Thiophene conversion under mild conditions over a ZSM-5 catalyst

Chemical Engineering Science

Volumn 64, Issue 11, 2009, Pages 2539-2561

  Jaimes, Lisette ^a   Lujan Ferreira, M ^b   de Lasa, Hugo ^a  

^a Faculty of Engineering   (Canada)

^b UNIVERSIDAD NACIONAL DEL SUR   (Argentina)

Author keywords

Catalyst selectivity; Reaction mechanisms; Thermodynamics; Thiophene; Zeolites; ZSM 5

Indexed keywords

BENZOTHIOPHENE; CATALYTIC CONVERSIONS; DE-SULFURIZATION PROCESS; DIMERIZATION REACTIONS; FCC GASOLINES; FLUIDIZED BED; FLUIDIZED BED SYSTEMS; FLUIDIZED-BED REACTORS; HYDROGEN ADDITIONS; N OCTANES; POST TREATMENTS; REACTION MECHANISMS; REACTION NETWORKS; RING OPENINGS; RISER SIMULATORS; SILICA MATRICES; THERMO DYNAMIC ANALYSIS; THIOPHENE CONVERSIONS; ZSM-5; ZSM-5 CATALYSTS; ZSM-5 ZEOLITES;

ALKYLATION; CATALYSIS; CATALYST ACTIVITY; COKE; DESULFURIZATION; ENVIRONMENTAL REGULATIONS; FLUID CATALYTIC CRACKING; FLUID DYNAMICS; FLUIDIZATION; FLUIDIZED BEDS; GASOLINE; HYDROCARBONS; HYDROGEN; ORGANIC POLYMERS; SILICA; SILICATE MINERALS; SULFUR; THERMOANALYSIS; THERMODYNAMICS; THIOPHENE; ZEOLITES;

CATALYST SELECTIVITY;

EID: 65549149666     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2009.01.070     Document Type: Article

References (33)

