A new synthesis, including asymmetric synthesis, of alkylidenecyclopropanes by 1,2-CC insertion of cyclobutylmagnesium carbenoides as the key reaction

Tetrahedron Letters

Volumn 50, Issue 29, 2009, Pages 4212-4216

  Nakaya, Nobuhito ^a   Sugiyama, Shimpei ^a   Satoh, Tsuyoshi ^a  

^a TOKYO UNIVERSITY OF SCIENCE   (Japan)

Author keywords

1,2 CC insertion; Alkylidenecyclopropane; Cyclobutylmagnesium carbenoid; Magnesium carbenoid; Sulfoxide magnesium exchange

Indexed keywords

1 CHLOROCYCLOBUTYL PARA TOLYL SULFOXIDE; 1 CHLOROVINYL PARA TOLYL SULFOXIDE DERIVATIVE; ALKYLIDENECYCLOPROPANE DERIVATIVE; CARBENOID; CARBON; CARBOXYLIC ACID DERIVATIVE; CARBOXYLIC ACID TERTBUTYL ESTER; CHLOROMETHYL PARA TOLYL SULFOXIDE; CYCLOBUTYLMAGNESIUM CARBENOID DERIVATIVE; CYCLOPENTYLMAGNESIUM CHLORIDE; CYCLOPROPANE DERIVATIVE; KETONE; LITHIUM ENOLATE; MAGNESIUM; REAGENT; TETRAHYDROFURAN; UNCLASSIFIED DRUG;

ARTICLE; ASYMMETRIC SYNTHESIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; NUCLEAR OVERHAUSER EFFECT; STEREOCHEMISTRY;

EID: 66149172041     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2009.04.038     Document Type: Article

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