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Rapid scan and step scans are two different techniques that can be used to record real time-resolved infrared spectra. In the rapid scan technique, the time-dependent evolution of the infrared active species is observed by recording the spectra in sequence. In this acquisition mode, the time resolution is limited to about 20 ms because of the scanning speed of the moving mirror. In the step-scan mode, instead, the position of the moving mirror is fixed at a particular position, and a complete time run is recorded at this particular mirror position. This procedure is repeated at all other mirror positions, and a 3D representation of the temporal evolution of the entire interferogram is obtained by combining the respective time traces. Fourier transformation yields the corresponding 3D representation of the time evolution of the IR difference spectra
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Rapid scan and step scans are two different techniques that can be used to record real time-resolved infrared spectra. In the rapid scan technique, the time-dependent evolution of the infrared active species is observed by recording the spectra in sequence. In this acquisition mode, the time resolution is limited to about 20 ms because of the scanning speed of the moving mirror. In the step-scan mode, instead, the position of the moving mirror is fixed at a particular position, and a complete time run is recorded at this particular mirror position. This procedure is repeated at all other mirror positions, and a 3D representation of the temporal evolution of the entire interferogram is obtained by combining the respective time traces. Fourier transformation yields the corresponding 3D representation of the time evolution of the IR difference spectra.
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