Synthesis and characterization of carboxy-functionalized diiron model complexes of [FeFe]-hydrogenases: Decarboxylation of Ph2PCH2COOH promoted by a diiron azadithiolate complex

Journal of Organometallic Chemistry

Volumn 694, Issue 15, 2009, Pages 2309-2314

  Zhao, Zhenbo ^a   Wang, Mei ^a   Dong, Weibing ^a   Li, Ping ^a   Yu, Ze ^a   Sun, Licheng ^a,b  

^a DALIAN UNIVERSITY OF TECHNOLOGY   (China)

^b ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

Author keywords

Bioinorganic chemistry; Carboxy functionalized phosphine; Decarboxylation; Diiron complex; Iron hydrogenase

Indexed keywords

[FEFE]HYDROGENASE; [FEFE]HYDROGENASES; ACTIVE SITE; APICAL POSITIONS; BIOINORGANIC CHEMISTRY; BIOMIMETIC MODEL; CARBOXY-FUNCTIONALIZED PHOSPHINE; DECARBOXYLATION; DIIRON COMPLEX; EXPERIMENTAL EVIDENCE; FUNCTIONALIZED; HYDROGEN ATOMS; MODEL COMPLEXES; PHOSPHINE LIGANDS; PLAUSIBLE MECHANISMS; SYNTHESIS AND CHARACTERIZATION; X-RAY CRYSTALLOGRAPHIC ANALYSIS;

ATOMS; BIOCHEMISTRY; BIOMIMETICS; CARBOXYLATION; COMPLEXATION; HYDROGEN; LIGANDS; PH; PHOSPHORUS COMPOUNDS;

IRON COMPOUNDS;

EID: 66149156253     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2009.03.039     Document Type: Article

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