Study of the cis to trans isomerization of 1-Phenyl-2,3-disubstituted tetrahydro-β-carbolines at C(1). Evidence for the carbocation-Mediated mechanism

Journal of Organic Chemistry

Volumn 74, Issue 7, 2009, Pages 2771-2779

  Kumpaty, Hephzibah J ^a   Van Linn, Michael L ^b   Shahjahan Kabir, M ^b   Holger Forsterling F ^b   Deschamps, Jeffrey R ^c   Cook, James M ^b  

^a UNIVERSITY OF WISCONSIN WHITEWATER   (United States)

^b UNIVERSITY OF WISCONSIN MILWAUKEE   (United States)

^c NAVAL RESEARCH LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDIC CONDITIONS; BOND CLEAVAGES; CARBOCATION; CARBOLINES; CARBON ATOMS; CIS-TO-TRANS ISOMERIZATION; DIASTEREOMER; DIASTEREOMERS; ELECTRON-RICH; ELECTRON-RICH AROMATICS; EPIMERIZATION; EPIMERS; FASTER RATES; INDOLE ALKALOIDS; KINETIC STUDIES; L TRYPTOPHANS; PHENYL RINGS; PICTET-SPENGLER REACTIONS; SCISSION PROCESS; TRANS-ISOMERS; X-RAY CRYSTALLOGRAPHIC ANALYSIS;

ALDEHYDES; AMINO ACIDS; CONDENSATION REACTIONS; ELECTRON TRANSITIONS; ISOMERIZATION; PYRIDINE; SYNTHESIS (CHEMICAL);

ISOMERS;

1 PHENYL 2,3 DISUBSTITUTED TETRAHYDRO BETA CARBOLINE; ALDEHYDE; CARBOLINE DERIVATIVE; TRYPTOPHAN; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; DIASTEREOISOMER; ISOMERIZATION; KINETICS; PICTET SPENGLER REACTION; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

ALKYLATION; CARBOLINES; ELECTRONS; HYDROGEN; ISOMERISM; MOLECULAR STRUCTURE;

EID: 64249132822     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo8028168     Document Type: Article

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