Emerging n-type redox-active radical polymer for a totally organic polymer-based rechargeable battery

Advanced Materials

Volumn 21, Issue 16, 2009, Pages 1627-1630

  Suga, Takeo ^a   Ohshiro, Hiroki ^a   Ugita, Shuhei ^a   Oyaizu, Kenichi ^a   Nishide, Hiroyuki ^a  

^a WASEDA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE MATERIAL; BATTERY APPLICATIONS; CHARGE AND DISCHARGE; CHARGE-STORAGE MATERIALS; CONSTANT OUTPUT VOLTAGE; GALVINOXYL RADICALS; HIGH CAPACITY; HIGH-POWER; LONG TERM; NEUTRAL RADICAL; NEW CLASS; RADICAL POLYMERS; RECHARGEABLE BATTERY; REDOX ACTIVITY; REDOX-ACTIVE;

LITHIUM BATTERIES; REDOX REACTIONS; SECONDARY BATTERIES;

FREE RADICAL POLYMERIZATION;

EID: 66149116002     PISSN: 09359648     EISSN: None     Source Type: Journal    
DOI: 10.1002/adma.200803073     Document Type: Article

References (35)

1. Applications of Electroactive Polymers (Ed: B. Scrosati ), Chapman and Hall, London 1993.
2. P. Novak, K. Muller, K. S. V. Santhanam, O. Haas, Chem. Rev. 1997, 97, 207.
3. M. Baumgarten, K. Muellen, Top. Curr. Chem. 1994, 169, 1.
4. A. P Kulkarni,, C. J. Tonzola, A. Babel, S. A. Jenekhe, Chem.Mater. 2004, 16, 4556.
5. M. M. Alam, S. A. Jenekhe, Chem. Mater. 2002, 14, 4775.
6. L.-L. Chua, J. Zaumseil, J.-F. Chang, E. C.-W. Ou, P. K.-H. Ho, H. Sirringhaus, R. H. Friend, Nature 2005, 434, 194.
7. J. A. Letizia, M. R. Salata, C. M. Tribout, A. Facchetti, M. A. Ratner, T. J. Marks, J. Am. Chem. Soc.2008, 130, 9679.
8. B. C. Thompson, Y.-G. Kim, T. D. McCarley, J. R. Reynolds, J. Am. Chem. Soc. 2006, 128, 12714. b)
9. E. M. Galand, Y.-G. Kim, J. K. Mwaura, A. G. Jones, T. D. McCarley, V. Shrotriya, Y. Yang, J. R. Reynolds, Macromolecules 2006, 39, 9132.
10. R. Berridge, P. J. Skabara, C. Pozo-Gonzalo, A. Kanibolotsky, J. Lohr, J. J. W. McDouall, E. J. L. McInnes, J. Wolowska, C. Winder, N. S. Sariciftci, R. W.Harrington, W. Clegg, J. Phys. Chem. B 2006, 110, 3140.
11. Y. Gofer, H. Sarker, J. G. Killian, T. O. Poehler, P. C. Searson, Appl. Phys. Lett. 1997, 71, 1582.
12. M. Mastragostino, L. Soddu, Electrochim. Acta 1990, 35, 463.
13. The small charge-storage capacity and the fluctuating voltage of the n-dopable polythiophenes originated from the low doping levels and the potential shift via doping process, have impeded their use in a rechargeable battery, where a constant output voltage is required.
14. H. Nishide, K. Oyaizu, Science 2008, 319, 737.
15. H. Nishide, T. Suga, Electrochem. Soc. Interface 2005, 14, 32.
16. H. Nishide, S. Iwasa, Y. J. Pu, T. Suga, K. Nakahara, M. Satoh, Electrochim. Acta 2004, 50, 827.
17. K. Oyaizu, T. Suga, K. Yoshimura, H. Nishide, Macromolecules 2008, 41, 6646.
18. K. Nakahara, S. Iwasa, M. Satoh, Y. Morioka, J. Iriyama, M. Suguro, E. Hasegawa, Chem. Phys. Lett. 2002, 359, 351. d) M. Suguro, S. Iwasa, Y. Kusachi, Y. Morioka, K. Nakahara, Macromol. Rapid Commun. 2007, 28, 1929.
19. K. Nakahara, J. Iriyama, S. Iwasa, M. Suguro, M. Satoh, E. J. Cairns, J. Power Sources 2007, 165, 1110.
20. K. Oyaizu, Y. Ando, H. Konishi, H. Nishide, J. Am. Chem. Soc. 2008, 130, 14459.
21. L. Bugnon, C. J. H. Morton, P. Novak, J. Vetter, P. Nesvadba, Chem. Mater. 2007, 19, 2910.
22. J.-K. Kim, G. Cheruvally, J.-W. Choi, J.-H. Ahn, D.-S. Choi, C. E. Song, J. Electrochem. Soc. 2007, 154, A839.
23. J. Qu, T. Katsumata, M. Satoh, J. Wada, J. Igarashi, K. Mizoguchi, T. Masuda, Chem. Eur. J. 2007, 13, 7965.
24. T. Suga, Y. J. Pu, S. Kasatori, H. Nishide, Macromolecules 2007, 40, 3167.
25. In extensive studies on the radical polymer-based batteries [10-12], no other organic radical species has been reported as a cathode-active material except for TEMPO. Thus, to explore n-type radical species as an anode-active material is even more challenging. We have previously reported the switching from p- to n-type redox behavior of a nitroxide radical with substituent electronic effect [13], but it was a preliminary result.
26. E. Fukuzaki, N. Takahashi, S. Imai, H. Nishide, A. Rajca, Polym. J. 2005, 37, 284.
27. Poly(galvinoxylstyrene) 1 was suitably modified via crosslinking with tetraethyleneglycol diacrylate (10 mol%) during the polymerization, to impede its dissolution into the electrolyte solution composed of acetonitrile, dimethoxyethane, and propylene carbonate. The thin film 1 was prepared by methods shown in Experimental section.
28. A. J. Bard, L. R. Faulkner, Electrochemical Methods, 2nd ed., Wiley, New York 2001.
29. T. Suga, Y. J. Pu, K. Oyaizu, H. Nishide, Bull. Chem. Soc. Jpn. 2004, 77, 2203.
30. S. J. Visco, C. C. Mailhe, L. C. DeJonghe, J. Electrochem. Soc. 1989, 136, 661.
31. N. Oyama, T. Tatsuma, T. Sato, T. Sotomura, Nature 1995, 373, 598.
32. -1, which is much slower [19].
33. -1.
34. T. Suga, H. Konishi, H. Nishide, Chem. Commun. 2007, 1730.
35. T. Kaneko, H. Tatsumi, T. Aoki, E. Oikawa, H. Yoshiki, N. Yoshioka, E. Tsuchida, H. Nishide, J. Polym. Sci. Part A 1999, 37, 189.