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We have recently reported that discrete bis(guanidinate) alkoxide complexes of lanthanides initiate the stereoselective ROP of rac-BBL to afford syndiotactic PHB (Pr up to 0.84) via a chain-end control mechanism, while they are surprisingly non-stereoselective for the ROP of rac-LA under strictly similar conditions: Ajellal, N, Lyubov, D. M, Sinenkov, M. A, Fukin, G. K, Cherkasov, A. V, Thomas, C. M, Carpentier, J.-F, Trifonov, A. A. Chem. Eur. J. 2008, 14, 5440
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r up to 0.84) via a chain-end control mechanism, while they are surprisingly non-stereoselective for the ROP of rac-LA under strictly similar conditions: Ajellal, N.; Lyubov, D. M.; Sinenkov, M. A.; Fukin, G. K.; Cherkasov, A. V.; Thomas, C. M.; Carpentier, J.-F.; Trifonov, A. A. Chem. Eur. J. 2008, 14, 5440.
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14,15 The synthesis and characterization of trityl substituted complex 3 will be reported in due course.
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14,15 The synthesis and characterization of trityl substituted complex 3 will be reported in due course.
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66549102667
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1H} NMR spectroscopy of reprecipitated polymers (see Supporting Information).
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1H} NMR spectroscopy of reprecipitated polymers (see Supporting Information).
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