Atmospheric fate of acrylic acid and acrylonitrile: Rate constants with Cl atoms and OH radicals in the gas phase

Atmospheric Environment

Volumn 41, Issue 27, 2007, Pages 5769-5777

  Teruel, Mariano A ^a   Blanco, María B ^a   Luque, Gabriela R ^a  

^a DEPARTAMENTO DE FISICOQUÍMICA   (Argentina)

Author keywords

Acrylic acid; Acrylonitrile; Addition reactions; Rate coefficients; Tropospheric chemistry

Indexed keywords

ATMOSPHERIC PRESSURE; CHEMICAL BONDS; CHLORINE; GAS CHROMATOGRAPHY; RATE CONSTANTS; TROPOSPHERE;

ACRYLIC ACID; ACRYLONITRILE; FLAME IONIZATION DETECTOR (GC-FID);

ORGANIC ACIDS;

ACRYLIC ACID; ACRYLONITRILE; CHLORINE; HYDROXYL RADICAL;

ATMOSPHERIC CHEMISTRY; ATMOSPHERIC PRESSURE; CHLORINE; ENVIRONMENTAL FATE; ESTIMATION METHOD; GAS CHROMATOGRAPHY; GAS PHASE REACTION; HYDROXYL RADICAL; IONIZATION; ORGANIC COMPOUND; REACTION KINETICS; TROPOSPHERE;

ARTICLE; ATMOSPHERIC PRESSURE; CHEMICAL REACTION; GAS CHROMATOGRAPHY; MOLECULAR INTERACTION; PRIORITY JOURNAL; TROPOSPHERE;

EID: 34547106835     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.atmosenv.2007.02.028     Document Type: Article

References (31)