1. Atias J.A., Tonetto G., and de Lasa H. Modeling fluid catalytic cracking in a novel CREC riser simulator: adsorption parameters under reaction conditions. International Journal of Chemistry Reactor Engineering A 50 (2003) 1-24
2. Babich I.V., and Moulijn J.A. Science and technology of novel processes for deep desulfurization of oil refinery streams: a review. Fuel 82 (2003) 607-631
3. Bartholomew C.H., Fuentes C.A., Guisnet M., Magnoux P., and Martin D. Roles of acidity and pore structure in the deactivation of zeolites by carbonaceous deposits. Catalyst Deactivation (1997) 1-20
4. Belliere V., Geantet Ch., Vrinat M., Ben-Taarit Y., and Yoshimura Y. Alkylation of 3-methylthiophene with 2-methyl-2-butene over a zeolitic catalyst. Energy and Fuels 18 (2004) 1806-1813
5. Chica A., Strohmaier K.G., and Iglesia E. Adsorption, desorption, and conversion of thiophene on H-ZSM5. Langmuir 20 (2004) 10982-10991
6. Chica A., Strohmaier K.G., and Iglesias E. Effects of zeolite structure and aluminum content on thiophene adsorption, desorption, and surface reactions. Applied Catalysis B: Environmental 60 (2005) 223-232
7. de Lasa, H., 1992. Riser Simulator. US Patent 5 102 628.
8. de Lasa H., Hernandez R., and Tonetto G. Catalytic desulfurization of gasoline via dehydrosulfidation. Industrial & Engineering Chemistry Research 45 (2006) 1291-1299
9. Delitala C., Cadoni E., Delpiano D., Meloni D., Melis S., and Ferino I. Liquid-phase thiophene adsorption on MCM-22 zeolite and activated carbon. Microporous and Mesoporous Materials 110 (2008) 197-215
10. Deng Y., White G.N., and Dixon J.B. Effect of structural stress on the intercalation rate of kaolinite. Journal of Colloid and Interface Science 250 (2002) 379-393
11. 3 adsorption. Applied Surface Science 246 (2005) 96-101
12. Franklin J.L. Prediction of heat and free energies of organic compounds. Industrial and Engineering Chemistry 41 (1949) 1070-1076
13. Fu J., Wang P., and He M.Y. Reaction chemistry related to FCC gasoline sulfur reduction. American Chemical Society Preprint Division Petrochemical 45 (2000) 697-700
14. Garcia C.L., and Lercher J.A. Adsorption and surface reactions of thiophene on ZSMS zeolites. Journal of Physical Chemistry 96 (1992) 2669-2675
15. Garcia C.L., and Lercher J.A. Hydrogen bonding of sulfur containing compounds adsorbed on zeolite HZSMS. Journal of Molecular Structure 293 (1993) 235-238
16. Geldart D. Types of gas fluidization. Powder Technology 7 (1973) 285-292
17. Guisnet M., and Magnoux P. Coking and deactivation of zeolites influence of the pore structure. Applied Catalysis 54 (1989) 1-27
18. Jaimes L., Tonetto G., Lujan M., and de Lasa H. Desulfurization of FCC gasoline: novel catalytic processes with zeolites. International Journal of Chemical Reactor Engineering 6 (2008) 1-66
19. Joback K.G., and Reid R.C. Estimation of pure-component properties from group-contributions. Chemical Engineering Communications 57 (1987) 233-243
20. Li W., Yu S.Y., and Iglesia E. Isotopic tracer studies of thiophene desulfurization reactions using hydrogen from alkanes on H-ZSM5 and Co/H-ZSM5. Journal of Catalysis 203 (2001) 175-183
21. Poling B.E., Prausnitz J.M., and O'Connell J.P. The Properties of Gases and Liquids. fifth ed (2001), McGraw-Hill, USA
22. Richardeau D., Joly G., Canaff C., Magnoux P., Guisnet M., Thomas M., and Nicolaos A. Adsorption and reaction over HFAU zeolites of thiophene in liquid hydrocarbon solutions. Applied Catalysis A: General 263 (2004) 49-61
23. Saintigny X., van Santen R.A., Clémendot S., and Hutschka F. A theoretical study of the solid acid catalyzed desulfurization of Thiophene. Journal of Catalysis 183 (1999) 107-118
24. Shan H.H., Li C.Y., Yang C.H., Zhao H., Zhao B.Y., and Zhang J.F. Mechanistic studies on thiophene species cracking over USY zeolite. Catalysis Today 77 (2002) 117-126
25. Smirniotis P.G., and Ruckenstein E. Comparison of the performance of ZSM-5, β zeolite, Y, USY, and their composites in the catalytic cracking of n-octane, 2,2,4-trimethylpentane, and 1-octene. Industrial Chemical Engineering Research 33 (1994) 800-813
26. Stull D., Westrum E., and Sinke G. The Chemical Thermodynamics of Organic Compounds (1969), John Wiley & Sons, USA
27. Valla J.A., Lappas A.A., and Vasalos I.A. Catalytic cracking of thiophene and benzothiophene: mechanism and kinetics. Applied Catalysis A: General 297 (2006) 90-101
28. van Krevelen D.W., and Chermin H.A.G. Estimation of the free enthalpy (Gibbs free energy) of formation of organic compounds from group-contributions. Chemical Engineering Science 1 (1951) 66-80
29. Wang P., Fu J., and He M.Y. Cracking-desulfurization of thiophene contained paraffin over zeolites. Petroleum Processing and Petrochemicals 31 (2000) 58-62
30. Welters W.J., de Beer V.H., and van Santen R. Influence of zeolite acidity on thiophene hydrodesulfurization activity. Applied Catalysis A: General 119 (1994) 253-269
31. Xu Y., Shu Y., Liu Sh., Huang J., and Guo X. Interaction between ammonium heptamolybdate and NH4ZSM-5 zeolite: the location of Mo species and the acidity of Mo/HZSM-5. Catalysis Letters 35 (1995) 233-243
32. Yin C., and Xia D. A study of the distribution of sulfur compounds in gasoline produced in China: Part 3. Identification of individual sulfides and thiophenes. Fuel 83 (2004) 433-441
33. Yu S.Y., Li W., and Iglesia E. Desulfurization of thiophene via hydrogen transfer from alkanes on cation-modified H-ZSM5. Journal of Catalysis 187 (1999) 257-261