9001846     Document Type: Article

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