Highly enantioselective Cu-catalyzed conjugate addition-elimination of activated ally lie acetates with glycine derivatives

Organic Letters

Volumn 11, Issue 10, 2009, Pages 2073-2075

  Chen, Chun Gen ^a   Hou, Xue Long ^a   Pu, Lin ^b  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

^b UNIVERSITY OF VIRGINIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID DERIVATIVE; ALLYL ACETATE; ALLYL COMPOUND; COPPER; DRUG DERIVATIVE; FERROCENE; FERROUS ION; GLUTAMIC ACID; GLYCINE;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

ACETATES; ALLYL COMPOUNDS; CATALYSIS; COPPER; FERROUS COMPOUNDS; GLUTAMIC ACID; GLYCINE; MOLECULAR STRUCTURE; STEREOISOMERISM;

EID: 66149154630     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol900439h     Document Type: Article

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49. Allylic acetate 2a was also tried, but a complicated mixture of products was afforded after hydrolysis perhaps caused by the reactivity of the methyl ester and the PhCH=N-groups.
50. The ee value was obtained by HPLC analysis of 7.