Preparation, structures, and some reactivities of five-coordinate alkyne complexes of mo with tetraphosphine or diphosphine coligand [mo(rc≡cr ){mes0-0-c6h4(pphch2ch2pph 2)2}] and [mo(rc≡cr )(ph2pch 2ch2pph2)2]

Organometallics

Volumn 28, Issue 4, 2009, Pages 1112-1121

  Niikura, Fumiya ^a   Seino, Hidetake ^a   Mizobe, Yasushi ^a  

^a INSTITUTE OF INDUSTRIAL SCIENCE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYL COMPLEXES; BIPYRAMIDAL GEOMETRIES; BIPYRAMIDAL STRUCTURES; CONTROLLED CONDITIONS; DIPHOSPHINE; HYDROGENATION PRODUCTS; INTERMEDIATE COMPLEXES; INTERMEDIATE STAGES; INTERNAL ALKYNES; NMR STUDIES; REACTION CONDITIONS; TETRAPHOSPHINE; X- RAY DIFFRACTIONS; X-RAY ANALYSIS;

ACETYLENE; CHROMIUM COMPOUNDS; DYES; HYDROGENATION; MOLYBDENUM; MOLYBDENUM COMPOUNDS; OLEFINS; PARAFFINS;

COORDINATION REACTIONS;

EID: 64549144220     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om800615a     Document Type: Article

References (52)

