Macroporous polymer electrolytes based on PVDF/PEO-b-PMMA block copolymer blends for rechargeable lithium ion battery

Journal of Membrane Science

Volumn 334, Issue 1-2, 2009, Pages 117-122

  Xiao, Qizhen ^a   Wang, Xingzhu ^a   Li, Wen ^b   Li, Zhaohui ^a   Zhang, Tianjing ^a   Zhang, Hailiang ^a  

^a XIANGTAN UNIVERSITY   (China)

^b Shen Zhen Shi Dong Fang Hua Lian Technology Company   (China)

Author keywords

Ionic conductivity; Macroporous polymer electrolyte; Phase inversion; PVDF PEO b PMMA

Indexed keywords

BLOCK COPOLYMER BLENDS; CRYSTALLINITY; ELECTROCHEMICAL STABILITIES; MACROPOROUS POLYMER ELECTROLYTE; PHASE INVERSION; PHASE INVERSION TECHNIQUES; POLIES (METHYLMETHACRYLATE); POLYETHYLENEOXIDE; POLYMER LITHIUM ION BATTERIES; POLYVINYLIDENE FLUORIDES; POTENTIAL APPLICATIONS; PVDF/PEO-B-PMMA; RECHARGEABLE LITHIUM ION BATTERIES; ROOM TEMPERATURES; THERMAL ANALYSIS;

BLOCK COPOLYMERS; COPOLYMERIZATION; ELECTROLYSIS; ESTERS; ETHYLENE; IONIC CONDUCTIVITY; IONS; LITHIUM; LITHIUM ALLOYS; LITHIUM BATTERIES; LITHIUM COMPOUNDS; POLYELECTROLYTES; POLYETHYLENE OXIDES; POLYMER BLENDS; POLYMERS; THERMOANALYSIS;

CONDUCTING POLYMERS;

COPOLYMER; ELECTROLYTE; LITHIUM; POLY(ETHYLENE OXIDE) BLOCK POLY(METHYLMETHACRYLATE); POLYMER; POLYVINYLIDENE FLUORIDE; UNCLASSIFIED DRUG;

ARTICLE; BATTERY INDUSTRY; CRYSTAL STRUCTURE; ELECTROCHEMICAL ANALYSIS; ION TRANSPORT; MOLECULAR STABILITY; NONHUMAN; POROSITY; PRIORITY JOURNAL; RECHARGEABLE BATTERY; STRUCTURE ANALYSIS; THERMAL ANALYSIS;

EID: 64049096913     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2009.02.018     Document Type: Article

References (22)

1. Tarascon J.M., and Armand M. Issues and challenges facing rechargeable lithium batteries. Nature 414 (2001) 359-367
2. AricÒ A.S., Bruce P., Scrosati B., Tarascon J.-M., and Schalkwijk W.V. Nanostructured materials for advanced energy conversion and storage devices. Nat. Mater. 4 (2005) 366-377
3. Song J.Y., Cheng C.L., Wang Y.Y., and Wan C.C. Microstructure of Poly(vinylidene fluoride)-based polymer electrolyte and its effect on transport properties. J. Electrochem. Soc. 149 (2002) A1230-A1236
4. Zhao H.P., Jiang C.Y., He X.M., Ren J.G., and Wan C.R. Preparation of micro-porous membrane electrodes and their application in preparing anodes of rechargeable lithium batteries. J. Membr. Sci. 310 (2008) 1-6
5. 2. J. Membr. Sci. 293 (2007) 100-110
6. Wang Y.J., and Kim D. The effect of F127 addition on the properties of PEGDA/PVdF cross-linked gel polymer electrolytes. J. Membr. Sci. 312 (2008) 76-83
7. 3 nanoparticles. Solid State Ionics 176 (2005) 1903-1908
8. 4 complex as 'solid' and 'wet' polymer electrolyte. Solid State Ionics 175 (2004) 747-750
9. 6 solid polymer electrolyte with enhanced ion conduction in 'wet' form. J. Power Sources 123 (2003) 222-229
10. Mohamed N.S., and Arof A.K. Investigation of electrical and electrochemical properties of PVDF-based polymer electrolytes. J. Power Sources 132 (2004) 229-234
11. Cheng C.L., Wan C.C., and Wang Y.Y. Microporous PVdF-HFP based gel polymer electrolytes reinforced by PEGDMA network. Electrochem. Commun. 6 (2004) 531-535
12. M. Oliver, Blended polymer gel electrolytes, US Patent 5,658,685, 1997.
13. Lin D.J., Chang C.L., Lee C.K., and Cheng L.P. Preparation and characterization of microporous PVDF/PMMA composite membranes by phase inversion in water/DMSO solutions. Eur. Polym. J. 42 (2006) 2407-2418
14. Nicotera I., Coppola L., Oliviero C., Castriota M., and Cazzanelli E. Investigation of ionic conduction and mechanical properties of PMMA-PVdF blend-based polymer electrolytes. Solid State Ionics 177 (2006) 581-588
15. Shi Q., Yu M.X., Zhou X., Yan Y.S., and Wan C.R. Structure and performance of porous polymer electrolytes based on P(VDF-HFP) for lithium ion batteries. J. Power Sources 103 (2002) 286-292
16. Huang C., and Zhang L. Miscibility of poly(vinylidene fluoride) and atactic poly(methyl methacrylate). J Appl. Polym. Sci. 92 (2004) 1-5
17. Tomura H., Saito H., and Inoue T. Light scattering analysis of upper critical solution temperature behavior in a poly(vinylidene fluoride)/poly(methyl methacrylate) blend. Macromolecules 25 (1992) 1611-1614
18. Sun X.Y., Zhang H.L., Zhang L.J., Wang X.Y., and Zhou Q.F. Synthesis of amphiphilic poly(ethylene oxide)-b-poly(methyl methacrylate) diblock copolymers via atom transfer radical polymerization utilizing halide Exchange Technique. Polym. J. 37 (2005) 102-108
19. Rosenberg Y., Sigmann A., Narkis M., and Shkolnik S. The sol/gel contribution to the behavior of Y-irradiated poly(vinylidene fluoride). J. Appl. Polym. Sci. 43 (1991) 535-541
20. Zhang S.S., Xu K., Foster D.L., Ervin M.H., and Jow T.R. Microporous gel electrolyte Li-ion battery. J. Power Sources 125 (2004) 114-118
21. Kim D.W., Oh B.K., and Choi Y.M. Electrochemical performance of lithium-ion polymer cell using gel polymer electrolyte based on acrylonitrile-methyl methacrylate-styrene terpolymer. Solid State Ionics 123 (1999) 243-249
22. Appetechi G.B., Dautzenberg G., and Scrosati B. A new class of advanced polymer electrolytes and their relevance in plastic-like, rechargeable lithium batteries. J. Electrochem. Soc. 143 (1996) 6-12