OH-initiated degradation of unsaturated esters in the atmosphere: Kinetics in the temperature range of 287-313 K

Journal of Physical Chemistry A

Volumn 113, Issue 20, 2009, Pages 5958-5965

  Blanco, María B ^a   Bejan, Iustinian ^a,c   Barnes, Ian ^b   Wiesen, Peter ^b   Teruel, Mariano A ^a  

^a DEPARTAMENTO DE FISICOQUÍMICA   (Argentina)

^b UNIVERSITY OF WUPPERTAL   (Germany)

^c UNIVERSITY COLLEGE CORK   (Ireland)

Author keywords

[No Author keywords available]

Indexed keywords

ADDUCT FORMATION; ARRHENIUS EXPRESSIONS; BUTYL ACRYLATES; BUTYL METHACRYLATES; CONCENTRATION-TIME; DEGRADATION PATHWAYS; GAS-PHASE REACTIONS; HYDROXYL RADICALS; METHYL METHACRYLATES; NEGATIVE TEMPERATURES; OH RADICAL; PHOTOREACTOR; PREEXPONENTIAL FACTOR; QUARTZ GLASS; RADICAL ACTIVITY; RATE COEFFICIENTS; RESIDENCE TIME; ROOM TEMPERATURE; STRUCTURE ACTIVITY RELATIONSHIPS; SYNTHETIC AIR; TEMPERATURE RANGE; TOTAL PRESSURE; UNSATURATED ESTERS; VINYL ACETATES;

ABSORPTION SPECTROSCOPY; DEGRADATION; ESTERIFICATION; ESTERS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; FREE RADICALS; GAS ABSORPTION; HYDROGEN; HYDROGEN PEROXIDE; LASERS; OXIDE MINERALS; PHASE INTERFACES; PHOTODEGRADATION; PHOTOLYSIS; QUARTZ; UNSATURATED COMPOUNDS;

ATMOSPHERIC TEMPERATURE;

ACETIC ACID DERIVATIVE; ESTER; HYDROXYL RADICAL;

ARTICLE; ATMOSPHERE; CHEMISTRY; KINETICS; OXIDATION REDUCTION REACTION; TEMPERATURE; VOLATILIZATION;

ACETATES; ATMOSPHERE; ESTERS; HYDROXYL RADICAL; KINETICS; OXIDATION-REDUCTION; TEMPERATURE; VOLATILIZATION;

EID: 66149183266     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp901755x     Document Type: Article

References (40)

