Rubidium and cesium ion adsorption by an ammonium molybdophosphate-calcium alginate composite adsorbent

Colloids and Surfaces A: Physicochemical and Engineering Aspects

Volumn 342, Issue 1-3, 2009, Pages 76-83

  Ye, Xiushen ^a,b   Wu, Zhijian ^a,c   Li, Wu ^a   Liu, Haining ^a,b   Li, Quan ^a   Qing, Binju ^a,b   Guo, Min ^a,b   Ge, Fei ^a,b  

^a QINGHAI INSTITUTE OF SALT LAKES   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

^c HUAQIAO UNIVERSITY   (China)

Author keywords

Adsorption; Adsorption kinetics; Ammonium molybdophosphate; Cesium; Composite adsorbent; Rubidium

Indexed keywords

ALKALINITY; AMMONIUM COMPOUNDS; CALCIUM; CALCIUM ALLOYS; CALCIUM CHLORIDE; CESIUM; CESIUM COMPOUNDS; IONIC STRENGTH; LIGHT METALS; METAL IONS; RATE CONSTANTS; SCANNING ELECTRON MICROSCOPY;

ADSORPTION CAPACITIES; ADSORPTION KINETICS; ADSORPTION RATES; AMMONIUM MOLYBDOPHOSPHATE; AQUEOUS SOLUTIONS; CALCIUM ALGINATES; CESIUM IONS; COMPOSITE ADSORBENT; EQUILIBRIUM ADSORPTIONS; FIRST ORDERS; INITIAL ADSORPTIONS; KINETIC MODELS; METAL ION CONCENTRATIONS; PH VALUES; SECOND ORDERS; SECOND-ORDER RATE CONSTANTS; SEM; SODIUM ALGINATES; SODIUM IONS;

ADSORPTION;

ADSORBENT; AMMONIUM PHOSPHOMOLYBDATE; CALCIUM ALGINATE; CESIUM ION; RUBIDIUM ION; UNCLASSIFIED DRUG;

ADSORPTION; ARTICLE; COMPOSITE MATERIAL; IONIC STRENGTH; PH; POROSITY; PRIORITY JOURNAL; SCANNING ELECTRON MICROSCOPE; TEMPERATURE DEPENDENCE;

EID: 65549107284     PISSN: 09277757     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.colsurfa.2009.04.011     Document Type: Article

References (36)