1. (a) Artta, C.; Seino. H.; Mizobe, Y.; Hidat, M. Chem. Lett. 1999, 28, 611.
2. (b) Arita, C.; Seino, H.; Mizobe, Y.; Hidai, M. Bull. Chem. Soc. Jpn. 2001, 74, 561.
3. Seino, H.; Arita. C.: Hidai, M.; Mizobe. Y. J.Oreanomet. Chem. 2002, 658, 106.
4. Ohnishi, T.; Seino. H.; Hidai, M.; Mizobe. Y. J. Omanomet. Chem. 2005, 690, 1140.
5. Seino. H.; Watanabe. D.; Ohnishi. T.; Arita, C.; Mizobe, Y. Inorg. Chem. 2007. 46, 4784.
6. Ishino. H.; Kuwata, S.; Ishii. Y.: Hidai, M. Organometallics 2001, 20, 13.
7. Davies, S. C.; Henderson. R. A.; Hughes, D. L.; Oglieve. K. E. Chem. Commun. 1996, 2039.
8. Henderson, R. A.; Oglieve, K. E.; Salisbury, P.J. Chem. Soc., Dalton Trans. 1995, 2479.
9. Hills. A.; Hughes. D. L.; Kashef, N.; Lemos. A. N. D. A.; Pombeiro, A. J. L.; Richards, R. L. J. Chem. Soc., Dalton Trans. 1992, 1775.
10. (a) Baker. P. K. Adv. Organomet. Chem. 1996. 40. 45.
11. (b) Templeton, J. L. Adv. Organomet. Chem. 1989. 29, 1.
12. Ohnishi. T.; Tsuboi, H.; Seino, H.; Mizobe, Y. J. Oreanomet. Chem. 2008, 693, 269.
13. (a) Henderson, R. A. Angew. Chem., Int. Ed. Engl. 1996, 35. 946.
14. (b) Pombeiro, A. J. L.; Richards. R. L. Coord. Chem. Rev. 1990, 104, 13.
15. (c) Seino, H.; Mizobe, Y.; Hidai, M. Chem. Rec. 2001, 1, 349.
16. Chatt, J.; Heath, G. A.; Richards, R. L. J. Chem. Soc., Dalton Trans. 1974, 2074.
17. Busby. D. C.; George, T. A.; Iske, T. D. A., Jr.; Wagner. S. D. Inorg. Chem. 1981, 20, 22.
18. (a) Thomas, J. L. J.Am. Chem. Soc. 1973, 95, 1838.
19. (b) Herberich, G. E.; Englert, U.; Eassbender, W. J.Organomet. Chem. 1991, 420, 303.
20. Theopold, K. H.; Holmes, S. J.; Schrock, R. R. Angew. Chem., Int. Ed. Engl. 1983, 22, 1010.
21. Henderson, R. A.; Lowe. D. L.; Salisbury. P. J.Oreanomet. Chem. 1995, 489, C22.
22. Labinger. J. A.; Schwartz. J. J.Am. Chem. Soc. 1975, 97, 1596.
23. Shur, V. B.; Burlakov. V. V.; Vol'pin, M. E. J.Oreanomet. Chem. 1988, 347, 77.
24. Takahashi. T.; Swanson. D. R.; Negishi, E. Chem. Lett. 1987. 16, 623.
25. (a) Barlex, D. M.; Kemmit, R. D. W.; Littlecott. G. W. Chem. Commun. 1969, 613.
26. (b) Tripathy. P. B.; Roundhill. D. M.J.Am. Chem.Soc. 1970 92 3825.
27. Abu Bakar, A.; Bryan. C. D.; Cordes. A. W.; Allison. N. T. Organometallics 1994, 13, 3375.
28. Masters, A. P.; Richardson, J. F.; Sorensen. T. S. Can. J. Chem. 1990, 68, 2221.
29. Bleek. J. R.; Donnay, E. Organometallics 2002, 21, 4099.
30. Cheng, M.-H.; Cheng. C.-Y.; Wang. S.-L.; Peng. S.-M.; Liu, R.-S. Organometallics 1990, 9, 1853.
31. Baudry, D.; Daran, J. C.; Dromzee, Y.; Felkin, H.; Jeannin, Y.; Zekrzewski, J. J. Chem. Soc., Chem. Commun. 1983, 813.
32. Schmidt, T.; Goddard, R. J. Chem. Soc., Chem. Commun. 1991, 1427.
33. Frohnapfel, D. S.; Templeton. J. L. Coord. Chem. Rev. 2000, 206-207. 199.
34. (a) Bottrill, M.; Green, M. J.Am. Chem. Soc. 1977, 99, 5795.
35. (b) Green. M. J. Organomet. Chem. 1986, 300, 93. and references therein. .
36. (a) Feng, S. G.; Templeton, J. L. Organometallics 1992, 11, 2168.
37. (b) Frohnapfel, D. S.; White, P. S.; Templeton, J. L. Organometallics 1997, 16, 3737.
38. (c) Frohnapfel, D. S.; White. P. S.; Templeton. J. L. Organometallics 2000, 19, 1497.
39. Kashef, N.; Richards, R. L. J.Oprganomet. Chem. 1989, 365, 309.
40. (a) Ito, T.; Tosaka, H.; Yoshida, S.; Mita, K.; Yamamoto, A. Organometallics 1986, 5, 735.
41. (b) Woodworth, B. E.; Frohnapfel. D. S.; White, P. S.; Templeton, J. L. Organometallics 1998, 17, 1635.
42. Almeida, S. S. P.; Duarte, M. T.; Ribeiro, L. M. D.; Gormley, F.; Galvao. A. M.; da Silva, J. J. R. F.; Pombeiro, A. J. L. J. Organomet. Chem. 1996, 524, 63.
43. Iwasa, K.; Seino, H.; Niikura, F.; Mizobe, Y. Unpublished results.
44. (a) Hidai. M.; Tominari, K.; Uchida, Y. J.Am. Chem. Soc. 1972, 94, 110.
45. (b) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1980, 20, 119.
46. Kumar, I; Jolly, R. S. Org. Lett. 1999, 1, 207.
47. (a) CrystalClear 1.3.5; Rigaku Corporation, 1999; CrystalClear Software User s Guide; Molecular Structure Corporation, 2000.
48. (b) Pflugrath, J. W. Acta Crystallogr., Sect. D 1999, 55, 1718.
49. (a) CrystalStructure 3.8.0, Crystal Structure Analysis Package; Rigaku and Rigaku/MSC, 2000-2006.
50. (b) Carruthers, J. R.; Rollett, J. S.; Betteridge, P. W.; Kinna, D.; Pearce, L.; Larsen, A.; Gabe, E. CRYSTALS Issue 11; Chemical Crystallography Laboratory: Oxford, U.K., 1999.
51. PATTY: Beurskens. P. T.; Admiraal. G.; Beurskens, G.; Bosman, W. P.; Garcia-Granda, S.; Gould, R. O.; Smits, J. M. M.; Smykall, C. The DIRDIF Program System, Technical Report of the Crystallography Laboratory; University of Nijmegen: Nijmegen. The Netherlands, 1992.
52. DIRD1F-99: Beurskens, P. T.; Admiraal, G.; Beurskens. G.; Bosman, W. P.; de Gelder, R.; Israel, R.; Smits, J. M. M. The DIRDIF-99 Program System, Technical Report of the Crystallography Laboratory; University of Nijmegen: Nijmegen, The Netherlands, 1999.