Photochromism of diarylethene derivatives having cyclohexyl and cyclohexenyl groups in single-component crystals and a two-component mixed crystal

Tetrahedron Letters

Volumn 50, Issue 26, 2009, Pages 3404-3407

  Morimoto, Masakazu ^a,b   Irie, Masahiro ^a  

^a RIKKYO UNIVERSITY   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

Cyclohexyl group; Diarylethene; Mixed crystal; Photochromism

Indexed keywords

CYCLOHEXENE DERIVATIVE; ETHER DERIVATIVE;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; CRYSTALLIZATION; ISOMER; MOLECULE; PHOTOREACTIVITY; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 65549171604     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2009.02.139     Document Type: Article

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23. 3), 6.77 (s, 1H, thienyl H).
24. 3), 6.07 (m, 1H, olefinic H), 6.70 (s, 1H, thienyl H).
25. 2: C 61.11, H 5.32. Found: C 60.87, H 5.31.
26. Another photochromic compound, which was supposed to be a diarylethene derivative having two cyclohexenyl groups, 1,2-bis(5-cyclohexenyl-2-methyl-3-thienyl)perfluorocyclopentene, was detected on the TLC analysis, but could not be isolated because of the low yield and the instability of the compound. The compound decomposed during the isolation and purification process.
27. 2 (all data) = 0.1922. Crystallographic data (excluding structure factors) for the structures in this Letter have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC 714780-714782. Copies of the data can be obtained, free of charge, on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK, (fax: +44-(0)1223-336033 or e-mail: deposit@ccdc.cam.ac.Uk).
28. Kobatake S., Yamada T., Uchida K., Kato N., and Irie M. J. Am. Chem. Soc. 121 (1999) 2380-2386
29. Kobatake S., Yamada M., Yamada T., and Irie M. J. Am. Chem. Soc. 121 (1999) 8450-8456