1. Graedel, T. E.; Hawkins, D. T.; Claxton, L. D. Atmospheric Compounds: Sources, Occurrence, and Bioassay; Academic Press: Orlando, FL, 1986.
2. Koppmann, R., Ed. Volatile Organic Compounds in the Atmosphere; Wiley-Blackwell: New York, 2007.
3. Calvert, J. G.; Derwent, R. G.; Orlando, J. J.; Tyndall, G. S.; Wallington, T. J.; Mechanisms of Atmospheric Oxidation of the Alkanes; Oxford University Press: New York, 2008.
4. Calvert, J. G.; Atkinson, R.; Kerr J. A.; Madronich, S.; Moortgat G. K.; Wallington T. J.; Yarwood G. The Mechanisms of Atmospheric Oxidation ofthe Alkenes; Oxford University Press: New York, 2000.
5. Calvert, J. G.; Atkinson, R.; Becker, K. H.; Kamens, R. M.; Seinfeld, J. H.; Wallington T. J.; Yarwood G. The Mechanisms of Atmospheric Oxidation ofthe Aromatic Hydrocarbons; Oxford University Press: New York, 2002.
6. Organisation for Economic Co-operation and Development, OECD integrated HPV database: http://cs3-hq.oecd.org/scripts/hpv/index.asp.
7. Toxic Chemical Release Inventory. U.S. Environmental Protection Agency, Office of Toxic Substances: Washington, DC, 2006. (http://toxnet.nlm.nih.gov/cgi-bin/sis/htmlgen?TRI.htm).
8. Gordon, S. J.; Meeks, S. A. A Study of Gaseous Pollutants in the Houston, Texas Area. American Institute of Chemical Engineers Symposium Series 1977, 73, 84-94.
9. Pellizzari, E. D. Environ. Sci. Technol. 1982, 16, 781-785.
10. Hodgson, A. T.; Wooley, J. D.; Daisey, J. M. J. Air Waste Manage. Assoc. 1993, 43, 316-324.
11. Mellouki, A.; Le Bras, G.; Sidebottom, H. Chem. Rev. 2003, 103 (12), 5077-5096.
12. Teruel, M. A.; Lane, S. I.; Mellouki, A.; Solignac, G.; Le Bras, G. Atmos. Environ. 2006, 40 (20), 3764-3772.
13. Blanco, M. B.; Taccone, R. A.; Lane, S. I.; Teruel, M. A. Chem. Phys. Lett. 2006, 429 (4-6), 389-394.
14. Blanco, M. B.; Teruel, M. A. J. Phys. Org. Chem. 2008, 21, 397-401.
15. Saunders, S. M.; Baulch, D. L.; Cooke, K. M.; Pilling, M. J.; Smurthwaite, P. I. Int. J. Chem. Kinet. 1994, 26, 113-130.
16. Blanco, M. B.; Taccone, R. A.; Lane, S. I.; Teruel, M. A. J. Phys. Chem. A. 2006, 110, 11091-11097.
17. Teruel, M. A.; Blanco, M. B.; Luque, G. R. Atmos. Environ. 2007, 41, 5769-5777.
18. Barnes, I.; Becker, K. H.; Mihalopoulos, N. J. Atmos. Chem. 1994, 18, 267-289.
19. Atkinson, R. Chem. Rev. 1986, 86, 69-201.
20. Le Calve, S.; Mellouki, A.; Le Bras, G.; Treacy, J.; Wenger, J.; Sidebottom, H. J Atmos. Chem. 2000, 37, 161-172.
21. Jimenez, E.; Lanza, B.; Martínez, E.; Albaladejo, J. Atmos. Chem. Phys. 2007, 7, 1565-1574.
22. Atkinson, R.; Arey, J. Chem. Rev. 2003, 103, 4605-4638.
23. Smith, M. B.; March, J. Advances in Organic Chemistry, 5th ed.; John Wiley & Sons: New York, 2001.
24. Atkinson, R. J. Phys. Chem. Ref. Data 1997, 26, 215-290.
25. Atkinson, R. Atmos. Environ. 2000, 34, 2063-2101.
26. Meylan, W. M.; Howard, P. H. Chemosphere 1993, 26, 2293-2299, http://www.epa.gov/opptintr/exposure/pubs/episuite.htm.
27. Kwok, E. C.; Atkinson, R. Atmos. Environ. 1995, 29, 1685-1695.
28. Butt, C. M.; Young, C. J.; Mabury, S. A.; Hurley, M. D.; Wallington, T. J. J. Phys. Chem. A, 2009, in press.
29. Albaladejo, J.; Ballesteros, B.; Jimenez, E.; Martin, P.; Martinez, E. Atmos. Environ. 2002, 36, 3231-3239.
30. Blanco, M. B.; Bejan, I.; Barnes, I.; Wiesen, P.; Teruel, M. A. Proceedings of the NATO Advanced Research Workshop Simulation and Assessment of Chemical Processes in a Multiphase Environment, Alushta, Ukraine, Barnes, I., Kharytonvo, M., Eds.; Springer, Dordrecht: The Netherlands, 2008, 485-494.
31. Blanco, M. B.; Bejan, I.; Barnes, I.; Wiesen, P.; Teruel, M. A. Geophys. Res. Abs. 2008, 10.
32. Blanco, M. B.; Bejan, I.; Barnes, I.; Wiesen, P.; Teruel, M. A. Environ. Sci. Pollut. Res. 2008, in press (Online First).
33. Canosa-Mas, C. E.; Carr, S.; King, M. D.; Shallcross, D. E.; Thompson, K. C.; Wayne, R. P. Phys. Chem. Chem. Phys. 1999, 1, 4195-4202.
34. Grosjean, D.; Grosjean, E.; Williams, E. L., II Int. J. Chem. Kinet. 1993, 25, 783-794.
35. Grosjean, E.; Grosjean, D. Int. J. Chem. Kinet. 1998, 30, 21-29.
36. Logan, J. A. J. Geophys. Res. 1985, 90, 463-482.
37. Shu, Y.; Atkinson, R. J. Geophys. Res. 1995, 100, 7275-7282.
38. Hein, R.; Crutzen, P. J.; Heimann, M. Global Biogeochemical Cycles 1997, 11, 43-76.
39. Wingenter, O. W.; Kubo, M. K.; Blake, N. J.; Smith, T. W.; Blake, D. R.; Rowland, F. S. Geophys. Res. 1996, 101, 4331-4340.
40. Spicer, C. W.; Chapman, E. G.; Finlayson-Pitts, B. J.; Plastridge, R. A.; Hubbe, J. M.; Fast, J. D.; Berkowitz, C. M. Nature (London) 1998, 394, 353-356.