1. Kennedy J.J. The alkali metal cesium and some of its salts. Chem. Rev. 23 (1938) 157-163
2. Vdović S., Sarkisyan D., and Pichler G. Absorption spectrum of rubidium and cesium dimers by compact computer operated spectrometer. Opt. Commun. 268 (2006) 58-63
3. Anan'ev V., Miklin M., Nelyubina N., and Poroshina M. Optical spectra of UV-irradiated rubidium and cesium nitrate crystals. J. Photochem. Photobiol. A 162 (2004) 67-72
4. Glendening B.L., Parrish D.B., and Schrenk W.G. Spectrographic determination of rubidium in plant and animal tissues. Anal. Chem. 27 (1955) 1554-1556
5. Jia B., Harris S., Lewis L.L., Zhan J.P., and Brooks P.R. Threshold behavior in electron-transfer collisions between rubidium atoms and CFCl or CFI molecules. J. Phys. Chem. A 109 (2005) 9213-9219
6. Dash K., Thangavel S., Chaurasia S.C., and Arunachalam J. Determination of traces of rubidium in high purity cesium chloride by electrothermal atomic absorption spectrometry (ETAAS) using boric acid as a modifier. Anal. Chim. Acta 584 (2007) 210-214
7. Cui R.F., Hu M.C., Jin L.H., Li S.N., Jiang Y.C., and Xia S.P. Activity coefficients of rubidium chloride and cesium chloride in methanol-water mixtures and a comparative study of Pitzer and Pitzer-Simonson-Clegg models (298.15 K). Fluid Phase Equilib. 251 (2007) 137-144
8. Webber P.R.A., Beer P.D., Chen G.Z., Felix V., and Drew M.G.B. Bis(calix[4]diquinone) receptors: cesium- and rubidium-selective redox-active ionophores. J. Am. Chem. Soc. 125 (2003) 5774-5785
9. Hu M.C., Jin L.H., and Li S.N. Equilibrium phase behavior of water + propan-1-ol or propan-2-ol + cesium chloride at (298.15, 308.15, and 318.15) K. J. Chem. Eng. Data 50 (2005) 2049-2052
10. Guo H.Y., Hu M.C., Li S.N., Jiang Y.C., and Wang M.X. Liquid-liquid-solid equilibrium of the quaternary systems sodium chloride + rubidium chloride + propanols + water at 25 °C. J. Chem. Eng. Data 53 (2008) 131-135
11. Levitskaia T.G., Bryan J.C., Sachleben R.A., Lamb J.D., and Moyer B.A. A surprising host-guest relationship between 1,2-dichloroethane and the cesium complex of tetrabenzo-24-crown-8. J. Am. Chem. Soc. 122 (2000) 554-562
12. Wiesbrock F., and Schmidbaur H. Crystal structures of rubidium and cesium anthranilates and salicylates. Inorg. Chem. 42 (2003) 7283-7289
13. Nelson C.R., Olson S., Poling S.A., and Martin S.W. Synthesis and characterization of hydrated rubidium thiohydroxosilicogermanates using mechanochemical hydrothermal synthesis. Chem. Mater. 18 (2006) 6436-6441
14. 2O at 30 °C and 50 °C. Chin. J. Inorg. Chem. 18 (2002) 701-704
15. Dan D.Z., Du G., and Wan Y.P. Indirect determination of cesium in brine by single-sweep oscillopolarography. Electroanalysis 4 (2005) 575-580
16. Ye X.S., Nai X.Y., Li H.J., Dong Y.P., Li Y.H., and Li W. FAAS determination of microamounts of rubidium in chloride bittern. PTCA Part B: Chem. Anal. 44 (2008) 763-764, 767
17. Ye X.S., Zhang S.Y., Li H.J., Li W., and Wu Z.J. Determination rubidium and cesium in chloride type oilfield water by flame atomic absorption spectrometry. Spectrosc. Spect. Anal. 29 3 (2009) 1-4
18. Collins A.G. Flame spectrophotometric determination of cesium and rubidium in oil field waters. Anal. Chem. 35 (1963) 1258-1261
19. Fewox C.S., Kirumakki S.R., and Clearfield A. Structural and mechanistic investigation of rubidium ion exchange in potassium zirconium trisilicate. Chem. Mater. 19 (2007) 384-392
20. Clarke T.D., and Wai C.M. Selective removal of cesium from acid solutions with immobilized copper ferrocyanide. Anal. Chem. 70 (1998) 3708-3711
21. Pekárek V., and Veselý V. Synthetic inorganic ion exchangers-II: salts of heteropolyacids, insoluble ferrocyanides, synthetic aluminosilicates and miscellaneous exchangers. Talanta 19 (1972) 1245-1283
22. Dias J.A., Caliman E., and Dias S.C.L. Effects of cesium ion exchange on acidity of 12-tungstophosphoric acid. Micropor. Mesopor. Mater. 76 (2004) 221-232
23. Arida H.A.M., Aglan R.F., and El-Reefy S.A. A new cesium ion selective graphite rod electrode based on Cs-molybdophosphate. Anal. Lett. 37 (2004) 21-33
24. 137Cs concentration in seawater using ammonium 12-molybdophosphate adsorption and chemical separation method. J. Environ. Radioac. 99 (2008) 1815-1818
25. Doležal J., Stejskal J., Tympl M., and Kouřǐm V. Improved inorganic ion-exchangers II. Ammonium molybdophosphate-silica gel system. J. Radioanal. Chem. 21 (1974) 381-387
26. Roy S.D., and Das M.S. Studies on the cation-exchange behaviour of ammonium 12-molybdophosphate. Part I. Separation of rubidium, thallium and caesium. Anal. Chim. Acta 51 (1970) 520-522
27. 137Cs from acidic nuclear waste solutions. Adv. Environ. Res. 6 (2002) 107-121
28. Khanchi A.R., Yavari R., and Pourazarsa S.K. Preparation and evaluation of composite ion-exchanger for the removal of cesium and strontium radioisotopes. J. Radioanal. Nucl. Chem. 273 (2007) 141-145
29. Šebesta F., and Štefula V. Composite ion exchanger with ammonium molybdophosphate and its properties. J. Radioanal. Nucl. Chem. 140 (1990) 15-21
30. Todd T.A., Mann N.R., Tranter T.J., Šebesta F., John J., and Motl A. Cesium sorption from concentrated acidic tank wastes using ammonium molybdophosphate-polyacrylonitrile composite sorbents. J. Radioanal. Nucl. Chem. 254 (2002) 47-52
31. 3). J. Radioanal. Nucl. Chem. 242 (1999) 11-16
32. Murthy G.S., Sivaiah M.V., Kumar S.S., Reddy V.N., Krishna R.M., and Lakshminarayana S. Adsorption of cesium on a composite inorganic exchanger zirconium phosphate-ammonium molybdophosphate. J. Radioanal. Nucl. Chem. 260 (2004) 109-114
33. Gilson C.D., and Thomas A. Calcium alginate bead manufacture: with and without immobilised yeast. Drop formation at a two-fluid nozzle. J. Chem. Technol. Biotechnol. 62 (1995) 227-232
34. Pathak P.N., and Choppin G.R. Kinetic and thermodynamic studies of cesium (I) sorption on hydrous silica. J. Radioanal. Nucl. Chem. 270 (2006) 299-305
35. Flury M., Czigány S., Chen G., and Harsh J.B. Cesium migration in saturated silica sand and Hanford sediments as impacted by ionic strength. J. Contam. Hydrol. 71 (2004) 111-126
36. + to micaceous subsurface sediments from the Hanford site, USA. Geochim. Cosmochim. Acta 66 (2002) 193-211