1. Anderson R.A., Watson A.A., and Harland W.A. Fire deaths in the Glasgow area: II the role of carbon monoxide. Medicine Science Law 21 4 (1981) 288-294
2. Albaladejo J., Ballesteros B., Jiménez E., Diaz de Mera Y., and Martinez E. Gas-phase OH radical initiated oxidation of the 3-halopropenes studied by PLP-LIF in the temperature range 228-388 K. Atmospheric Environment 37 (2003) 2919-2926
3. Aranda A., Martínez E., Díaz de Mera Y., Rodriguez A., Rodriguez D., and Cuartero J. Low-pressure study of the reactions of Cl atoms with acrylic acid and allyl alcohol. Atmospheric Environment 37 (2003) 4361-4369
4. Aranda A., Diaz de Mera Y., Rodriguez D., Rodriguez A., Cabanas B., and Martinez E. Gas-phase reaction of chlorine atoms with acrylonitrile. Temperature and pressure dependence Chemical Physical Letters 377 (2003) 571-576
5. ARB, 2002. California Air Toxics Program. California Air Resources Board, A department of the California Environmental Protection. 〈www.arb.ca.gov/toxics/tac/factshts/acrylica.pdf〉.
6. Atkinson R., and Arey J. Atmospheric degradation of volatile organic compounds. Chemical Reviews. 103 (2003) 4605-4638
7. 3 radicals with a series of alkynes, haloalkenes, and alpha, beta unsaturated-aldehydes. International Journal of Chemical Kinetics 19 (1987) 299-307
8. 2: a temperature dependence study. Journal of Physical Chemistry A 110 38 (2006) 11091-11097
9. Blanco M.B., Taccone R.A., Lane S.I., and Teruel M.A. On the OH-initiated degradation of methacrylates in the troposphere: gas-phase kinetics and formation of pyruvates. Chemical Physics Letters 429 4-6 (2006) 389-394
10. Ezell M.J., Wang W., Ezell A.A., Soskin G., and Finlayson-Pitts B.J. Kinetics of reactions of chlorine atoms with a series of alkenes at 1 atm and 298 K: structure and reactivity. Physical Chemistry Chemical Physics 4 (2002) 5813-5820
11. Finlayson-Pitts B.J., Keoshian C.J., Buehler B., and Ezell A.A. Kinetic of reaction of chlorine atoms with some biogenic organics. International Journal of Chemical Kinetics 31 (1999) 491-499
12. Graedel T.E. Chemical Compounds in the Atmosphere (1978), Academic Press, New York
13. Grosjean D. Atmospheric chemistry of toxic contaminants. 3. Unsaturated aliphatics: acrolein, acrylonitrile, maleic anhydride. Journal of the Air and Waste Management Association 40 12 (1990) 1664-1669
14. Grosjean D., Grosjean E., and Williams II E.L. Rate constants for the gas-phase reactions of ozone with unsaturated alcohols, esters and carbonyls. International Journal of Chemical Kinetics 25 (1993) 783-794
15. 2{double bond, long}CH-CN in the Temperature Range 298-424 K. Chemical Physics Letters 80 (1981) 479-483
16. Hein R., Crutzen P.J., and Heimann M. An inverse modeling approach to investigate the global atmospheric methane cycle. Global Biogeochemical Cycles 11 (1997) 43-76
17. Howard P.H. Handbook of Environmental Fate and Exposure for Organic Chemicals vols. 1-4 (1990), Lewis Publishers, Chelsea, Michigan
18. 3 reactions with allyl and isopropenyl acetate. Journal of Atmospheric Chemistry 37 (2000) 161
19. Logan J.A. Tropospheric ozone-seasonal behaviour, trends, and anthropogenic influence. Journal of Geophysical Research 90 (1985) 463-482
20. March J. Advanced Organic Chemistry Reactions, Mechanisms and Structure. Fifth ed. (2001), Wiley
21. Mellouki A., Téton S., and Le Bras G. Kinetics of OH radical reactions with a series of ethers. International Journal of Chemical Kinetics 27 (1995) 791-805
22. Mellouki A., Le Bras G., and Sidebottom H. Kinetics and mechanisms of the oxidation of oxygenated organic compounds in the gas phase. Chemical Review 103 (2003) 5077-5096
23. Munshi H.B., Rao K.V.S.R., and Iyer R.M. Rate constants of the reactions of ozone with nitriles, acrylates and terpenes in gas phase. Atmospheric Environment 23 (1989) 1945-1948
24. Neeb P., Kolloff A., Koch S., and Moortgat G.K. Rate constants for the reactions of methylvinyl ketone, methacrolein, methacrylic acid, and acrylic acid with ozone. International Journal of Chemical Kinetics 30 (1998) 769-776
25. NIST-Chemical Kinetics Database on the Web-Standard Reference Database 17, Version 7.0 (Web Version), Release 1.2, 2006.
26. Spicer C.W., Chapman E.G., Finlayson-Pitts B.J., Plastidge R.A., Hubbe J.M., Fast J.D., and Berkowitz C.M. Observations of molecular chlorine in coastal air. Nature 394 (1998) 353-356
27. 2 reactions at 298 K. International Journal of Chemical Kinetics 31 (1999) 867-872
28. 2 at 298 K. Comparisson to reactions with some other substitued ethenes. International Journal of Chemical Kinetics 33 (2001) 415-421
29. Teruel M.A., Lane S.I., Mellouki A., Solignac G., and Le Bras G. OH reaction rate constants and UV absorption cross-sections of unsaturated esters. Atmospheric Environment 40 20 (2006) 3764-3772
30. Wallington T.J., Skewes L.M., Siegl W.O., Wu C.-H., and Japar S.M. International Journal of Chemical Kinetics 20 1111 (1988) 867-875
31. Wingenter O.W., Kubo M.K., Blake N.J., Smith T.W., Blake D.R., and Rowland F.S. Hydrocarbon and halocarbon measurements as photochemical and dynamical indicators of atmospheric hydroxyl, atomic chlorine and vertical mixing obtained during Lagrangian flights. Journal of Geophysical Research 101 (1996) 4331-4340