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Volumn 48, Issue 6, 2009, Pages 2355-2357

Redox isomerism in the lanthanide complex [(dpp-bian)Yb(DME)( μ -Br)]2 (dpp-bian ) 1,2-Bis[(2,6-diisopropylphenyl)imino]acenaphthene) †

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EID: 64349116250     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic900022s     Document Type: Article
Times cited : (89)

References (46)
  • 28
    • 0000610858 scopus 로고    scopus 로고
    • Lange, C. W.; Foldeaki, M.; Nevodchikov, V. I.; Cherkasov, V. K.; Abakumov, G. A.; Pierpont.C. G. J. Am. Chem. Soc. 1992, 114, 4220-4222.
    • (b) Lange, C. W.; Foldeaki, M.; Nevodchikov, V. I.; Cherkasov, V. K.; Abakumov, G. A.; Pierpont.C. G. J. Am. Chem. Soc. 1992, 114, 4220-4222.
  • 44
    • 64349118313 scopus 로고    scopus 로고
    • alpha;,α-Dibromostilbene (5 mg, 0.015 mmol) and 1 (0.5 g, 1 mmol) were added to the ytterbium metal (10.5 g, 60.7 mmol) in DME (30 mL, Within 30 min of reflux, the reaction mixture turned brown. The solvent was slowly evaporated from the decanted solution. Compound 2 was isolated (0.64 g, 75, as deep-red prismatic crystals. Elem anal. Calcd for G44H 60YbN2O4 (853.98, C, 61.88; H, 7.08. Found: C, 61.35: H, 7.93. 1H NMR (THF-d8, 200 MHz, ô 6.91 (d, 4 H, CH arom, 3 J, 7.53 Hz, 6.67 (t, 2 H, CH arom, 3J, 7.53 Hz, 6.54 (d, 2 H, CH arom, 3 J, 8.03 Hz, 6.46 (dd, 2 H, CH arom, 3 J, 6.53 Hz, 3 J, 8.03 Hz, 5.64 (d, 2 H, CH arom, 3 J, 6.53 Hz, 3.94 (sept, 4 H. CH(CH3)2, 3 J, 6.78 Hz, 1.16 (d, 12 H, CH(CH3)2, 3J
    • 3J = 6.78 Hz).
  • 45
    • 64349097876 scopus 로고    scopus 로고
    • 2 (1867.78): C. 56.59; H, 6.48. Found: C, 56.28; H, 6.30.
    • 2 (1867.78): C. 56.59; H, 6.48. Found: C, 56.28; H, 6.30.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.