Investigation of cyclization reactions of dicyclohexyl-6-iodo- and -6-tosylhexenylborane. A facile radical cyclization diverted to a rearrangement-cyclization with base

Journal of Organic Chemistry

Volumn 74, Issue 11, 2009, Pages 4143-4148

  Hinkens, Diane M ^a   Midland, M Mark ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL EQUATIONS; CHIRAL AMINO ALCOHOLS; CYCLIZATION PRODUCTS; CYCLIZATION REACTIONS; ENVIRONMENTALLY-FRIENDLY; HYDROGEN DONOR; METHYLLITHIUM; RADICAL CYCLIZATION; RADICAL INITIATORS; ROOM TEMPERATURE; TETRABUTYLAMMONIUM; TETRABUTYLAMMONIUM HYDROXIDES; TIN HYDRIDES; TRI-N-BUTYLTIN;

ALCOHOLS; AMINES; ENANTIOSELECTIVITY; HYDROGEN; INITIATORS (CHEMICAL); TIN;

CYCLIZATION;

AMINOALCOHOL; BASE; BORANE DERIVATIVE; BUTYLTIN DERIVATIVE; CYCLOHEXANE DERIVATIVE; CYCLOPENTANE DERIVATIVE; IODINE DERIVATIVE; LITHIUM DERIVATIVE; METHANOL; PHOSPHITE; RADICAL; TETRABUTYLAMMONIUM; TIN DERIVATIVE; TOLUENESULFONIC ACID DERIVATIVE;

ARTICLE; CHIRALITY; CYCLIZATION; ENANTIOSELECTIVITY; OXIDATION; QUANTUM YIELD; REACTION ANALYSIS; ROOM TEMPERATURE;

EID: 66249125674     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo900243q     Document Type: Article

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